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Battery electrolyte, secondary battery and terminal

A technology of secondary battery and electrolyte, which is applied in battery electrolyte, secondary battery and terminal fields, and can solve problems such as inability to meet equipment battery life and standby requirements, ineffective effect, and poor overall performance of the battery.

Pending Publication Date: 2022-06-17
HUAWEI TECH CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The energy density of commercial lithium-ion batteries using graphite as the negative electrode material is close to the upper limit, but it still cannot meet the user's needs for battery life and standby for the above-mentioned devices
Using anode materials such as silicon-based, tin-based and metal with higher theoretical capacity to partially or completely replace graphite anode is an effective way to increase the energy density of batteries. However, such anode materials with high theoretical capacity have high activity due to their large volume expansion. , in the process of charging and discharging the battery, a large amount of electrolyte will be consumed, resulting in low

Method used

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  • Battery electrolyte, secondary battery and terminal
  • Battery electrolyte, secondary battery and terminal
  • Battery electrolyte, secondary battery and terminal

Examples

Experimental program
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Effect test

Example Embodiment

[0070]相应地,本申请实施例还提供上述电池电解液的制备方法,包括以下步骤:

[0071]在惰性环境或密闭环境(如填充氩气的手套箱)中,将上述第一有机溶剂和 / 或第二有机溶剂与共溶剂混合,得到非水有机溶剂;将添加剂加入到非水有机溶剂中,再将充分干燥的电解质盐溶解于非水有机溶剂中,搅拌混合均匀后,得到电池电解液。

[0072]上述制备方法中的各操作可根据现有常规电解液制备工艺实施,其中,关于电解质盐、第一有机溶剂、第二有机溶剂、共溶剂、添加剂等原料的具体选择如前文所述,此处不再赘述。可以理解地,当电池电解液不包含添加剂时,则可以直接向非水有机溶剂中加入电解质盐,搅拌混合均匀后,得到电池电解液。

[0073]本申请实施例还提供一种二次电池,包括正极、负极、隔膜和电解液,其中,电解液采用本申请实施例上述提供的电池电解液。本申请实施例提供的二次电池,由于采用本申请前述的电池电解液,因此能够获得较高的库仑效率和良好循环稳定性。本申请实施方式中,二次电池可以是锂二次电池、钾二次电池、钠二次电池、镁二次电池、锌二次电池、铝二次电池等。本申请实施例提供的二次电池,可用于终端消费产品,如手机、平板电脑、移动电源、便携机、笔记本电脑、数码相机以及其它可穿戴或可移动的电子设备、以及无人机、汽车等产品,以提高产品性能。

[0074]本申请实施方式中,负极可包括碳基负极、硅基负极、锡基负极、锂负极、钠负极、钾负极、镁负极、锌负极和铝负极中的一种或多种。其中碳基负极可包括石墨、硬碳、软碳、石墨烯等;硅基负极可包括硅、硅碳、硅氧、硅金属化合物等;锡基负极可包括锡、锡碳、锡氧、锡金属化合物;锂负极可包括金属锂或锂合金。锂合金具体可以是锂硅合金、锂钠合金、锂钾合金、锂铝合金、锂锡合金和锂铟合金中的至少一种。本申请实施例电解液与金属负极也具有良好的相容性,同时具有耐氧化性,满足高电压特性。

[0075]本申请实施方式中,正极包括能够可逆地嵌入 / 脱嵌金属离子(锂离子、钠离子、钾离子、镁离子、锌离子、铝离子等)的正极活性材料,本申请对正极活性材料的选择无特殊限定,可为现有二次电池常规使用的正极活性材料,为配合制备高电压二次电池,可以采用高电压正极材料。以锂二次电池为例,正极活性材料可以是钴酸锂(LiCoO2)、磷酸铁锂(LiFePO4)、镍钴锰酸锂(LiNi0.6Co0.2Mn0.2)、聚阴离子锂化合物LiM...

Example Embodiment

[0081]实施例1

[0082]一种锂二次电池电解液,包括锂盐(六氟磷酸锂LiPF6),由碳酸乙烯酯(EC)和碳酸甲乙酯(EMC)按质量比50:50混合形成的非水有机溶剂,以及包括化合物A:CF3-S(=O)-N(CH3)2和硫酸乙烯酯(DTD),其中,锂盐(LiPF6)的浓度为1.0mol / L,化合物A和硫酸乙烯酯(DTD)的质量百分含量分别为20%和2%。

[0083]本实施例上述锂二次电池电解液的制备:

[0084]在填充氩气的手套箱中,将EC和EMC混合形成非水有机溶剂,向上述非水有机溶剂中添加化合物A和硫酸乙烯酯(DTD),然后再将充分干燥的锂盐(LiPF6)溶解于上述溶剂中,搅拌混合均匀,制得锂二次电池电解液。

[0085]锂二次电池的制备

[0086]称取质量百分含量为2%聚偏氟乙烯(PVDF)、2%导电剂super P和96%钴酸锂(LiCoO2),依次加入到N-甲基吡咯烷酮(NMP)中,充分搅拌混合均匀,将浆料涂布在铝箔集流体上,烘干、冷压、分切制得正极极片。

[0087]称取质量百分含量为1.5%CMC、2.5%SBR、1%Super P和95%石墨,依次加入到去离子水中,充分搅拌混合均匀,将浆料涂布在铜箔集流体上,烘干、冷压、分切制得负极极片。

[0088]将上述制备的正极极片、负极极片和商用PE隔膜制成电芯,采用聚合物包装,灌注本申请实施例1制备得到的锂二次电池电解液,经化成等工艺后制成软包锂二次电池。

Example Embodiment

[0089]实施例2

[0090]一种锂二次电池电解液,包括锂盐(LiPF6),由碳酸乙烯酯(EC)和碳酸甲乙酯(EMC)按质量比50:50混合形成的非水有机溶剂,以及包括化合物B:CF3CF2CF2CF2-S(=O)2-N(CH3)2和硫酸乙烯酯(DTD),其中,锂盐(LiPF6)的浓度为1.0mol / L,化合物B和硫酸乙烯酯(DTD)的质量百分含量分别为20%和2%。

[0091]本实施例上述锂二次电池电解液的制备:

[0092]在填充氩气的手套箱中,将EC和EMC混合形成非水有机溶剂,向上述非水有机溶剂中添加化合物B和硫酸乙烯酯(DTD),然后再将充分干燥的锂盐(LiPF6)溶解于上述溶剂中,搅拌混合均匀,制得锂二次电池电解液。

[0093]锂二次电池的制作同实施例1。

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Abstract

The invention provides a battery electrolyte, which comprises an electrolyte salt and a non-aqueous organic solvent, and the non-aqueous organic solvent comprises a first organic solvent represented by a formula (I) and/or a second organic solvent represented by a formula (II): R1-S (= O) x-N (-R3)-R2 formula (I), r1-S (= O) x-N (-R3)-S (= O) y-R4 formula (II); r < 1 > and R < 4 > are independently selected from a fluoroalkyl group, a fluoroalkoxy group, a fluoroalkenyl group, a fluoroalkenyloxy group, a fluoroaryl group or a fluoroaryloxy group; r2 and R3 are respectively and independently selected from alkyl, alkoxy, alkenyl, alkenyloxy, aryl or aryloxy; x = 1 or 2; y = 1 or 2; and the total mass content of the first organic solvent and/or the second organic solvent in the electrolyte is 10-90%. The electrolyte contains the first organic solvent and/or the second organic solvent with relatively large mass content, so that the side reaction between the electrolyte and a negative electrode can be reduced, and the coulombic efficiency and the cycle performance of the battery are improved.

Description

[0001] This application claims priority to a Chinese patent application filed with the China Patent Office on December 16, 2020, with application number 202011490108.5 and titled "Battery Electrolyte, Secondary Battery, and Terminal," the entire contents of which are incorporated herein by reference. Applying. technical field [0002] The embodiments of the present application relate to the technical field of secondary batteries, in particular to a battery electrolyte, a secondary battery and a terminal. Background technique [0003] With the development of economy and technology, various products such as portable electronic devices (such as smartphones, digital cameras, and laptops), drones, and electric vehicles are in urgent need of energy storage devices with high energy density. The energy density of commercial lithium-ion batteries using graphite as the negative electrode material is close to the upper limit, but it still cannot meet the user's battery life and standby...

Claims

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Application Information

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IPC IPC(8): H01M10/0569H01M10/0568H01M10/0525
CPCH01M10/0569H01M10/0568H01M10/0525H01M2300/0037H01M10/0567
Inventor 马强邓永红张光照洪响
Owner HUAWEI TECH CO LTD