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Power transmission belt

a transmission belt and power technology, applied in the direction of mechanical equipment, transportation and packaging, other domestic objects, etc., can solve the problem of challenging inventing polymers that actually self-heal cracks, and achieve the effect of improving the growth performance of flex cracks

Active Publication Date: 2020-07-07
THE DOW CHEM CO
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0006]The invention is directed to a power transmission belt or hose or other dynamic article with an elastomeric body that is formed from a rubber composition that includes an ionomeric polymer additive, such as an ethylene-methacrylic acid copolymer or a butyl ionomer. The rubber body exhibits improved crack growth resistance over the same body composition without the ionomer additive. The ionomer additive may be added to the rubber composition at a concentration of up to 50 phr. The invention is also directed to a method of improving crack growth resistance in a rubber composition for a dynamic article by adding an ionomer additive to the rubber composition.

Problems solved by technology

Concepts, realization and outlook: A review,”eXPRESS Polymer Letters, Vol. 2, No. 4 pp 238-250 (2008), concludes that achievements in the field are “far from satisfactory,” and it is very challenging to invent polymers that actually self-heal cracks, whether used alone (inherently) or in an integrated healing system.

Method used

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first embodiment

[0019]In the examples according to the invention, EMAA was used as an additive to put into a fiber-loaded ethylene-propylene-diene elastomer (EPDM) belt compound. DeMattia rubber crack growth test method was used to monitor the material crack growth. The effect of EMAA on the rubber material's static and dynamic mechanical properties was investigated as well. Two EMAA types manufactured by DuPont were used in this work, namely, EMAA and partially neutralized EMAA copolymers.

[0020]Nucrel® is a thermoplastic EMAA random copolymer sold by DuPont under that trade name. The Nucrel® 925 copolymer contains 85 weight % ethylene and 15 weight % methacrylic acid (MA), i.e., 5.4 mole % MA groups randomly distributed along the polymer chains. Nucrel® 925 has a greater average molecular weight than Surlyn® 8920. Nucrel® is commonly used as a thermoplastic molding resin or coating resin in applications involving footwear, wire and cable coating, metal coating, and glass coating. It is tough and f...

second embodiment

[0034]In the examples according to the invention, butyl ionomer was used as an ionic polymer additive to put into a fiber-loaded ethylene-propylene-diene elastomer (EPDM) belt compound. The DeMattia rubber crack growth test method was used to monitor the material crack growth. The effect of the butyl iononier on the rubber material's static and dynamic mechanical properties was investigated as well. “LanXess XLINK TP” butyl ionomer was supplied by LanXess. It is in pellet form, and the specific gravity is 0.93 g / cm3. The preparation of such butyl ionomers is described for example in U.S. Pat. No. 7,662,480 B2, U.S. Pat. No. 7,915,333 B2, and U.S. Pat. Appl. Publ. No. 2010 / 0010140 A1, all to Resendes et al., the contents of which are hereby incorporated herein by reference. Herein, “butyl ionomer” in general refers to any of the ionomeric butyl polymers described in those patent publications.

[0035]Butyl rubber is understood to be a copolymer of an isoolefin and one or more, preferabl...

embodiment 71

[0067]Likewise hoses utilizing rubber compositions according to an embodiment of the invention may be subject to repeated pressure impulses or flexing and therefore benefit from the invention in the form of increased life and / or decreased crack growth rates. A hose typically includes one or more rubber layers and one or more reinforcement layers. The reinforcement layers may be textiles, cords or wires, which may be wrapped or wound or braided. There may also be tie layers to bond various layers together, and the tie layers may also be rubber compositions. FIG. 7 shows exemplary hose embodiment 71, including inner tube layer 72, reinforcement layer 74, and outer cover layer 76. Any of the rubber compositions utilized in the hose may advantageously include an ionomeric polymer additive as described generally herein and in connection with the specific examples herein. The ionomeric polymer additive may be polyethylene-methacrylic acid copolymer or butyl ionomer. The polyethylene-metha...

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Abstract

A power transmission belt or hose or other dynamic article with an elastomeric body comprising a rubber composition that includes an ionomeric polymer additive, such as an ethylene-methacrylic acid copolymer or a butyl ionomer. The rubber body exhibits improved crack growth resistance over the same body composition without the ionomer additive.

Description

BACKGROUND OF THE INVENTIONField of the Invention[0001]This invention relates generally to use of ionomers (ionic polymers) in rubber articles in dynamic applications, more particularly to a power transmission belt with an ionomeric additive in the rubber compound, and specifically to polyethylene-co-methacrylic acid ionomers and butyl ionomers in rubber belts and hose.Description of the Prior Art[0002]Ionomers are multiphase polymers that contain low levels of ionic groups (typically less than 15 mole %) along the hydrocarbon backbone. Small amounts of ionic functionality bound to polymers of low dielectric constant (such as butyl rubber, “BIIR”) can significantly affect material properties: since the non-polar backbone cannot solvate the ionic components, there is significant ion pair aggregation. The ions associate through multiplets of ions to create networks that can have dynamic mechanical properties similar to vulcanizates (covalently crosslinked polymeric materials). Multipl...

Claims

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Application Information

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Patent Type & Authority Patents(United States)
IPC IPC(8): C08L23/16F16G5/20B29D29/08F16G1/08F16G5/06C08K5/09F16G1/28F16G1/06F16G5/04C08L23/08C08L33/02
CPCC08L23/16F16G5/06F16G1/08F16G5/20F16G5/04F16G1/28F16G1/06B29D29/08C08K5/09C08L21/00C08L33/08Y10T428/1386C08L23/0869C08L33/02C08L23/0876
Inventor FENG, YUDING
Owner THE DOW CHEM CO
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