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High-efficiency corrosion-retarding detergent for cobalt-base alloy

A technology of cobalt-based alloys and composite corrosion inhibitors, which is applied in the field of high-efficiency corrosion-inhibiting cleaning agents and cobalt-based alloy cleaning agents, can solve problems affecting the quality of alloy products, health hazards to operators, and high chemical oxygen demand in sewage. Excellent degreasing and cleaning effect, good corrosion inhibition effect, and the effect of reducing the precipitation of cobalt ions

Active Publication Date: 2013-06-12
WUHAN RES INST OF MATERIALS PROTECTION
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

A variety of water-based metal cleaning agents have appeared on the market. In order to achieve a better cleaning effect, the content of organic matter such as surfactants in these cleaning agent formulations is relatively high. The content of organic matter in the cleaning agent accounts for 35%. The high content of organic matter in the cleaning liquid means that the chemical oxygen demand of the sewage after cleaning is high, causing serious pollution to the water environment; Added strong alkali, phosphate and sodium nitrite, these have a strong corrosion inhibition effect, but also have high toxicity, which is harmful to the health of the operator and will also cause environmental pollution. The newly developed environmentally friendly cleaning agent uses The corrosion inhibitors of ammonium salts such as triethanolamine, such as the Chinese patent environment-friendly multifunctional metal cleaning agent with the publication number CN101994126, the efficient multifunctional metal cleaning agent with the publication number CN1844456A and the antirust metal cleaning agent with the publication number CN101413129A are all Contains triethanolamine corrosion inhibitor. Although triethanolamine corrosion inhibitor has good corrosion inhibition effect and environmental protection, there is a serious problem for cobalt-based alloys. Triethanolamine will promote the precipitation of cobalt in cobalt-based alloys , so that the structure of the alloy changes, which seriously affects the quality of the alloy product

Method used

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  • High-efficiency corrosion-retarding detergent for cobalt-base alloy
  • High-efficiency corrosion-retarding detergent for cobalt-base alloy

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] The corrosion inhibitor in the formula is a compound corrosion inhibitor compounded with sodium gluconate / borax.

[0025] Take by weighing compound nonionic surfactant 74g (wherein fatty alcohol polyoxyethylene ether AEO-9 8g, alkylphenol polyoxyethylene ether OP-10 30g, alkylphenol polyoxyethylene ether TX-1014g, coconut Oil fatty acid diethanolamide 6501 22g), composite borax corrosion inhibitor 12g (including borax 8g, sodium gluconate 4g), ethanol co-solvent 8g, ethylenediaminetetraacetic acid water softener 10g, silicon polyether defoamer (MG319) 4g and 892g of water were uniformly mixed to obtain a concentrated solution of a high-efficiency corrosion-inhibiting cleaning agent for cobalt-based alloys.

[0026] Dilute the above-mentioned concentrated solution with water into a working solution with a mass percentage of 10%, that is, add 9kg of water to the above-mentioned 1kg of concentrated solution to obtain 10kg of working solution, and the workpiece can be clean...

Embodiment 2

[0028] The corrosion inhibitor in the formula is a composite corrosion inhibitor compounded with borax / sodium molybdate.

[0029] Take by weighing 37g of composite nonionic surfactant according to the formula ratio (wherein fatty alcohol polyoxyethylene ether AEO-9 4g, alkylphenol polyoxyethylene ether OP-10 15g, alkylphenol polyoxyethylene ether TX-10 7g, Coconut oil fatty acid diethanolamide 6501 11g), composite borax corrosion inhibitor 6g (including borax 4g, sodium molybdate 2g), ethanol co-solvent 4g, EDTA water softener 5g, silicon polyether defoamer (MG319 ) 2g and 946g of water were uniformly mixed to obtain the concentrated solution of high-efficiency corrosion-inhibiting cleaning agent for cobalt-based alloys.

[0030] Dilute the above-mentioned concentrated solution with water into a working solution with a mass percentage of 10%, that is, add 9kg of water to the above-mentioned 1kg of concentrated solution to obtain 10kg of working solution, and the workpiece can ...

Embodiment 3

[0032] The corrosion inhibitor in the formula is a composite corrosion inhibitor compounded with borax / sodium molybdate.

[0033] Weigh 55.5g of composite nonionic surfactant according to the formula ratio (including fatty alcohol polyoxyethylene ether AEO-9 6g, alkylphenol polyoxyethylene ether OP-10 22.5g, alkylphenol polyoxyethylene ether TX-10 10.5g, coconut oil fatty acid diethanolamide 6501 16.5g), composite borax corrosion inhibitor 9g (including borax 6g, sodium molybdate 3g), ethanol cosolvent 6g, ethylenediaminetetraacetic acid water softener 7.5g, silicon polyether 3 g of defoaming agent (MG319) and 919 g of water were uniformly mixed to obtain a high-efficiency corrosion-inhibiting cleaning agent concentrate for cobalt-based alloys.

[0034] Dilute the above-mentioned concentrated solution with water into a working solution with a mass percentage of 10%, that is, add 9kg of water to the above-mentioned 1kg of concentrated solution to obtain 10kg of working solution...

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Abstract

The invention provides a high-efficiency corrosion-retarding detergent for cobalt-base alloy. The invention belongs to the field of detergents and especially relates to a detergent for cobalt-base alloy. The concentrated solution of the high-efficiency corrosion-retarding detergent for cobalt-base alloy provided in the invention comprise the following components on a mass basis: 3.7 to 7.4% of a composite nonionic surfactant, 0.6 to 1.2% of a composite borax corrosion inhibitor, 0.4 to 0.8% of an ethanol cosolvent, 0.5 to 1% of an ethylene diamine tetraacetic acid water softener and 0.2 to 0.4% of a silicone polyether anti-foaming agent, with the balance being water. The concentrated solution and water are mixed according to a mass ratio of 1:9 to prepare a working solution. The surfactant of the detergent is a high-efficiency environment-friendly alkalescence detergent compounded by three surfactants and is used with the composite borax corrosion inhibitor according to a scientific mixing rate. The high-efficiency corrosion-retarding detergent has the advantages of low content of organic matters, high cleaning efficiency and a good corrosion-retarding effect, and especially enables the problem of precipitation of cobalt from cobalt-base alloy due to utilization of normal metal detergents to be overcome, loss of cobalt in the alloy structure resulting from cleaning of cobalt-base alloy to be avoided and the quality of the cleaned products to be guaranteed.

Description

technical field [0001] The invention relates to a high-efficiency corrosion-inhibiting cleaning agent for cobalt-based alloys, which belongs to the field of metal cleaning agents, and in particular relates to a cobalt-based alloy cleaning agent. Background technique [0002] Water-based metal cleaning agent has the advantages of strong detergency, good rust resistance, energy saving, convenient and safe use, reduced environmental pollution, low cleaning cost, high economic benefit, and is suitable for mechanical automatic cleaning. It has replaced diesel, kerosene or Traditional cleaning fluids such as gasoline are widely used in the maintenance and repair of machining and mechanical equipment, automobiles, etc. Water-based metal cleaner is compounded by surfactant, builder, corrosion inhibitor, stabilizer, solubilizer and foam stabilizer. A variety of water-based metal cleaning agents have appeared on the market. In order to achieve a better cleaning effect, the content of...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C23G1/16
Inventor 刘秀生李健汪洋杨成凤刘兰轩苗毅张迎平
Owner WUHAN RES INST OF MATERIALS PROTECTION