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Adhesive composition curable with actinic energy ray

An active energy ray and composition technology, which is applied in the directions of graft polymer adhesives, adhesives, non-polymer organic compound adhesives, etc. People's satisfaction and other issues, to achieve the effect of excellent adhesion and less coloring

Inactive Publication Date: 2008-04-16
TOAGOSEI CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0016] In recent years, it has been used under more severe high temperature and high humidity conditions, outdoor use under sunlight, and a longer product life is required. However, the known adhesive composition has problems such as poor bonding strength and coloring over time. , unsatisfactory

Method used

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  • Adhesive composition curable with actinic energy ray
  • Adhesive composition curable with actinic energy ray
  • Adhesive composition curable with actinic energy ray

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1~5

[0120] Components (A), (B), and (C) of Table 1 below and a photopolymerization initiator were dissolved under heating and stirring at 60° C. for 1 hour to manufacture an active energy ray-curable adhesive composition.

[0121] The resulting compositions were evaluated according to the following test methods. The results are shown in Table 2.

[0122] Table 1

[0123]

Reality

apply

example

(A)

(B)

(C)

photopolymerization initiation

agent

That

it

11)

MA

Compare

Rate

12)

M1200 1)

UN920

0A 2)

OPPA 3)

PCPA 4)

BCHM 5)

HBAs 6)

HEMA 7)

IBXA

8)

I-184

9)

TPO

10)

1

30

60

10

3

10

2

20

40

20

20

3

20 ...

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Abstract

The present invention relates to an active energy beam-curable adhesive composition having excellent adhesive power under high temperature and high humidity conditions and causing little coloration even when used for a long period of time. The active energy beam-curable adhesive composition of the present invention comprises (A) 5 to 50 weight % of a urethane (meth)acrylate having a polyester or polycarbonate skeleton, (B) 5 to 95 weight % of a compound having one (meth)acryloyl group represented by formula (1) below or / and formula (2) below, and as necessary (C) 0 to 85 weight % of an ethylenically unsaturated group-containing compound, 5 to 30 weight % of methacrylate compound being contained in the total amount of components (A) to (C). In formulae (1) and (2), R 1 and R 3 denote a hydrogen atom or a methyl group, R 2 and R 4 denote a halogen atom or a hydrocarbon group that has 10 or less carbons and does not have a hydrogen atom on the ±-position carbon atom, and m and n denote an integer of 1 to 5.

Description

technical field [0001] The present invention relates to an active energy ray-curable adhesive composition capable of bonding various substrates by irradiation with active energy rays such as electron beams and ultraviolet rays. [0002] The composition of the present invention is suitable for lamination and bonding of thin-layer coatings such as plastic films or plastic sheets of optical parts, and is suitable for use in liquid crystal display elements, EL (electroluminescence) display elements, projection display elements, The manufacture of various optical films or sheets of FED (field emission display) display elements, plasma display elements, etc. is well applied to these technical fields. Background technique [0003] Conventionally, the dry lamination method has been mainly used in lamination between thin-layer coverings such as plastic films or sheets, or between thin-layer coverings such as plastic films and sheets and thin-layer coverings of other materials, that i...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J4/02C08F290/06
CPCC09J4/00C08G18/672C09J151/08C08F8/00C08F290/061C08F290/06C09J175/16C09J133/14C08L2666/02C08F10/06C08G18/44C08G18/42C09J133/00C09J133/08C09J133/10
Inventor 小副川干英
Owner TOAGOSEI CO LTD