Treatment method of antibiotic pharmaceutical wastewater

A technology of pharmaceutical wastewater and treatment method, which is applied in the fields of natural water body treatment, water/sewage multi-stage treatment, water/sludge/sewage treatment, etc. There are many problems such as degradable substances and complex and changeable organic matter components, so as to achieve the effects of stable operation effect, short start-up time and meeting wastewater discharge standards

Active Publication Date: 2022-04-29
郑琪豫
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

②The organic components contained are complex and changeable, contain many heterocycles and refractory substances, have strong inhibition to microorganisms, high toxicity, deep color and high salt content
[0006] Chinese patent application 20071013952.2 discloses a clean production method for antibiotics, which includes the steps of fermentation liquid dilution and pretreatment-filtration-decolorization-alkaliization crystallization-secondary filtration, etc. The method uses membrane filtration, which leads to high operating costs and cumbersome operations. Inefficient operation of antibiotic industrial wastewater treatment
Each part of the combined process of this method is a relatively simple traditional process, and the water quality standard after treatment is low. It is not suitable for the treatment of pharmaceutical wastewater with complex components, nor can it meet the increasingly stringent environmental protection requirements.

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  • Treatment method of antibiotic pharmaceutical wastewater
  • Treatment method of antibiotic pharmaceutical wastewater
  • Treatment method of antibiotic pharmaceutical wastewater

Examples

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Effect test

Embodiment 1

[0068] An antibiotic pharmaceutical company in Shandong mainly produces β-lactam and quinolone antibiotics. The wastewater indicators are: COD concentration 11000-14000mg / L, BOD concentration 3420-3850mg / L, NH 3 -N concentration 623-927mg / L, pH value 6.5-7.2, antibiotic residue 180-230mg / L. Adopt the treatment method of a kind of antibiotic pharmaceutical waste water that the present invention relates to process, concrete treatment process is as follows:

[0069] (1) Oxidation flocculation sedimentation unit:

[0070] Discharge the antibiotic pharmaceutical wastewater into the adjustment tank, add dilute sulfuric acid or sodium hydroxide, adjust the pH value of the wastewater to 8.0-9.0, discharge the adjusted wastewater into the oxidation reaction tank, add potassium ferrate 7mg / L, and stir the reaction 2-4h, according to the mass ratio of 2:2:1, add polyaluminum chloride, nano-ferric oxide and polyacrylamide 1.25mg / L, stir for 0.5-1.5h, let stand for 1-2h, then discharge th...

Embodiment 2

[0080] Example 2: An antibiotic pharmaceutical company in Jiangsu mainly produces macrolides and aminoglycoside antibiotics. The wastewater indicators are: COD concentration 10800-12600mg / L, BOD concentration 3420-3850mg / L, NH 3 -N concentration 485-522mg / L, pH value 6.2-7.1, antibiotic residue 160-205mg / L. Adopt the treatment method of a kind of antibiotic pharmaceutical waste water that the present invention relates to process, concrete treatment process is as follows:

[0081] (1) Oxidation flocculation sedimentation unit:

[0082] Discharge the antibiotic pharmaceutical wastewater into the adjustment tank, add dilute sulfuric acid or sodium hydroxide, adjust the pH value of the wastewater to 8.0-9.0, discharge the adjusted wastewater into the oxidation reaction tank, add potassium ferrate 3mg / L, and stir the reaction 2-4h, add polyferric chloride, ferrous sulfate, aluminum sulfate and polyacrylamide 2.4mg / L according to the mass ratio of 2:2:1:1, stir for 0.5-1.5h, stand ...

Embodiment 3

[0092] Embodiment 3: An antibiotic pharmaceutical enterprise in Hebei mainly produces β-lactams, macrolides, and quinolones antibiotic drugs, and the wastewater index is: COD concentration 13200-14500mg / L, BOD concentration 4080-4156mg / L, NH 3 -N concentration 605-650mg / L, pH value 5.8-7.0, antibiotic residue 210-255mg / L. Adopt the treatment method of a kind of antibiotic pharmaceutical waste water that the present invention relates to process, concrete treatment process is as follows:

[0093] (1) Oxidation flocculation sedimentation unit:

[0094] Discharge the antibiotic pharmaceutical wastewater into the adjustment tank, add dilute sulfuric acid or sodium hydroxide, adjust the pH value of the wastewater to 8.0-9.0, discharge the adjusted wastewater into the oxidation reaction tank, add potassium ferrate 10mg / L, and stir the reaction 2-4h, add polyferric chloride, polyaluminum chloride and polyacrylamide 2.5mg / L according to the mass ratio of 2:2:1, stir for 0.5-1.5h, let...

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Abstract

The invention discloses a treatment method of antibiotic pharmaceutical wastewater, and belongs to the technical field of wastewater treatment environmental protection. The treatment method is a combined process of a plurality of units, and mainly comprises an oxidation flocculation precipitation unit, an electrochemical-microorganism synergistic degradation unit, a biochemical improvement and enhancement unit, a microorganism enhanced deep treatment unit and a filtration purification discharge unit. The method is reasonable in process combination, low in energy consumption, high in efficiency, stable in operation effect and suitable for treating wastewater generated in the biological fermentation type and chemical synthesis type antibiotic pharmaceutical process.

Description

technical field [0001] The invention relates to a method for treating antibiotic pharmaceutical wastewater, in particular to a method for treating wastewater produced in the process of biological fermentation and chemical synthesis antibiotic pharmaceuticals, and belongs to the technical field of environmental protection. Background technique [0002] Antibiotics are a class of chemicals that inhibit or kill other microorganisms. In the environment, even trace amounts of antibiotics can form or enhance the resistance of pathogens in humans and animals, seriously threatening the function of the ecosystem. In recent years, antibiotics have been detected in water bodies such as sewage treatment plant effluent, surface water, and groundwater, which has become a serious environmental pollution problem. [0003] Antibiotic pharmaceutical wastewater is a type of high-concentration organic wastewater with high pollution load, high toxicity, and strong antibacterial properties. It m...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F9/14C02F103/34C02F101/30
CPCC02F9/00C02F2103/343C02F1/72C02F1/66C02F1/5236C02F1/56C02F3/005C02F3/30C02F1/722C02F1/725C02F2305/026C02F2101/30C02F3/34
Inventor 郑琪豫
Owner 郑琪豫
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