Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Cellulose ester compositions

a technology of cellulose esters and compositions, applied in the field of cellulose ester chemistry, can solve the problems of difficult dispersibility of cellulose esters into elastomers

Inactive Publication Date: 2011-12-29
EASTMAN CHEM CO
View PDF3 Cites 9 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

The data show that without the use of a plasticizer, the cellulose ester did not disperse as well through the elastomer as shown by the poor Phillips Dispersion data. Further, the Mooney viscosities of the compositions containing both cellulose ester and plasticizer were lower than when plasticizer was not utilized. This shows that in the presence of the plasticizer, CEs acted as a processing aid and lowered Mooney viscosity. Furthermore, the break stress and wear was also improved over compositions without plasticizer, presumably indicating that in presence of the plasticizers, CEs can disperse into finer particles and can improve the properties that are dependent on particle size and / or surface area.

Problems solved by technology

These factors make dispersion of cellulose esters into elastomers difficult via most industrially utilized melt mixing process.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Cellulose ester compositions

Examples

Experimental program
Comparison scheme
Effect test

example 1

Non-Reactive Compatibilizer in Cellulose Ester / Elastomer Compositions

[0097]Experiments were conducted to evaluate certain non-reactive compatibilizer in cellulose ester / elastomer compositions. In Table 1, the non-reactive compatibilizers evaluated are listed.

TABLE 1CompatibilizerCompoundMW1#CH22#EO3% EOMP4 ° C.Tergitol 15-S-957015963Tergitol 15-S-301400153085~50Polyethylene920321250~100block polyethyleneglycol5Polyethylene2250324080~85block polyethyleneglycolPolyethylene1400501650~100block polyethyleneglycol1Molecular Weight2Number of carbon atoms3Number of Ethylene Oxide groups4Melting Point5PE Block PEG

Tergitol 15-S-9 and Tergitol 15-S-30 are secondary alcohol ethoxylates obtained from Dow Chemical in Midland, Mich. The polyethylene block polyethylene glycol compatibilizers were obtained from Sigma-Aldrich. Although not wishing to be bound by theory, it is believed that the ethylene oxide units of the above compounds plasticizes the cellulose acetate butyrate and the hydrocarbon c...

example 2

Reactive Compatabilizers in Cellulose Ester / Elastomer Compositions

[0100]Reactive compatibilizers were evaluated to improve the mixing of CAB in styrene butadiene rubber (SBR). The reactive compatibilizers were selected such that they contained reactive groups that can react with the CAB and the rest of the molecule is compatible with the SBR. The molecular weight, and the type and concentration of the reactive moiety were varied.

TABLE 5BrandChemicalReactiveAcid number,NameCompositionManufacturerMoietyMwmg KOH / gmTm, ° C.CommentsSMAStyreneSartomer / CrayMaleic9500285180Styrene:MA =3000maleicValleyanhydride(Tm ~3:1anhydrideTg +copolymer55)EastmanMaleicEastmanMaleic4700015156G-3015anhydrideanhydridegraftedpolypropyleneEpoleneMaleicWestlakeMaleic1580045158E-43anhydrideChemicalsanhydridegraftedpolypropyleneLotaderRandomArkemaMaleic17100MaleicMAHterpolymer ofanhydrideanhydride8200Ethylene,~2.8 wt %Acrylic esterEsterand Maleic~6.5 wt %anhydrideLotaderRandomArkemaGlycidylNA65GlycidylGMA AXterp...

example 3

Use of Plasticizers

[0105]Masterbatches of cellulose esters with two different plasticizers at various loadings were prepared in an attempt to lower the Tg of the cellulose esters such that their flow temperature is lower than the typical rubber processing temperature of 150° C. Compounding in a Brabender mixer at 150° C. for 10 minutes at 100 rpm followed by cryogrinding yielded the masterbatches shown in Table 10.

TABLE 10Tg ofTg ofMasterCE,QuantityType ofQuantity ofmasterBatchCE1° C.of CE, gPlasticizerplasticizer, gBatch, ° C.MB 1CAB 551-0.2101100Eastman 16821084MB 2CAB 553-0.4136100Eastman 1682585MB 3CAB 381-0.1123100Eastman 1682087MB 4CAB 381-2133100Eastman 1682595MB 5CAB 553-0.4136100Poly (ethylene2565glycol)3MB 6CAB 381-2133100Poly (ethylene2570glycol)MB 7CAP 504-0.2159100Poly (ethylene3093glycol)MB 8CAP 482-0.5142100Poly (ethylene2590glycol)MB 9CA 398-3180100Poly (ethylene40109glycol)1CE—Cellulose Ester2bis(2-ethylhexyl)-1,4-benzene dicarboxylate3polyethylene glycol - molecula...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
Temperatureaaaaaaaaaa
Percent by massaaaaaaaaaa
Specific volumeaaaaaaaaaa
Login to View More

Abstract

A cellulose ester composition is provided comprising at least one cellulose ester and at least one additive selected from the group consisting of a compatibilizer, and a plasticizer. Processes for producing the cellulose ester composition are also provided. In another embodiment, a cellulose ester / elastomer composition is provided comprising at least one elastomer, at least one cellulose ester; and at least one additive; wherein the additive is at least one selected from the group consisting of a compatibilizer and a plasticizer. Processes for producing the cellulose ester / elastomer composition is also provided as well as articles comprising the cellulose ester / elastomer composition.

Description

RELATED APPLICATIONS[0001]This application claims priority from U.S. Provisional Pat. Appln. No. 61 / 359,582, filed Jun. 29, 2010, the disclosure of which is incorporated herein by reference in its entirety.FIELD OF THE INVENTION[0002]This invention belongs to the field of cellulose ester chemistry, particularly to cellulose esters comprising compatibilizers and optionally, plasticizers. The invention also belongs to the field of cellulose ester / elastomer compositions comprising at least one elastomer and at least one additive wherein the additive is at least one selected from the group consisting of a compatibilizer and a plasticizer. Processes for producing the cellulose ester compositions and the cellulose ester / elastomer compositions are also provided.BACKGROUND OF THE INVENTION[0003]This invention relates to the dispersion of cellulose esters in elastomers as small particles to improve the mechanical and physical properties of the elastomer. Polar cellulose esters (CE) are incom...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
IPC IPC(8): C08L1/14
CPCC08L1/10C08L1/12C08L1/14C08L1/16C08L1/18C08L1/20C08L1/22C08L9/06C08L1/32C08L1/24C08L23/08C08J5/00C08K5/00C08L23/00
Inventor HELMER, BRADLEY JAMESBASU, SOUMENDRA KUMARWOOD, MATTHEW DAVIEDAGENHART, CHRIS STANLEYDE WIT, JOS SIMONTESTA, CARLO ANTONYSHELBY, MARCUS DAVID
Owner EASTMAN CHEM CO
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic, Popular Technical Reports.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap|About US| Contact US: help@patsnap.com