Treatment method of antibiotic pharmaceutical wastewater
A technology of pharmaceutical wastewater and treatment method, which is applied in the fields of natural water body treatment, water/sewage multi-stage treatment, water/sludge/sewage treatment, etc. There are many problems such as degradable substances and complex and changeable organic matter components, so as to achieve the effects of stable operation effect, short start-up time and meeting wastewater discharge standards
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Embodiment 1
[0068] An antibiotic pharmaceutical company in Shandong mainly produces β-lactam and quinolone antibiotics. The wastewater indicators are: COD concentration 11000-14000mg / L, BOD concentration 3420-3850mg / L, NH 3 -N concentration 623-927mg / L, pH value 6.5-7.2, antibiotic residue 180-230mg / L. Adopt the treatment method of a kind of antibiotic pharmaceutical waste water that the present invention relates to process, concrete treatment process is as follows:
[0069] (1) Oxidation flocculation sedimentation unit:
[0070] Discharge the antibiotic pharmaceutical wastewater into the adjustment tank, add dilute sulfuric acid or sodium hydroxide, adjust the pH value of the wastewater to 8.0-9.0, discharge the adjusted wastewater into the oxidation reaction tank, add potassium ferrate 7mg / L, and stir the reaction 2-4h, according to the mass ratio of 2:2:1, add polyaluminum chloride, nano-ferric oxide and polyacrylamide 1.25mg / L, stir for 0.5-1.5h, let stand for 1-2h, then discharge th...
Embodiment 2
[0080] Example 2: An antibiotic pharmaceutical company in Jiangsu mainly produces macrolides and aminoglycoside antibiotics. The wastewater indicators are: COD concentration 10800-12600mg / L, BOD concentration 3420-3850mg / L, NH 3 -N concentration 485-522mg / L, pH value 6.2-7.1, antibiotic residue 160-205mg / L. Adopt the treatment method of a kind of antibiotic pharmaceutical waste water that the present invention relates to process, concrete treatment process is as follows:
[0081] (1) Oxidation flocculation sedimentation unit:
[0082] Discharge the antibiotic pharmaceutical wastewater into the adjustment tank, add dilute sulfuric acid or sodium hydroxide, adjust the pH value of the wastewater to 8.0-9.0, discharge the adjusted wastewater into the oxidation reaction tank, add potassium ferrate 3mg / L, and stir the reaction 2-4h, add polyferric chloride, ferrous sulfate, aluminum sulfate and polyacrylamide 2.4mg / L according to the mass ratio of 2:2:1:1, stir for 0.5-1.5h, stand ...
Embodiment 3
[0092] Embodiment 3: An antibiotic pharmaceutical enterprise in Hebei mainly produces β-lactams, macrolides, and quinolones antibiotic drugs, and the wastewater index is: COD concentration 13200-14500mg / L, BOD concentration 4080-4156mg / L, NH 3 -N concentration 605-650mg / L, pH value 5.8-7.0, antibiotic residue 210-255mg / L. Adopt the treatment method of a kind of antibiotic pharmaceutical waste water that the present invention relates to process, concrete treatment process is as follows:
[0093] (1) Oxidation flocculation sedimentation unit:
[0094] Discharge the antibiotic pharmaceutical wastewater into the adjustment tank, add dilute sulfuric acid or sodium hydroxide, adjust the pH value of the wastewater to 8.0-9.0, discharge the adjusted wastewater into the oxidation reaction tank, add potassium ferrate 10mg / L, and stir the reaction 2-4h, add polyferric chloride, polyaluminum chloride and polyacrylamide 2.5mg / L according to the mass ratio of 2:2:1, stir for 0.5-1.5h, let...
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