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High-efficiency and novel biological carrier for sewage biological treatment and preparation method thereof

A technology of sewage biological treatment and biological carrier, which is applied in the field of high-efficiency new biological carrier for sewage biological treatment and its preparation, can solve the problems of poor microbial adhesion, high cost, small specific surface area, etc., and achieve not easily deformed and broken, good mechanical strength, The effect of large specific surface area

Inactive Publication Date: 2011-07-27
常州华钛化学有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

They generally have the disadvantages of high energy consumption for circulatory reflux, small specific surface area, difficult carrier stripping, complex preparation process, high raw material cost and high use cost, etc.
[0004] The magnetic biological carrier used in the sewage treatment of activated sludge method is added to the aeration tank to help increase the biological concentration and improve the efficiency of sewage treatment. Disadvantages of high cost and poor microbial adhesion
CN101254976A discloses magnetic biocarrier, its component is magnetic particle 7~21wt%; High molecular polymer 79~93wt%, described high molecular resin is polyethylene, polypropylene, polystyrene, powdery rubber, and its preparation The method needs to be ground and sieved, and the preparation process is relatively complicated. The biological carrier is a particle with a particle size of 0.043-0.315mm. The shape of the biological carrier is single, which limits its scope of application and the specific surface area of ​​the biological carrier; the cost is high ;The product density is 1.0~1.4g / cm 3 , there is not much room for adjustment, and the scope of use is limited; the surface is a non-polar or weakly polar polymer material, and its bioadhesion is not enough

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0041] Polypropylene (resin) (2500g), 10% maleic anhydride vinyl acetate (wherein the ratio of maleic anhydride and vinyl acetate is 1: 1) co-grafts polypropylene resin (500g), nano-scale silicon dioxide (1500g ), hemp fiber (500g), waste rubber fine powder (500g), and trace antioxidant 1010 are fully mixed through a high-speed mixer, and then added to the injection molding machine. In the barrel of the injection molding machine, polypropylene resin, horse Toric anhydride vinyl acetate co-grafted polypropylene resin, SiO 2 Fully mixed with hemp fiber and waste rubber powder, after extrusion, secondary injection molding or direct injection molding into three-dimensional elastic filler, combined filler, folded wave filler, hexagonal honeycomb filler or soft filler, the density is about 1.03g / cm 3 Biocarrier S-01. Can be used for biological contact oxidation.

Embodiment 2

[0043] Polypropylene resin (3750g), 15% maleic anhydride acrylic acid (maleic anhydride and acrylate ratio 10: 5) graft polypropylene resin (500g), nano-scale silicon dioxide (500g), trace antioxidant 1010 and Fe 3 o 4 After the magnetic particles (250g) are fully mixed with a high-speed stirrer, they are added to the plastic extruder, and in the barrel of the plastic extruder, the polypropylene resin, maleic anhydride acrylic acid grafted polypropylene resin and carbon dioxide are melted. Silicon, Fe 3 o 4 The magnetic particles are fully mixed, extruded and cut to form particles containing magnetic particles. Then grind the particles with a plastic mill to obtain a particle size of about 10 -6 ~10 -7 Micron-sized magnetic carrier with a density of about 0.98g / cm 3 , to obtain the magnetic biological carrier S-02.

Embodiment 3

[0045] Polyethylene resin (3000g), 25% maleic anhydride vinyl acetate graft polyethylene propylene copolymer resin (500g), nanoscale calcium carbonate (1000g), rice husk powder (500g), after fully mixing through high-speed stirrer , fed into the injection molding machine, in the barrel of the injection molding machine, polyethylene resin, maleic anhydride vinyl acetate grafted polyethylene propylene resin, SiO 2 Fully mixed with rice husk powder, injection molded, formed into triangular wavy fillers, or hollow spheres, fibrous or netted shapes to obtain a density of about 1.02g / cm 3 Biocarrier S-03.

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Abstract

The invention relates to a high-efficiency and novel biological carrier for a sewage biological treatment and a preparation method thereof. The biological carrier is prepared by comprising the following steps of: blending, extruding or injection-molding the following components: PP, PE, and ethylene-propylene copolymer, compatilizer, inorganic materials, plant materials, magnetic particles, and waste rubber according to a certain proportion, thus providing a biological carrier with large specific surface area, high hydrophilicity and easy hanged membrane on surfaces. The shapes of the biological carriers can be spherical, fibrous and polyhedral or powdery with various forms. The chemical or physical methods such as grinding, acid base reaction, coating on surface and the like can also be carried out to prepare the biological carrier, thus further improving the specific surface area, strengthening the adhesive ability of the biological membrane on the carrier, and improving the microorganism concentration. The preparation method of the biological carrier provided by the invention is simple, has wide adjusting range of the carrier density, easy obtaining materials, low cost, high efficiency of eliminating COD and variety shapes, can be lighter or heavier than water, and is applicable to all biological wastewater treatments.

Description

technical field [0001] The invention belongs to the field of sewage treatment, and in particular relates to a new high-efficiency biological carrier for sewage biological treatment and a preparation method thereof. Background technique [0002] Sewage (including waste water) biological treatment includes activated sludge method and biofilm method. At present, sewage biological treatment plays an important role: ① About 60% of the organic matter in urban sewage can only be removed by biological methods; ② Generally speaking, the removal of nitrogen in sewage can only rely on biological methods; More than 90% of urban sewage treatment plants use biological treatment methods; ④ most industrial sewage or wastewater treatment plants also use biological methods as the main body. [0003] The core part of sewage biofilm treatment is the carrier of biofilm. Microbes attach to the surface of the biological carrier and use their own metabolism to absorb pollutants in the water to pur...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F3/10C02F3/12
CPCB29B7/007
Inventor 徐俊伟蔡卫滨黄建朱志翔沙晓峰
Owner 常州华钛化学有限公司
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