The invention relates to the technical field of ferro-
titanium alloy smelting, in particular to a ferro-
titanium alloy smelting process based on a composite aluminum material aluminothermy method, which specifically comprises the following steps: modifying aluminum skimmings by using an auxiliary agent for pretreatment, and preparing the ferro-
titanium alloy through gradient mixing and layered distribution, aluminothermy reaction
initiation and
smelting. The composite
fluoride-MgO compound is melted at the initial stage of the reaction, and the composite
fluoride and the nano MgO form a physical-chemical dual
membrane rupture effect. CaO and BaB6 micro
powder are wrapped by Li2B4O7, so that the effects of protecting and avoiding layering are achieved. Internal
active components are gradually released, so that the
effective action time of the additive is prolonged. Li < + > and BaB6 which are released by melting Li2B4O7 react with each other to gradually generate BF3, and F <-> is chemically corroded to form synergistic
membrane rupture of internal and external clamping, so that the
membrane rupture efficiency is improved. CaO reacts with Li2B4O7 to generate Ca3B2O6, so that the
slag phase
viscosity is reduced, and the
slag-
metal separation is improved. And meanwhile, CaO has the desulfurization capacity, melt purification can be achieved, and the
recovery rate of titanium and the alloy purity are improved.