Flexible chemical production platform

a flexible and chemical technology, applied in the field of chemicals, can solve the problems of not being able to easily accommodate or integrate the production of other chemicals, and achieve the effect of high reactive and high production efficiency

Inactive Publication Date: 2018-02-01
NOVOMER INC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0006]Provided herein are methods and systems that consolidate multiple product trains into a single facility that would allow producers to respond quickly to changes in market demand for each product and reduce their present reliance upon the transportation of certain production intermediates, some of which like acrylic acid are highly reactive and dangerous.

Problems solved by technology

Industrial-scale production of most chemicals generally relies upon devoted synthetic precursors, chemical transformations and production plants that cannot easily accommodate or integrate the production of other chemicals.

Method used

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Experimental program
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embodiment 4

5. The system of embodiment 4, further comprising an oxidative reactor, comprising an inlet fed by ethylene, an oxidative reaction zone that converts at least some of the ethylene to EO, and an outlet which provides an outlet stream comprising the EO, which is fed to the inlet of the central reactor.

6. The system of embodiment 1, wherein the first C3 product and the second C3 product are independently selected from an α,β-unsaturated acid, an α,β-unsaturated ester, an α,β-unsaturated amide, a polymer and 1,3-propanediol (PDO).

7. The system of embodiment 6, wherein the first C3 product is polypropiolactone (PPL).

8. The system of embodiment 6, wherein the first C3 product is acrylic acid.

9. The system of embodiment 1, wherein the first C3 product is PPL, and the system further comprises a third C3 reactor, comprising an inlet fed by the outlet stream comprising PPL of the first C3 reactor, a third C3 reaction zone that converts at least some of the PPL to a third C3 product, and an ou...

embodiment 14

15. The system of embodiment 14, wherein the system produces the AA from ethylene.

16. The system of embodiment 15, comprising:[0910]an oxidative reactor, comprising an inlet fed by ethylene, an oxidative reaction zone that converts at least some of the ethylene to ethylene oxide (EO), and an outlet which provides an outlet stream comprising the EO, which is fed to an inlet of a central reactor,[0911]the central reactor, comprising the inlet fed by the outlet stream comprising the EO from the oxidative reactor and a carbon monoxide (CO) source, a central reaction zone that converts at least some of the EO to beta propiolactone (BPL), and an outlet which provides an outlet stream comprising the BPL,[0912]one or more of:[0913](i) a first C3 reactor, comprising an inlet fed by the outlet stream comprising BPL of the central reactor, a first C3 reaction zone that converts at least some of the BPL to a polypropiolactone (PPL), and an outlet which provides an outlet stream comprising the P...

embodiment 41

42. The system of embodiment 41, wherein the system is configured to produce AA at about 200 to about 800 kilotons per annum (kta).

43. The system of any one of embodiments 32 to 42, wherein the first C4 product is succinic anhydride.

44. The system of any one of embodiments 32 to 42, wherein the first C4 product is succinic anhydride, and the system further comprises:[0962]a second C4 reactor comprising:[0963]an inlet configured to receive the outlet stream comprising succinic anhydride of the first C4 reactor,[0964]a second C4 reaction zone configured to convert at least some of the succinic anhydride to a second C4 product, and[0965]an outlet configured to provide an outlet stream comprising the second C4 product.

45. The system of embodiment 44, wherein the second C4 product is succinic acid, 1,4 butanediol (BDO), tetrahydrofuran (THF) or gamma butyrolactone (GBL).

46. A system, comprising:[0966]an ethylene source;[0967]a carbon monoxide (CO) source;[0968]an alcohol source;[0969]an ...

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Abstract

Disclosed are integrated systems and methods for the conversion of epoxides to beta lactones and to multiple C3 products and / or C4 products.

Description

CROSS-REFERENCE TO RELATED APPLICATIONS[0001]This application claims priority to U.S. Provisional Patent Application No. 62 / 116,234, filed Feb. 13, 2015, which is incorporated herein by reference in its entirety.FIELD[0002]The present disclosure relates generally to the production of chemicals, and more specifically to the conversion of epoxides to various C3 products and / or C4 products, such as acrylic acid and acid anhydrides.BACKGROUND[0003]Industrial-scale production of most chemicals generally relies upon devoted synthetic precursors, chemical transformations and production plants that cannot easily accommodate or integrate the production of other chemicals. For example, production of three-carbon-containing C3 chemicals, such as acrylic acid (AA) and esters thereof, and that of four-carbon-containing C4 chemicals, such as succinic anhydride (SA), generally proceed from distinct precursors via unrelated transformations that require specialized plants and methods.[0004]Acrylic a...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): B01J19/24C07D307/33C07D307/08C07C29/149B01J19/00C08G63/78C07D307/60C08J11/12C07C51/09C07D305/12C07C67/03C08G63/08
CPCB01J19/2445C07C67/03C07D307/33C07D307/08C07C29/149C08G63/08C08G63/785C07D307/60C08J11/12C07C51/09C07D305/12B01J19/245B01J19/0006C08J2367/04B01J2219/00049B01J2219/24C07C29/132C07C29/147C07D301/03C08G63/78C07C69/54C07C31/207C07C57/04C07C51/252B01J8/02C07C55/10
Inventor SOOKRAJ, SADESH H.
Owner NOVOMER INC
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