Chewing gum containing hydrophobic enzyme preparation
A technology of chewing gum and hydrophobic enzyme, applied in the field of chewing gum, can solve problems such as loss
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Embodiment 1
[0281] Preparation of polyester elastomers by step-growth polymerization
[0282] Elastomer samples were produced using a 500 mL resin kettle equipped with an overhead stirrer, nitrogen inlet, thermometer, and distillation head for methanol removal. Charge 83.50 g (0.43 moles) of dimethyl terephthalate, 99.29 g (0.57 moles) of dimethyl adipate, 106.60 g (1.005 moles) of bis(ethylene glycol) and 0.6 g of calcium acetate monohydrate in the cauldron. The mixture was heated slowly under nitrogen with stirring until all components were molten (120-140°C). Heating and stirring were continued to continuously distill methanol. The temperature was slowly raised to 150-200°C until methanol evolution ceased. Turn off the heat and allow the contents to cool to about 100°C. The reactor lid was removed and the molten polymer was carefully poured into a receiving vessel.
[0283] The product was characterized by Mn = 40,000 g / mol, Mw = 190,000 g / mol, Tg = -30°C.
Embodiment 2
[0285] Preparation of polyester resins by ring-opening polymerization
[0286] Resin samples were produced using a jacketed 10 L cylindrical glass test reactor equipped with a glass stirring shaft and Teflon stirring blades and bottom outlet. Heating of the reactor contents was achieved by circulation of silicone oil through the external jacket thermostated at 130°C. ε-caprolactone (358.87g, 3.145mol) and 1,2-propanediol (79.87g, 1.050mol) with stannous octoate (1.79g, 4.42×10 -3 mol) were charged into the reactor together and reacted at 130° C. for about 30 minutes. Molten D,L-lactide (4.877 kg, 33.84 mol) was then added and the reaction continued for about 2 hours. After the reaction was complete, the bottom outlet was opened to allow the molten polymer to discharge into a Teflon-lined paint tank.
[0287] The product is characterized as M n = 6,000 g / mol, Mw = 7,000 g / mol, Tg = 25-30°C.
Embodiment 3
[0289] Preparation of polyester resins by ring-opening polymerization
[0290] Resin samples were prepared by polymerization similar to Example 2 at a molar ratio of 50% D,L-lactide to 50% glycolide.
[0291] The product is characterized as M n = 6,000 g / mol, Mw = 7,000 g / mol, Tg = 36°C.
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