Packaging material
A packaging material and photoluminescence technology, applied in photovoltaic power generation, electrical components, circuits, etc., can solve the problems of complex manufacturing process, increased manufacturing process and related costs, and inability to improve the heat resistance of inner layer packaging materials.
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Embodiment 1
[0030]Get 80, 90, 98, and 99 weight percent (wt%) of ethylene-vinyl acetate copolymer (DupontD150, VA content: 32%) and 20, 10, 2, and 1 weight percent (wt%) of poly Caprolactone (source as shown in Preparation Example 1B) was mixed with toluene (Tedia, 99%) as a solvent, and then made into a film on glass by spin coating (Spin coating), and its haze and transmittance were measured respectively As shown in Table 1. It can be seen from Table 1 that even if the amount of polycaprolactone is increased to 10wt%, the film still has high transmittance and low haze, indicating that polycaprolactone can be effectively dispersed in ethylene-vinyl acetate copolymer.
[0031] Table 1
[0032]
preparation example 1A
[0039] Get 0.09g of 1-pyrene butanol (1-pyrenebutanol, Aldrich), 18g of caprolactone (Tokyo Chemical TCI purity 98%) and 0.1g of stannous octoate (Aldrich) dissolved in 20mL toluene (Tedia, 99% ), heated to 130°C for ring-opening polymerization for 8 hours as shown in Formula 2, 7g of photoluminescent polymers (yield 70%) were formed, the number average molecular weight was 8139 as measured by GPC, and its melting point was between 55°C Its refractive index is between 1.52 and 1.48, and its film absorption spectrum and the fluorescence emission spectrum obtained by using the central wavelength of 340nm as the excitation light source are as follows: figure 2 shown.
[0040]
preparation example 1B
[0042] Get 18g of caprolactone (TCI) and 0.1g of stannous octoate (Aldrich) and be dissolved in 20mL toluene, be heated to 130 ℃ and carry out ring-opening polymerization reaction and promptly form 15g polycaprolactone polymer (productive rate 83% ), its number average molecular weight measured by GPC is 8500, and its melting point is between 55°C and 60°C.
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