The invention discloses a preparation method of methyl phenyl vinyl silicone resin. The preparation method comprises the following steps: firstly mixing and agitating organic solvent, deionized water and strong acid, then dropwise adding a mixture for hydrolysis reaction, and increasing temperature and reflowing to obtain mixed solution, wherein the mixture consists of difunctional alkoxy silane, trifunctional alkoxy silane, monofunctional alkoxy silane and tetraethoxysilane; standing the mixed solution, cooling to room temperature, separating out an organic layer, washing the organic layer with deionized water till the organic layer becomes neutral, then adding an alkaline catalyst into the organic layer, increasing the temperature for azeotropic reflowing for a certain time to obtain azeotropic reflowing solution; cooling the azeotropic reflowing solution to 50 DEG C below, then adding solid acidic neutralizer, stirring for neutralizing, filtering, and conducting vacuum purification to obtain the methyl phenyl vinyl silicone resin. According to the preparation method, the process is easy to control, the labor intensity is low, the whole process has small toxicity, and the preparation method has the advantages that monomer sources are wide, cost is low, and the prepared methyl phenyl vinyl silicone resin has stable storage performance.