Ape-free laundry emulsifier

a laundry emulsifier and ape-free technology, applied in the field of detergents, can solve the problems of contaminating water, vegetation and marine life, disfavored apes, and not readily biodegradable npe, and achieve the effect of high conten

Active Publication Date: 2015-02-26
ECOLAB USA INC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

The composition achieves effective soil removal and emulsification, matching or exceeding the performance of NPE-containing detergents while being environmentally friendly and biodegradable, suitable for both laundry and hard surface cleaning applications.

Problems solved by technology

However, while effective, APEs are disfavored due to environmental concerns.
Both NP and NPEs exhibit estrogen-like properties and may contaminate water, vegetation and marine life.
NPE is also not readily biodegradable and remains in the environment or food chain for indefinite time periods.

Method used

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  • Ape-free laundry emulsifier
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  • Ape-free laundry emulsifier

Examples

Experimental program
Comparison scheme
Effect test

example 1

[0185]A tergotometer test procedure was employed to measure detergency of test compositions according to the invention. A tergotometer along with 500 mL pots and water bath were employed. First, unwashed swatches from the lot numbers to be used in the test are read on the Konica Minolta Spectrophotometer model CM-3600d to establish the average initial (before washing) L value. A sampling of 25 of each swatch type is used. The desired wash temperature is programmed into the Tergotometer and its water bath is allowed to heat up to that temperature. 500 mL of the desired water type is added to each Tergotometer pot and allowed to equilibrate to the desired temperature.

[0186]Test swatches (clean) were dipped into the solution of interest (e.g. chili oil, etc.). The soiled swatches are dried overnight before the detergency experiment. The following standard, commercially available (EMPA) soiled swatches were used for baseline testing in the Examples, as shown in Table 2.

TABLE 2SampleSoil...

example 2

[0191]The beneficial results obtained in Example 1 were further analyzed in the presence of a builder product to increase the pH conditions of the laundry application. The methods of Example 1 were employed along with the use of an alkalinity-containing builder composition (commercially-available from Ecolab, Inc.). The building provides to the cleaning system a source of sodium hydroxide and a polyacrylate (to control build-up caused by the hard water employed). The pH of the cleaning systems was increased from about neutral to a pH between about 11.3 to about 11.5 with the addition of the builder component, with all other test conditions remaining constant.

[0192]As shown in FIG. 2 both test compositions F43 and F64 provided improved soil removal (shown as % L*diff) over both control formulations, including the NPE-containing and NPE-free compositions. The inclusion of a building to increase the pH conditions of the laundry cycle provided increased soil removal (shown as % L*diff) ...

example 3

[0194]Additional testing of the compositions according to the invention were conducted at additional higher temperature ranges. The methods of Example 1 were further conducted using the laundry emulsifiers (F43, F64) in comparison to controls (NPE-containing, NPE-free) at temperatures of 30° C., 40° C., and 50° C.

[0195]FIG. 4 shows the results of the test formulations on EMPA 104 swatches at varying temperatures. FIG. 5 shows the results of the test formulations on EMPA 106 swatches at varying temperatures. FIG. 6 shows the results of the test formulations on EMPA 101 swatches at varying temperatures. The test compositions outperform the controls at all temperatures analyzed.

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Abstract

A detergent emulsifier for laundry and other hard surface cleaning using an APE-free surfactant blend is disclosed. The emulsifier system is efficacious for removal of oily soils and greasy food removal. The compositions according to the invention include linear and branched fatty alcohol ethoxylates and ethoxylate propoxylate block copolymers. Methods of using the same are disclosed.

Description

CROSS REFERENCE TO RELATED APPLICATIONS[0001]This is a Continuation Application of U.S. Ser. No. 13 / 689,876 filed Nov. 30, 2012, herein incorporated by reference in its entirety.FIELD OF THE INVENTION[0002]The present invention relates to a detergent for laundry and other hard surface cleaning system which uses an APE-free surfactant blend. In particular, an emulsifier system including linear and branched fatty alcohol ethoxylates and ethoxylate propoxylate block copolymers is provided for laundry and other hard surface cleaning applications providing oily soil and greasy food removal.BACKGROUND OF THE INVENTION[0003]Conventional detergents used in the laundering industries and various other cleaning applications, particularly those intended for institutional use, generally contain alkyl phenol ethoxylates (APEs). APEs are used in detergents as a cleanser and a degreaser for their effectiveness at removing soils containing grease from a variety of surfaces. Commonly used APEs includ...

Claims

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Application Information

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Patent Type & AuthorityApplications(United States)
IPC IPC(8): C11D1/825C11D1/76B08B3/08C11D1/722
CPCC11D1/825B08B3/08C11D1/76C11D1/722C11D1/008C11D1/72C11D3/2006C11D3/2041C11D3/2065C11D3/2068C11D3/3707C11D1/8255B08B1/143B08B1/00
InventorSOONTRAVANICH, SUKHWANHUBIG, STEPHANZHANG, YANG
OwnerECOLAB USA INC