Oxide, method for preparing same, protected positive electrode, electrochemical device, and electrochemical cell
A technology of oxides and compounds, applied in the fields of oxides, preparations, protected positive electrodes, electrochemical devices, and electrochemical batteries, can solve problems such as long-lasting stability issues
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Embodiment 1
[0272] LiOH as a lithium precursor, Ta as a tantalum precursor 2 o 5 , as phosphorus precursor (NH 4 ) 2 HPO 4 , and Li as a boron precursor 2 B 4 o 7 According to the composition ratio shown in Table 1, it was mixed stoichiometrically. Acetone was added thereto, and it was pulverized and mixed for 2 hours by using a planetary mill including zirconia balls, whereby a precursor mixture was obtained. The amount of acetone is about 100 parts by weight, based on 100 parts by weight of the total weight of the precursors. When preparing the precursor mixture, LiOH was used in an excess of about 10% by weight to pre-compensate losses during the subsequent heat treatment of the precursor mixture.
[0273] The precursor mixture was heated to 600° C. at a heating rate of about 5° C. / minute, and at this temperature, a first heat treatment was performed in an air atmosphere for 8 hours.
[0274] After this process, the first heat-treated powder was subjected to planetary milling ...
Embodiment 2、 Embodiment 3、 Embodiment 5
[0276] Embodiment 2, embodiment 3, embodiment 5, and embodiment 16-18
[0277] Oxide powders were obtained in the same manner as in Example 1, except as follows: when preparing the precursor mixture, the boron precursor Li was changed2 B 4 o 7 amount to obtain oxide powders with the composition in Table 1.
Embodiment 4、 Embodiment 6、 Embodiment 7
[0278] Example 4, Example 6, Example 7, and Example 19
[0279] Oxide powder was obtained in the same manner as in Example 1, except as follows: when preparing the precursor mixture, Sb as an antimony precursor was used 2 o 3 Instead of Li as boron precursor 2 B 4 o 7 , and the amount thereof was controlled stoichiometrically to obtain oxide powders having the compositions shown in Table 1.
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