Phase-difference layer laminated polarizing plate, liquid crystal panel, and liquid crystal display device
A retardation layer and polarizer technology, applied in the direction of polarizing elements, can solve the problems of reduced contrast, light leakage, and uneven display
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Embodiment 1
[0236] (Preparation of adhesive layer)
[0237] In a reaction vessel equipped with a condenser tube, a nitrogen introduction tube, a thermometer and a stirring device, add 99 parts by weight of butyl acrylate, 1.0 parts by weight of 4-hydroxybutyl acrylate, 0.3 parts by weight of 2,2-azobisisobutyronitrile, and ethyl acetate to prepare a solution. Next, stirring was carried out blowing nitrogen gas into this solution, and polymerization reaction was performed at 60 degreeC for 4 hours, and the acrylic-type copolymer whose weight average molecular weight was 1.65 million was obtained.
[0238] Ethyl acetate was further added and diluted to the acrylate copolymer obtained above, and the polymer solution (1-A) whose total solid content concentration was 30 weight% was prepared. Next, to this polymer solution (1-A), 0.3 parts by weight of dibenzoyl peroxide [manufactured by NOF Corporation under the trade name "NYPER BO -Y"], 0.18 parts by weight of trimethylolpropane xylylene d...
Embodiment 2
[0249] Using 0.12 parts by weight of trimethylolpropane xylylene diisocyanate relative to 100 parts by weight of the above-mentioned acrylate copolymer to make an adhesive layer, except that, a Polarizing plate and liquid crystal display device of poor layer. The holding power of the obtained adhesive layer (H A ) is 150μm, holding force (H B ) is 100 μm, and the transmittance (T[590]) is 92%. The gel fraction was 82%, the glass transition temperature (Tg) was -38°C, and the water content was 0.25%.
Embodiment 3
[0251] A polarizing plate with a retardation layer and a liquid crystal display device were produced in the same manner as in Example 1, except that "WV Film SA" manufactured by Fujifilm Co., Ltd. was used as the retardation layer. The Re[590] of the film is 35nm, the Rth[590] is 155nm, the Nz coefficient is 4.43, and the average tilt angle is 18.9°.
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