The invention discloses a composite anticorrosive pigment and a preparation method and application thereof, and belongs to the field of pigments, which comprises the following steps: reacting sodium silicate and sulfuric acid used as raw materials at normal temperature and normal pressure to synthesize low-water-pore low-oil-absorption silicon dioxide, sequentially adding a supersaturated calciumhydroxide solution, a phosphoric acid solution and calcium chloride into the system, uniformly stirring and mixing to obtain the composite anticorrosive pigment, coating with a wax emulsion, washing,drying and crushing to obtain the anticorrosive pigment with the average particle size of less than 5[mu]m. According to the preparation method, the whole process is normal temperature and normal pressure, a single anti-corrosion mechanism is broken through, design is comprehensively considered from the aspects of compact layer forming, calcium ion exchange and metal chelating, the production costis low, and the prepared anti-corrosion pigment is excellent in salt mist resistance. The main component of the anticorrosive pigment is low-water-pore low-oil-absorption silicon dioxide, the main component of the anticorrosive pigment is calcium phosphate, oxidized polyethylene wax and adsorbed calcium ions, the salt spray resistance is achieved by forming a compact layer, chelating phosphoric acid ions and exchanging part of calcium ions, and the salt spray resistance is excellent.