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Electropolishing solution and methods for its use and recovery

a technology of electrolysis solution and electrode, which is applied in the direction of electrolysis components, manufacturing tools, lapping machines, etc., can solve the problems of difficult and expensive disposal, surface finishing of metals, and shaping of metals

Inactive Publication Date: 2005-03-03
ZHU JOSEPH SHOULIAN +4
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The sizing, shaping, and surface finishing of metals for complex parts such as turbine blades, impellers, vessels, and the like has often proven to be a challenge.
However, most commonly used etching solutions employ materials such as hydrofluoric acid that are hazardous to handle and difficult and expensive to dispose of.

Method used

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  • Electropolishing solution and methods for its use and recovery
  • Electropolishing solution and methods for its use and recovery

Examples

Experimental program
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Effect test

examples 1-8

[0035] All of the substrates described below were electropolished in an electrolyte comprising about 95 wt % ethylene glycol, about 5 wt % potassium chloride, and a water content of less than 0.01 wt %. The temperature was 115° C. and the current density was 2 A / cm2 with a voltage was about 30-60V. The electropolishing time was two minutes. The cathodes were 6 centimeter by 6 centimeter by 0.158 centimeter stainless steel 304 plates. The surface roughness was measured with a profilometer.

[0036] For Example 1, the substrate was a titanium 6-4 coupon (titanium 64 is an alloy containing about 6 weight percent aluminum, about 4 weight percent vanadium, and the balance titanium). After electropolishing at a maximum metal removal rate of 0.00125 inches per minute, a smooth and shining surface was obtained. The surface roughnesses before and after electropolishing were 50 and 15 microinches, respectively.

[0037] For Example 2, the substrate was a titanium 6-4 engine blade. After electropo...

example 9

[0044] 65 milliliters (ml) spent electropolishing solution comprising ethylene glycol and potassium chloride in a 95:5 ratio by weight and 35 wt % titanium-containing solid was heated to an elevated temperature of 115° C. in a glass beaker. While at the elevated temperature, the spent electropolishing solution was sparged with compressed air for one hour. Following sparging, the metal-containing solid particles began to settle. After about 20 minutes it was observed that about 20 ml of clear electropolishing solution was formed in the beaker while about 45 ml of a sediment bed remained at the bottom of the beaker.

example 10

[0045] In order to demonstrate the effectiveness of recovered electropolishing solution, spent electropolishing solution containing about 35 wt % titanium-containing solid, ethylene glycol and potassium chloride (in a weight ratio of 95:5, respectively) was mixed with water. The spent electropolishing solution to water ratio was maintained at 10:90 by weight. After distillation, the recovered electropolishing solution was reused to electropolish titanium metal and no changes in the electropolishing behavior were observed.

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Abstract

An electrolyte solution containing an alkylene glycol and a chloride salt is useful for electropolishing metal substrates. An electropolishing method using the electrolyte solution is effective for polishing a varied of metals, including titanium and noble metals. The method avoids the handling and disposal challenges associated with previous methods using etching solutions containing hydrofluoric acid. A method of recycling the spent electrolyte solution is also described.

Description

BACKGROUND [0001] The sizing, shaping, and surface finishing of metals for complex parts such as turbine blades, impellers, vessels, and the like has often proven to be a challenge. One commonly used method for shaping and finishing metals and metal alloys is etching. However, most commonly used etching solutions employ materials such as hydrofluoric acid that are hazardous to handle and difficult and expensive to dispose of. An alternative to etching is electropolishing, but there is a need for electropolishing materials and methods that achieve high surface smoothness, and are less expensive, less corrosive, and more environmentally friendly than current etching materials and methods. BRIEF SUMMARY [0002] An electropolishing solution effective for surface finishing of metals comprises about 75 to about 99 weight percent of an alkylene glycol; and about 1 to about 25 weight percent of a chloride salt selected from the group consisting of alkali metal chlorides, alkaline earth metal...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): B23H3/08B24B37/04C25F3/16C25F7/02
CPCB23H3/08C25F7/02C25F3/16B24B37/042
Inventor ZHU, JOSEPH SHOULIANKIM, BANG MOSCHWORM, JEFFERY L.GREEN, KEVIN C.GUILMETTE, PAUL
Owner ZHU JOSEPH SHOULIAN
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