Process for producing a high stability desulfurized heavy oils stream

a technology of desulfurized heavy oil and process, which is applied in the direction of thermal non-catalytic cracking, water treatment refining, and aqueous alkaline solution raffination, etc., can solve the problems of difficult removal of sulfur, many refineries lack the conversion equipment necessary to process these heavier crude oils, and the inability of partial conversion techniques to perform significant conversion

Inactive Publication Date: 2013-12-24
EXXON RES & ENG CO
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0014]In a preferred embodiment, the portion of the light ends fraction used in the incompatibility stream has a T5 boiling point of at least 80° F. and a T95 boiling point of less than 450° F. In a more preferred embodiment, the amount of the incompatibility stream added to the conversion product stream is sufficient to lower the solubility number (SBN) of the combined incompatibility stream and conversion product stream by at least 10. In yet an even more preferred embodiment, the solubility number (SBN) of the self-compatible product stream is at least about 20 greater than the solubility number (SBN) of the conversion product stream.

Problems solved by technology

A significant portion of the sulfur contained in these heavy oils is in the form of heteroatoms in polycyclic aromatic molecules, comprised of sulfur compounds such as dibenzothiophenes, from which the sulfur is difficult to remove.
Many refineries lack the conversion equipment necessary to process these heavier crude oils.
Partial conversion techniques are often severely hampered in their ability to perform significant conversion due to compatibility problems with the partially converted product.
For example, one problem that exists in the industry is that heavy oil streams can be difficult to process due to the tendency of asphaltene components to precipitate during processing.
This can lead to fouling of the process equipment and / or catalyst, or alternatively can require expensive and complicated facilities to handle and process a feed with increased solids content.
A further problem exists in that many heavy oils, such as crudes, synthetic crudes, rough crude distillation cuts, and bitumens often need to be transported over pipelines spanning hundreds of miles for further processing at refineries and other related upgrading facilities.

Method used

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  • Process for producing a high stability desulfurized heavy oils stream
  • Process for producing a high stability desulfurized heavy oils stream
  • Process for producing a high stability desulfurized heavy oils stream

Examples

Experimental program
Comparison scheme
Effect test

example 1

Light Ends Fractionation

[0065]By way of example, molecular property modeling was carried out on a theoretical composition of a paraffin froth treated feed which had been converted via an alkali metal desulfurization process to an API of 21.7. In this example, the desulfurization results in about 70% 1050F+ conversion. The total liquid product stream was then theoretically distilled to varying percentages to demonstrate the effect of distillation on the API and the SBN of the final system. The results of the calculation are shown in Table 1 below:

[0066]

TABLE 1Removal via topping of light ends effects on API and SBN%RemovedAPISBNΔ APIΔ SBN0%21.789.41%20.991.1−0.8+1.72%20.292.6−1.5+3.23%19.594.1−2.2+4.74%19.095.4−2.7+6.0

[0067]It may be seen that the removal of only 4% of the lightest liquids results in an API decrease of 2.7 to 19, the pipeline specification, and an SBN increase of 6 units. If a larger than 6 unit SBN increase were desired, it would be desirable to convert the product ...

example 2

Example of Trim Deasphalting

[0068]To determine the degree of product losses a trim deasphalting / compatibilization scheme might involve, a series of conversion products generated using KOH as an alkali metal reagent catalyst were deasphalted using heptane and using a 1:1 mix of heptane and toluene. The deasphalting was done using a 10:1 ratio of solvents to oil. The heptane deasphalting is expected to result in a final product that has an IN value (insolubility number) of approximately 0, while the 1:1 heptane:toluene deasphalting is expected to result in a product having an IN of approximately 50. At the IN=50 level, a heavy oil product would be not only self compatible, but also generally compatible with most other crude oils (those with SBN values >70).

[0069]Table 2 shows the results from the trim deasphalting runs. All of the conversion products were first diluted in toluene and filtered to remove the toluene insolubles (shown in the table as % TI). All of the conversion products...

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Abstract

Self-compatible heavy oil streams are produced from converted and / or desulfurized fractions. In a preferred embodiment, an incompatibility stream is added to the converted and / or desulfurized stream to reduce the solubility number of the stream. After using a water wash to remove incompatible material, a lighter fraction is removed from the stream to increase the solubility number.

Description

[0001]This application claims the benefit of U.S. Provisional Application No. 61 / 284,529 filed Dec. 18, 2009.FIELD OF THE INVENTION[0002]The present invention relates to a process for conversion, such as desulfurization, of heavy oil feedstreams and improving the self-compatibility of the stream.DESCRIPTION OF RELATED ART[0003]Heavy oils and bitumens make up an increasing percentage of available liquid hydrocarbon resources. As the demand for hydrocarbon-based fuels has increased, the need for improved processes for desulfurizing heavy oil feedstreams has increased as well as the need for increasing the conversion of the heavy portions of these feedstreams into more valuable, lighter fuel products. These heavy oil feedstreams include, but are not limited to, whole and reduced petroleum crudes, shale oils, coal liquids, atmospheric and vacuum residua, asphaltenes, deasphalted oils, cycle oils, FCC tower bottoms, gas oils, including atmospheric and vacuum gas oils and cooker gas oils,...

Claims

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Application Information

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Patent Type & Authority Patents(United States)
IPC IPC(8): C10G19/00C10G19/073C10G19/08
CPCC10G9/00C10G19/02C10G29/06C10G31/08
Inventor LETA, DANIEL P.VANN, WALTER D.FERRUGHELLI, DAVID T.SIROTA, ERIC B.FREUND, HOWARD
Owner EXXON RES & ENG CO
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