Acrylic fiber dope dyed silk oil
A technology of dope dyeing and silk oiling agent, applied in the direction of chemical post-treatment of synthetic polymer rayon filament, can solve the problems of poor antistatic performance of acrylic fiber oiling agent and poor washing resistance.
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Embodiment 1
[0080] 1. Active ingredients of oil
[0081] According to the following formula, the active ingredients of the oil preparation are obtained by mixing the components uniformly:
[0082] Ethoxylated ethyl trilaurate methyl ammonium methyl sulfate, 33 parts;
[0083] Dimethyldiallylammonium chloride-acrylamide copolymer, 33 parts;
[0084] Potassium octadecyl phosphate, 11 parts;
[0085] Polyoxyethylene laurate (9) monoester, 62 parts;
[0086] Soybean oil polyoxyethylene (30) ether, 38 parts.
[0087] in:
[0088] Ethoxylated ethyl trilaurate methyl ammonium methyl sulfate, the structure is as in formula 1, R 1 ~R 3 Both are straight-chain C11 primary alkyl, R 4 is methyl, m 1 ~m 4 Both are 4, X is CH 3 OSO 3 ;
[0089] Dimethyl diallyl ammonium chloride-acrylamide copolymer is a random copolymer (in formula 2, p=5, q is 6, R 5 and R 6 is methyl, y is Cl);
[0090] In the octadecyl phosphate potassium salt, the molar ratio of the monooctadecyl phosphate potassium...
Embodiment 2
[0118] 1. Active ingredients of oil
[0119] According to the following formula, the active ingredients of the oil preparation are obtained by mixing the components uniformly:
[0120] Ethoxylated ethyl trilaurate methyl ammonium methyl sulfate, 66 parts;
[0121] Potassium octadecyl phosphate, 11 parts;
[0122] Polyoxyethylene laurate (9) monoester, 62 parts;
[0123] Soybean oil polyoxyethylene (30) ether, 38 parts.
[0124] in:
[0125] Ethoxylated ethyl trilaurate methyl ammonium methyl sulfate, the structure is as in formula 1, R 1 ~R 3 Both are straight-chain C11 primary alkyl, R 4 is methyl, m 1 ~m 4 Both are 4, X is CH 3 OSO 3 ;
[0126] In the octadecyl phosphate potassium salt, the molar ratio of the monooctadecyl phosphate potassium salt to the dioctadecyl phosphate potassium salt is 1.
[0127] 2. Test
[0128] The test method is the same as in Example 1.
[0129] For the convenience of comparison, the active ingredient composition of the oil agent i...
Embodiment 3
[0131] 1. Active ingredients of oil
[0132] According to the following formula, the active ingredients of the oil preparation are obtained by mixing the components uniformly:
[0133] Dimethyldiallylammonium chloride-acrylamide copolymer, 66 parts;
[0134] Potassium octadecyl phosphate, 11 parts;
[0135] Polyoxyethylene laurate (9) monoester, 62 parts;
[0136] Soybean oil polyoxyethylene (30) ether, 38 parts.
[0137] in:
[0138] Dimethyl diallyl ammonium chloride-acrylamide copolymer is a random copolymer (in formula 2, p=5, q is 6, R 5 and R 6 is methyl, y is Cl);
[0139] In the octadecyl phosphate potassium salt, the molar ratio of the monooctadecyl phosphate potassium salt to the dioctadecyl phosphate potassium salt is 1.
[0140] 2. Test
[0141] The test method is the same as in Example 1.
[0142] For the convenience of comparison, the active ingredient composition of the oil agent is listed in Table 1, and the test results are listed in Table 2.
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