A kind of preparation method of solid oxide fuel cell/electrolyzer connector

A solid oxide and fuel cell technology, applied in fuel cells, electrolytic components, electrolytic processes, etc., can solve problems such as SOFC performance degradation, increase battery internal resistance, etc., to improve life and stability, improve bonding strength, and cost low effect

Active Publication Date: 2022-07-12
GUANGDONG INST OF NEW MATERIALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, Cr will increase the internal resistance of the battery after oxidation at high temperature, and will volatilize and poison the cathode, resulting in the degradation of SOFC performance.

Method used

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  • A kind of preparation method of solid oxide fuel cell/electrolyzer connector
  • A kind of preparation method of solid oxide fuel cell/electrolyzer connector
  • A kind of preparation method of solid oxide fuel cell/electrolyzer connector

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preparation example Construction

[0046] The preparation method of the solid oxide fuel cell / electrolyte connector provided by the present application may include the following steps:

[0047] Step 1: Design and model the structure and function of the solid oxide fuel cell / electrolyte connector. please combine Figure 1 to Figure 7 , the solid oxide fuel cell / electrolytic cell connector includes a connector body 1 and a protective coating 2 on the surface of the connector body.

[0048] The connector body 1 described above has opposite first surfaces 101 and second surfaces 102 .

[0049] The connector body 1 is provided with at least four through holes penetrating the first surface 101 and the second surface 102 . The first surface 101 has an opposing first side 103 and a second side 104, and the second surface also has an opposing first side 103 and a second side 104, that is, the first side 103 of the first surface and the first side 103 of the second surface. The direction of one side 103 is the same, a...

Embodiment 1

[0086] This embodiment provides a solid oxide fuel cell / electrolyte connector, which adopts selective laser melting technology (SLM) and plasma spraying technology to realize the manufacture of the SOFC connector.

[0087] The specific manufacturing process of the SOFC connector is as follows:

[0088] (1) Integrated design of structure and function, rationally plan the structure, material and thickness of the metal part (ie, the connector body 1) and the coating 2 part. Specifically: the material of the connector body 1 is 430 stainless steel powder, the thickness is 3mm, and the material of the coating 2 (protective coating) is (Mn, Co) 3 O 4 , with a thickness of 30 μm.

[0089] (2) 3D modeling, the specific designed structure is as follows figure 1 , figure 2 and Figure 5 shown.

[0090] The connector body 1 is in the shape of a cube, and the front and back sides of the cube are a first surface 101 and a second surface 102 respectively. The connector body 1 has a f...

Embodiment 2

[0100] This embodiment provides a solid oxide fuel cell / electrolyte connector, which adopts the selective electron beam melting technology (SLM) and the plasma spraying technology to realize the manufacturing method of the SOFC connector.

[0101] The manufacturing process of this SOFC connector is as follows:

[0102] (1) Integrated design of structure and function, rationally plan the structure, material and thickness of the metal part (ie, the connector body 1) and the coating 2 part. Specifically: the material of the connector body 1 is Crofer22, the thickness is 4mm, and the material of the coating 2 (protective coating) is (Mn, Co) 3 O 4 , with a thickness of 50 μm.

[0103] (2) 3D modeling, the specific designed structure is as follows Figure 3 to Figure 5 shown.

[0104] The difference between this structure and Embodiment 1 is that starting from the end of the first side 103 close to the fourth side 106, in a clockwise direction, the first air inlet 13, the first...

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Abstract

The invention discloses a preparation method of a solid oxide fuel cell / electrolytic cell connector, belonging to the technical field of fuel cells / electrolytic cells. It includes: designing and modeling the solid oxide fuel cell / electrolyte connector; performing position placement, format conversion, defect repair and slicing processing on the model of the connector body; using the additive manufacturing method to prepare the connector body ; Post-processing the body of the connector; Prepare the protective coating by spraying or coating. Using the additive manufacturing method to prepare the connector body can realize the refined preparation of the complex structure of the connector body. The invention can realize the controllable preparation of the high-quality connecting body, significantly improve the consistency of the connecting body, and is beneficial to improve the stability and service life of the fuel cell / electrolyte stack. At the same time, the preparation method involved in the present invention has short cycle and low cost, and has strong practical significance for the promotion and application of fuel cells / electrolyzers.

Description

technical field [0001] The present invention relates to the technical field of fuel cells / electrolyzers, in particular to a method for preparing a solid oxide fuel cell / electrolyzer connector. Background technique [0002] Solid oxide fuel cell (SOFC) is a kind of fuel cell, which is an all-solid-state power generation device that directly converts chemical energy in fuel into electrical energy through chemical reaction. It is mainly composed of anode layer, electrolyte layer and cathode layer. Compared with the traditional heat engine power generation technology, the biggest feature of SOFCs is that the power generation process does not involve combustion, so its energy conversion efficiency is not limited by the Carnot cycle. The primary electrical efficiency can reach 50%-60%, and after linkage with the steam turbine, the energy conversion efficiency can reach more than 80%. At the same time, SOFC is environmentally friendly, with low pollutant emissions during power gen...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01M8/0245H01M8/0258H01M8/0263H01M8/0247H01M8/1231C25B9/65
CPCH01M8/0245H01M8/0258H01M8/0263H01M8/0247H01M8/1231C25B9/65Y02P70/50
Inventor 刘敏董东东宋琛刘太楷文魁周克崧马文有邓春明
Owner GUANGDONG INST OF NEW MATERIALS
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