Noctilucent artificial stone and preparation method thereof

An artificial stone and luminous technology, applied in the field of building decoration materials, can solve the problems of easy deterioration and blackening, short light storage time, low light storage intensity, etc., and achieve the effects of stable chemical properties, bright colors, and wide application

Active Publication Date: 2012-05-23
广州戈兰迪新材料股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] In the existing light-storing artificial stone products, the light-storage material is expensive, and has the disadvantages of short light-storage time, low light-storage intensity, and radioactivity in the light-storage material. Artificial stone products are mainly home decoration products, and the product is required to be non-radioactive, so Ordinary luminous artificial stone products have limitations
Moreover, the afterglow time of traditional light storage materials on the market is only 1 to 3 hours, and it is easy to deteriorate and turn black in strong light (such as sunlight), ultraviolet light and humid air.
The fillers used in existing artificial stone products are all inorganic minerals or ordinary stone powder, and their specific gravity is between 2.3-2.9, which leads to a high specific gravity of artificial stone products, about 1.5-1.9. The high density of the product will affect its decorative effect. Use in some fields, and increase the transportation cost of artificial stone products

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment approach 1

[0047] Embodiment 1: Production of low-density environmental protection luminous artificial stone products with overall luminous effect.

[0048] Take 13.5kg of unsaturated polyester resin, 29kg of aluminum hydroxide filler, 0.25kg of thermal expansion microcapsules, 0.4kg of alkaline earth aluminate type long-lasting luminescent material, 0.5kg of nano-titanium dioxide, 0.2kg of white paste, methacryloxytrimethyl Oxysilane 200g, cobalt isooctanoate 81g, methyl ethyl ketone peroxide 160g, mix the above raw materials evenly, pour into the mold, carry out vacuum degassing, use normal temperature curing molding, and carry out surface polishing treatment to get the overall luminous effect of environmental protection luminous artificial stone products. The addition of nano-titanium dioxide makes the surface of the artificial stone have the functions of decomposing oil stains, deodorizing, sterilizing and self-cleaning. The total weight of the product is 44.25kg, which is 88% of the...

Embodiment approach 2

[0049] Embodiment 2: Production of low-density environmental protection luminous artificial stone products with overall luminous effect.

[0050] Take 15kg of unsaturated polyester resin, 1.9kg of thermal expansion microcapsules, 0.4kg of alkaline earth aluminate type long-lasting luminescent material, 0.5kg of nano-titanium dioxide, 0.2kg of white paste, 200g of methacryloxytrimethoxysilane, cycloalkane Cobalt acid 90g, cyclohexanone peroxide 170g, mix the above raw materials evenly, pour into the mold, carry out vacuum degassing, adopt normal temperature curing molding, and carry out surface polishing treatment, you can get the low-density environmental protection luminous artificial stone products with overall luminous effect , the total weight of the product is 18.4kg, which is 38% of the normal formula weight, and when all the fillers are heat-expandable microcapsules, the weight of the product is reduced by 62%.

Embodiment approach 3

[0051] Embodiment 3: Production of granular luminous low-density environmentally friendly luminous artificial stone products.

[0052] Production of luminescent particles: 13.5kg of unsaturated polyester resin, 30kg of aluminum hydroxide filler, 2.25kg of alkaline earth aluminate type long-lasting luminescent material, 0.5kg of nano-titanium dioxide, 200g of methacryloxytrimethoxysilane, ring 75g of cobalt alkanoate, 150g of cyclohexanone peroxide, mix the above raw materials evenly, pour into the mold, carry out vacuum degassing, use normal temperature to solidify and shape, then carry out particle crushing, and sieve into 4 mesh, 6 mesh and 8 mesh respectively according to the particle size , 14 mesh, 20 mesh, 30 mesh, 40 mesh, 60 mesh, 100 mesh for use.

[0053]12kg of unsaturated polyester resin, 20kg of aluminum hydroxide filler, 9kg of luminous particles of different colors, 0.25kg of thermal expansion microcapsules, 0.5kg of nano-titanium dioxide, 0.5kg of white paste, ...

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Abstract

The invention discloses a noctilucent artificial stone and a preparation method thereof, belonging to the field of building decoration material. The noctilucent artificial stone contains, by weight percent, 0%-75% of inorganic filling, 20%-84% of unsaturated polyester resin or methacrylic acid type resin, 0%-6% of color paste, 0.5%-1.5% of coupling agent, 0.3%-20% of noctilucent material, 0.5%-11% of thermally expandable microcapsule, 0.5%-3% of nano titanium dioxide, accelerant which is 0.3%-2% of the content of the unsaturated polyester resin or methacrylic acid type resin, and curing agentwhich is 0.5%-3% of the content of the unsaturated polyester resin or methacrylic acid type resin. The nano titanium dioxide added to the artificial stone enables the surface of the artificial stone to have the functions of decomposing oil stains, removing bad smell, sterilizing and self-cleaning. Since the noctilucent material can absorb light and give out light naturally, the artificial stone can give out soft light at night. The specific gravity of the thermally expandable microcapsule is ultra-low, so the density of the artificial stone product can be greatly reduced.

Description

technical field [0001] The invention relates to a luminous artificial stone and a preparation method thereof, belonging to the field of building decoration materials. Background technique [0002] Under the circumstance that the worldwide environmental pollution problem has been paid more and more attention by the governments of various countries, the use of nano-materials for environmental governance has become a hot spot in the high-tech competition of various countries. In terms of nano-photocatalysis, Japan, the United States and other countries have invested heavily in research and development, and vigorously promoted its industrialization. At present, many products have appeared. Nano-TiO 2 High oxidation activity, good chemical stability, non-toxic to the human body, low cost, no pollution, wide application range, so it is the most valued and most promising green catalyst. [0003] In the existing light-storing artificial stone products, the light-storage material i...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B26/04C04B26/18C04B22/06B28B13/02C09K11/80
CPCC04B26/06C04B2111/50C04B26/18C04B2111/54C04B2111/807
Inventor 田雨江雪晓
Owner 广州戈兰迪新材料股份有限公司
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