Zr-Ti-based microwave dielectric ceramic material and preparation method thereof
A technology of microwave dielectric ceramics, zr-ti, applied in the direction of ceramics, inorganic insulators, etc., to achieve the effect of large promotion of practical value and simple sintering conditions
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[0024] The concrete implementation steps that make these embodiment microwave dielectric ceramics are as follows:
[0025] (1) Select ZrO with purity ≥99% 2 , ZnO, Nb 2 o 5 and TiO 2 As a raw material, according to the composition formula (1-x) ZrTi 2 o 6 -xZnNb 2 o 6 (0.20≤x≤0.40) molar ratio for batching, the specific formula is shown in Table 1;
[0026] (2) Put the above-mentioned prepared materials into the nylon ball mill tank, use zirconium balls as the balls and deionized water as the ball milling medium, and conduct a ball mill for 10-20 hours; Dry and pass through a 60-mesh sieve;
[0027] (3) Pre-calcining the above-mentioned primary ball mill material passed through a 60-mesh sieve at a temperature of 1000°C to 1150°C for 2 to 5 hours to obtain a pre-fired material;
[0028] (4) Add additives to the calcined material, that is, CuO equivalent to y wt% of the mass of the base material after calcining and MnO of z wt%, wherein 0.50≤y≤2.50, 0.12≤z≤0.90, the sp...
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