Apparatus for direct plating on resistive liners
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[0029] U.S. Published Application No. 2004 / 0069648 A1, the entire disclosure of which is incorporated herein by reference, discloses a method for the direct electroplating of a relatively low resistive metal, such as copper, on a resistive substrate. That method allows plating of copper directly on at least one liner layer, where the liner layer(s) act as a diffusion barrier for copper into the dielectric. These diffusion barrier layers typically have a sheet resistance, Rs, which can be several orders of magnitude higher than for currently used copper seed layers. For example, a typical diffusion barrier layer sheet resistance may be in the range of 5 to 300Ω / square, whereas copper seed layers may have a resistance in the range of 1 to 3Ω / square.
[0030] The method disclosed in U.S. Published Application No. 2004 / 0069648 A1 can be described as direct plating or seedless plating. This method is based on the fundamental concept that the driving force for plating, known as the overpote...
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