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Acrylic and para-aramid pulp and processes of making same

Inactive Publication Date: 2005-12-29
EI DU PONT DE NEMOURS & CO
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0020] thereby producing an acrylic and para-aramid pulp with the acrylic and the para-aramid fibrous structures having an average maximum dimension of no more than

Problems solved by technology

Asbestos fibers have historically been used as reinforcement materials, but due to their health risks, replacements have been made or proposed.
However, many of these replacements do not perform as well as asbestos in one way or another.
Despite the numerous disclosures proposing lower cost alternative reinforcement materials, many of these proposed products do not adequately perform in use, cost significantly more than currently commercial products, or have other negative attributes.

Method used

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  • Acrylic and para-aramid pulp and processes of making same
  • Acrylic and para-aramid pulp and processes of making same
  • Acrylic and para-aramid pulp and processes of making same

Examples

Experimental program
Comparison scheme
Effect test

first embodiment

I. First Embodiment of the Inventive Process

[0055] In a first embodiment, the process for making an acrylic and para-aramid pulp comprises the following steps. First, pulp ingredients are combined, added or contacted together. Second, the combined pulp ingredients are mixed to a substantially uniform slurry. Third, the slurry is simultaneously refined or co-refined. Fourth, water is removed from the refined slurry.

Combining Step

[0056] In the combining step, the pulp ingredients are preferably added together in a container. The pulp ingredients include (1) acrylic fiber, (2) para-aramid fiber, (3) optionally substantially or completely fibril-free, granular, para-aramid particles, (4) optionally other minor additives, and (5) water.

Acrylic Fiber

[0057] The acrylic fiber is added to a concentration of 10 to 90 wt % of the total solids in the ingredients, preferably 25 to 60 wt % of the total solids in the ingredients, and most preferably 25 to 55 wt % of the total solids in the in...

second embodiment

II. Second Embodiment of the Inventive Process

[0072] In a second embodiment, the process for making the acrylic fiber and para-aramid pulp is the same as the first embodiment of the process described above with the following differences.

[0073] Prior to combining all ingredients together, either the acrylic fiber or the para-aramid fiber, or both the acrylic fiber and the para-aramid fiber, may need to be shortened. This is done by combining water with the fiber ingredient. Then the water and fiber are mixed to form a first suspension and processed through a first disc refiner to shorten the fiber. The disc refiner cuts the fiber to an average length of no more than 10 cm. The disc refiner will also partially fibrillate and partially masticate the fiber. The other fiber, that was not previously added, can be shortened this way too forming a second processed suspension. Then the other fiber (or the second suspension, if processed in water) is combined with the first suspension.

[0074...

example 1

[0097] In this example of the invention, the pulp of this invention was produced from a feedstock of para-aramid fiber and acrylic staple. Acrylic staple having a cut length of 2 inches and having a filament linear density of 3 dpf (3.3 dtex per filament) was obtained from Solutia, Inc., with offices in St. Louis, Mo. Para-aramid fiber in the form of commercially available KEVLAR® brand floc, Style 1F178, having a ¼″ cut length, was obtained from E. I. de Pont de Nemours and Company with offices in Wilmington, Del.

[0098] Acrylic staple and water together were fed directly into a Sprout-Waldron 12″ Single Disc Refiner using a 10 mil plate gap setting and pre-pulped to reach an acceptable processing length in the range of 13 mm.

[0099] The pre-pulped acrylic fiber and the cut para-aramid fiber plus water were then combined into a highly agitated mixing tank at a solids concentration of 50 wt % para-aramid fiber and 50 wt % acrylic staple and mixed to form a uniform, pumpable slurry o...

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Abstract

The present invention relates to acrylic and para-aramid pulp for use as reinforcement material in products such as seals and friction materials. The pulp comprises (a) irregularly shaped, acrylic fibrous structures, (b) irregularly shaped, para-aramid fibrous structures, and (c) water, whereby acrylic fibrils and / or stalks are substantially entangled with para-aramid fibrils and / or stalks. The invention further relates to processes for making such acrylic and aramid pulp.

Description

BACKGROUND OF THE INVENTION [0001] 1. Field of the Invention [0002] This invention relates to acrylic and para-aramid pulp for use as reinforcement material in products, such as seals and friction materials. The invention further relates to processes for making such pulp. [0003] 2. Description of Related Art [0004] Fibrous and non fibrous reinforcement materials have been used for many years in friction products, sealing products and other plastic or rubber products. Such reinforcement materials typically must exhibit high wear and heat resistance. [0005] Asbestos fibers have historically been used as reinforcement materials, but due to their health risks, replacements have been made or proposed. However, many of these replacements do not perform as well as asbestos in one way or another. [0006] Research Disclosure 74-75, published February 1980, discloses the manufacture of pulp made from fibrillated KEVLAR® brand para-aramid fibers of variable lengths and use of such pulp as a rei...

Claims

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Application Information

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IPC IPC(8): D04H5/00D21H13/18D21H13/26
CPCD21H13/26D21H13/18Y10T428/249924D21H5/205
Inventor CONLEY, JILL A.MERRIMAN, EDMUND A.
Owner EI DU PONT DE NEMOURS & CO