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Manufacturing method of molybdenum or vanadium oxide briquetting for steelmaking alloying

A steelmaking alloying and oxide technology, applied in the direction of material forming presses, presses, manufacturing tools, etc., can solve the problem that the volatilization effect is not fully exerted, the yield of molybdenum is difficult to increase, and the yield of molybdenum or vanadium is low and other problems, to achieve the effect of simple and feasible method, good working environment and fast restoration speed

Active Publication Date: 2013-08-28
SHIJIAZHUANG IRON & STEEL +1
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  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] From the end of 1990s to the beginning of this century, the General Institute of Iron and Steel Research and Chongqing Special Iron and Steel Company conducted a large number of basic research and industrial experiments on the direct alloying of molybdenum oxide to smelt high-speed steel. It is easy to volatilize, and the recovery rate of molybdenum is still difficult to increase. Then, the method of adding damping agent quicklime (CaO) to suppress the volatilization of molybdenum oxide is studied, that is, adding molybdenum oxide, quicklime and reducing agent to the electric arc furnace for reduction, and the recovery rate of molybdenum The highest reached 96%, but the yield was unstable (Li Zhengbang, Guo Peimin, Feng Zhongyu. Theoretical analysis and industrial experiment of direct reduction alloying of scheelite and molybdenum oxide[J]. Iron and Steel, 1999, 34(10): 20 ~23; Li Zhengbang, Guo Peimin, Lin Gongwen. Resource development engineering - technology of smelting alloy steel from oxide ore[J]. China Tungsten Industry, 2001, 16(5~6): 45~47); Guo Peimin, Zhao Pei, Li Zhengbang . Effect of Additives on Volatility of Molybdenum Oxide at High Temperature[J]. Special Steel, 2006, 27(6): 30~31
[0011] (1) Molybdenum oxide and vanadium oxide are volatile at high temperature, and the yield of molybdenum or vanadium is low and unstable, which brings difficulties to on-site operation;
[0012] (2) Since quicklime (CaO) is easy to hydrate, adding quicklime (CaO) to molybdenum oxide or vanadium oxide has no suitable binder to make it shape
Therefore, the dust loss in the process of adding powder to the ladle is large, the working environment is harsh, and CaO inhibits MoO 3 and V 2 o 5 The volatile effect is not fully exerted

Method used

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  • Manufacturing method of molybdenum or vanadium oxide briquetting for steelmaking alloying
  • Manufacturing method of molybdenum or vanadium oxide briquetting for steelmaking alloying
  • Manufacturing method of molybdenum or vanadium oxide briquetting for steelmaking alloying

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0047] Embodiment 1: The molybdenum or vanadium oxide briquette used for alloying in steelmaking is prepared by the following raw material ratio and method.

[0048] Mix molybdenum oxide powder, FeSi75 powder, magnesia powder and fluorite powder in molar ratio MoO 3 :Si:MgO:CaF 2 =1:6:2:2 Calculate the mass of various materials, mix the various materials weighed evenly, then add water glass accounting for 8% of the mass of the mixture to wet the mixture, and press it into a diameter of 40mm with a ball press sized briquettes. The briquettes are dried at 200°C and packed into bags.

[0049] The compressive strength of the self-reducing briquette for direct alloying steelmaking with molybdenum oxide obtained in this example is greater than 50 kg / piece.

Embodiment 2

[0050] Embodiment 2: The molybdenum or vanadium oxide briquette used for alloying in steelmaking is prepared by the following raw material ratio and method.

[0051] Molybdenum oxide powder, FeSi65 powder, magnesia powder and fluorite powder are calculated by molar ratio MoO3:Si:MgO:CaF2=1:5:1.5:1.5 to calculate the quality of various materials, and the various materials weighed are mixed evenly, and then Add brine accounting for 10% of the mass of the mixture to wet the mixture, and press it into a briquette with a diameter of 40mm with a ball press. The briquettes are dried at 300°C and then bagged.

[0052] The compressive strength of the self-reducing briquette for direct alloying steelmaking with molybdenum oxide obtained in this example is greater than 80 kg / piece.

Embodiment 3

[0053] Embodiment 3: The molybdenum or vanadium oxide briquette used for alloying in steelmaking is prepared by the following raw material ratio and method.

[0054] Mix molybdenum oxide powder, silicon carbide powder, magnesia powder and fluorite powder in molar ratio MoO 3 : SiC : MgO : CaF 2 =1 : 5 : 2 : 2 Calculate the mass of various materials, mix the weighed various materials evenly, then add urea-formaldehyde resin accounting for 3% of the mass of the mixture to wet the mixture, and press it into a diameter of 40mm size briquetting. The briquettes are dried at 150°C and packed into bags.

[0055] The compressive strength of the self-reducing briquette for direct alloying steelmaking with molybdenum oxide obtained in this example is greater than 100 kg / piece.

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Abstract

The invention discloses a manufacturing method of molybdenum or vanadium oxide briquetting for steelmaking alloying, which comprises the following steps of: adding an inhibitor, a fluxing agent and a reducing agent into molybdenum or vanadium oxide; uniformly mixing the raw materials; wetting the mixture by a water-soluble adhesive; and pressing the wet mixture into a block, wherein the inhibitoris magnesia, the fluxing agent is fluorite and the reducing agent is ferrosilicon powder or carborundum powder. In the oxide briquetting, MgO contained in the magnesia is in tightly contact with MoO3or V2O5 to generate magnesium molybdate or vanadium molybdate difficult to volatilize by the solid-phase reaction, and the volatilization of MoO3 or V2O5 can be effectively inhibited; and meanwhile, the magnesia is difficult to hydrate and a water soluble compound (water glass, brine, urea-formaldehyde resin or the like) can be used as the adhesive. The method is simple and easy to operate, has high yield of directly alloying elements and can be popularized and applied in steel and iron works. Not only can the energy be greatly saved, the CO2 emission is reduced and the environmental load is reduced, but also the alloying cost of molten steel can be greatly reduced.

Description

technical field [0001] The invention relates to a steelmaking alloying agent, in particular to a method for preparing a molybdenum or vanadium oxide briquette used for steelmaking alloying. Background technique [0002] Molybdenum and vanadium are important alloying elements in steel. Molybdenum can significantly improve the thermal strength, hardenability and tempering stability of steel, and has a significant effect on improving the strength of steel; adding vanadium to steel can also significantly improve the performance of steel, increasing the strength by 10% to 20%, reducing the The weight of the structure is 15% to 25%. Vanadium is widely used in the production of high-speed steel and microalloyed steel. Steelmaking by direct alloying of oxides can save the ferroalloy production process, shorten the production cycle, save energy and reduce emissions, reduce environmental load, and greatly reduce the cost of molten steel alloying. [0003] In the 1980s, domestic res...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C21C7/00B30B11/00
Inventor 刘瑞宁薛正良王恭亮董大西宋生强王伟祥曲均志葛永肖
Owner SHIJIAZHUANG IRON & STEEL
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