Toner coated with thin film
A film coating, toner technology, applied in the direction of developer, electrography, optics, etc., can solve the problem of toner generation, difficult to provide low aggregation tendency (anti-clogging performance, high-speed melting performance, toner, performance Can not be all used and other problems, to achieve the effect of reducing heat energy and time, saving energy and high-speed melting method
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Embodiment 1-1
[0299] Film coating toner 1-1
[0300] A film coating was applied on commercially available black toner 1-1, which is a two-component developer for flash fixing. Black Toner 1-1 has a volume average particle diameter of 8 μm, its softening temperature is 120° C., the binder resin is ester and the colorant is carbon black.
[0301]First, a 25% by mass polyacrylic acid aqueous solution having a solution viscosity of 8,000 mPa·s at 25° C. was dissolved in water to prepare an aqueous medium having a pH of 4.5 and a concentration of 5% by mass. 100 parts by mass of the above-described black toner 1-1 were dispersed in 300 parts by mass of an aqueous medium at room temperature, and 8.2 parts by mass of hexamethylolmelamine prepolymer (produced by Showa Highpolymer Co., Ltd. manufactured; product name: Miruben 607). The resulting room temperature mixture was heated to 70° C. within 20 minutes, and a resinization reaction was performed for 2 hours, thereby coating the surface of Bla...
Embodiment 1-2
[0308] Film coating toner 1-2
[0309] Film coating toner 1-2 was prepared in the same manner as that of film coating toner 1-1 except that commercially available black toner 1 for a one-component developer containing magnetite was used -2 instead of Black Toner 1-1. Film-coated toner 1-2 has particularly good reproducibility during centrifugal deposition, and has the same or better performance than film-coated toner 1-1.
Embodiment 1-3
[0311] Film Coating Toner 1-3
[0312] Film coatings were applied on commercially available black toners 1-3, which are two-component developers for flash fixing. Black Toner 1-3 has a volume average particle diameter of 8 μm, its softening temperature is 70° C., the binder resin is ester and the colorant is carbon black.
[0313] First, 300 parts by mass of 10 mass% ethylene-maleic anhydride copolymer (manufactured by Mosanto; product name: EMA-31), 5 parts by mass of urea, and 0.5 parts by mass of resorcinol were mixed together, using hydrogen oxidation Aqueous sodium solution adjusted the pH to 3.2. Into 300 parts by mass of this solution, 100 parts by mass of Black Toner 1-3 was dispersed at room temperature, and then 12.5 parts by mass of formalin was mixed therein at room temperature. Within 20 minutes, the resulting room temperature mixture was heated to 70° C., and a resinization reaction was performed for 2 hours, thereby coating the surface of Black Toner 1-3 with ...
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