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Bulk nickel-based chromium and phosphorus bearing metallic glasses with high toughness

a technology of phosphorus and metallic glasses, which is applied in the field of high toughness, can solve the problem of forming a metallic glass with a relatively low toughness

Active Publication Date: 2014-11-27
APPLE INC
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, the alloy forms a metallic glass which has a relatively low toughness at the peak of glass formability of the alloy.

Method used

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  • Bulk nickel-based chromium and phosphorus bearing metallic glasses with high toughness
  • Bulk nickel-based chromium and phosphorus bearing metallic glasses with high toughness
  • Bulk nickel-based chromium and phosphorus bearing metallic glasses with high toughness

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Embodiment Construction

[0043]The present disclosure may be understood by reference to the following detailed description, taken in conjunction with the drawings as described below. It is noted that, for purposes of illustrative clarity, certain elements in various drawings may not be drawn to scale.

Description of Alloy Compositions and Metallic Glass Compositions

[0044]In accordance with the provided disclosure and drawings, Ni—Cr—Nb—P—B alloys are provided that lie along a well-defined compositional ridge that requires very low cooling rates to form metallic glass, thereby allowing for bulk metallic glass formation such that metallic glass rods with diameters greater than at least 6 mm can be formed. In particular embodiments, by controlling the relative concentrations of Ni, Cr, and Nb, and by incorporating minority additions of about 16.5 atomic percent of P and about 3 atomic percent of B, these alloys can form metallic glass rods with diameters greater than 6 mm. The present compositional ridge provid...

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Abstract

A Ni-based bulk metallic glass forming alloy is provided. The alloy includes Ni(100-a-b-c-d)CraNbbPcBd, where an atomic percent of chromium (Cr) a ranges from 3 to 13, an atomic percent of niobium (Nb) b is determined by x−y*a, where x ranges from 3.8 to 4.2 and y ranges from 0.11 to 0.14, an atomic percent of phosphorus (P) c ranges from 16.25 to 17, an atomic percent of boron (B) d ranges from 2.75 to 3.5, and the balance is nickel (Ni), and where the alloy is capable of forming a metallic glass object having a lateral dimension of at least 6 mm, where the metallic glass has a stress intensity factor at crack initiation when measured on a 3 mm diameter rod containing a notch with length between 1 and 2 mm and root radius between 0.1 and 0.15 mm, the stress intensity factor being at least 70 MPa m1 / 2.

Description

CROSS-REFERENCE TO RELATED APPLICATIONS[0001]The present application claims priority to U.S. Provisional Patent Application No. 61 / 720,015, entitled “Bulk Nickel-Based Chromium and Phosphorus Metallic Glasses with High Toughness”, filed on Oct. 30, 2012, which is incorporated herein by reference in its entirety.TECHNICAL FIELD[0002]The present disclosure is directed to Ni—Cr—Nb—P—B glasses capable of forming bulk metallic glass rods with diameters greater than 3 mm and as large as 11 mm or greater.BACKGROUND[0003]Ni—Cr—Nb—P—B alloys capable of forming bulk metallic glass rods with diameters of 3 mm or greater have been disclosed in U.S. patent application Ser. No. 13 / 592,095, entitled “Bulk Nickel-Based Chromium and Phosphorus Bearing Metallic Glasses”, filed on Aug. 22, 2012, the disclosure of which is incorporated herein by reference in its entirety. In that application, a peak in glass forming ability is identified at chromium (Cr) content ranging from 8.5 to 9 atomic percent, ni...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): C22C45/04
CPCC22C45/04C22C19/05C22C19/058C22C1/11
Inventor NA, JONG HYUNFLOYD, MICHAELDEMETRIOU, MARIOS D.JOHNSON, WILLIAM L.GARRETT, GLENNLAUNEY, MAXIMILIEN
Owner APPLE INC
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