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Preparation method of visible-light activated cuprous oxide/titanium dioxide nano-composite photocatalyst and applications thereof

A technology of titanium dioxide and cuprous oxide, which is applied in the field of environmental pollution control, can solve the problem that the photocatalytic properties have not been better applied, and achieve the improvement of visible light catalytic activity and stability, broaden the range of photoresponse, and improve the separation efficiency Effect

Inactive Publication Date: 2009-09-23
DALIAN UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

This patented technology allows researchers or manufacturers to easily prepare materials that have high purity without requiring costly facilities. These compositions also exhibit excellent properties such as enhanced photoelectric conversion ability due to their small size and unique structure. Overall, this method simplifies the way scientists study these materials by providing technical means for creating more efficient and effective devices with superior characteristics over existing technologies like chemical reactions.

Problems solved by technology

This patented technical solution describes different ways to enhance the optical characteristics of titanium dioxides called tin oxygen double heteroferrite or tungsten silicate. These materials exhibiting excellent absorbing capabilities include Ce02-, Er03++, Fe203-Thirionoxynthodim Acta Group IIIA metals such as Cadmobilte Acceptor Grille Metal(CCAG), Lanthum Quantum Dopammatory Anode Complex (LDAC). By combining these two types of material together, they could achieve superior optoelectronics effects without compromising their original functions.

Method used

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  • Preparation method of visible-light activated cuprous oxide/titanium dioxide nano-composite photocatalyst and applications thereof
  • Preparation method of visible-light activated cuprous oxide/titanium dioxide nano-composite photocatalyst and applications thereof
  • Preparation method of visible-light activated cuprous oxide/titanium dioxide nano-composite photocatalyst and applications thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0031] Cut industrial pure titanium sheet into several 20mm? 0mm size titanium sheet. Grind repeatedly with 240#, 400#, 800# and 1500# emery paper until the surface is clean and smooth, then place it in an ultrasonic oscillation pool for ultrasonic cleaning, and then immerse in HF:HNO 3 :H 2 Etching in a mixed solution of O=1:4:5 for 40 seconds, and cleaning the last etched titanium sheet with ethanol solution and deionized water for 20 minutes respectively. The treated titanium sheets were air-dried naturally for later use. Connect the titanium sheet and the platinum sheet to the positive and negative poles of the DC stabilized power supply respectively. The electrolyte is composed of hydrofluoric acid, and the concentration of hydrofluoric acid in the electrolyte is 0.2wt%. On the DC stabilized power supply. In the constant current anodizing process, the anodic oxidation voltage and time are first oxidized at 0-20V for 5 minutes, then the voltage is stabilized at 20V, an...

Embodiment 2

[0033] According to the preparation method of the present invention in Example 1, only the electrolytic solution was replaced with hydrofluoric acid with a concentration of 0.05 wt%, to prepare a cuprous oxide / titania nanocomposite photocatalyst.

Embodiment 3

[0035] According to the preparation method of the present invention in Example 1, only the electrolytic solution was replaced with hydrofluoric acid with a concentration of 1.0 wt%, to obtain a cuprous oxide / titania nanocomposite photocatalyst.

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Abstract

The invention discloses a preparation method of a visible-light activated cuprous oxide/titanium dioxide nano-composite photocatalyst and applications thereof, belonging to the technical field of environmental pollution control. The preparation of the catalyst comprises the following steps of: 1) carrying out electrochemical oxidation reaction under the action of hydrofluoric acid with the concentration of 0.2 percent by weight for preparing a titanium dioxide nanotube electrode, wherein the tube diameter of a nanotube is about 80nm, and the tube length is 550nm; and 2) adopting a photoreduction chemical method to prepare the cuprous oxide/titanium dioxide nano-composite photocatalyst. The prepared composite photocatalyst has the advantages of simple synthesis, stable performance, the synthesis process belonging to the field of green chemistry and the like. The composition of cuprous oxide can not only reduce the defect of high composite probability of photoproduced electron-hole pairs, but also expand the light response range of the titanium dioxide nanotube electrode and further improve the photocatalytic degradation efficiency thereof to organic pollutants in the visible light range, thereby having very high practical value and application prospect.

Description

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Claims

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Application Information

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Owner DALIAN UNIV OF TECH
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