Hydrotreatment and catalytic cracking combined method for residuum

A hydrotreating and catalytic cracking technology, which is applied in hydrotreating process, hydrocarbon oil treatment, petroleum industry, etc., can solve the problem of unsatisfactory high-quality diesel products, reduced total yield of gasoline products, and limited yield of naphtha and diesel To achieve the effects of reducing the difficulty of hydrogenation reaction and processing severity, increasing the yield of high value-added products, improving logistics distribution and mass transfer

Inactive Publication Date: 2012-10-17
CHINA PETROLEUM & CHEM CORP +1
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Problems solved by technology

In addition to the fractionation tower, the product fractionation system of the residual oil hydrogenation unit requires nearly 20 sets of other equipment such as pumps, heat exchangers, reboilers, air coolers, and various containers. The material requirements are high, and not only the construction investment is large, Moreover, the energy consumption during normal production and operation is also high
[0009] In addition, both the hydrotreating unit and the catalytic cracking unit have diesel products, and relatively speaking, the total yield of gasoline products will decrease
In addition, the residual oil cracking rate of the residual oil hydrotreating unit is low, and the yields of naphtha and diesel oil obtained by fractionating the hydrogenated oil are limited, and the diesel fraction obtained during the residual oil hydrotreating process still cannot meet the high quality requirements. Requirements for Diesel Products

Method used

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Embodiment

[0034] This embodiment adopts the combined method of residual oil hydrotreating and catalytic cracking provided by the present invention, the raw material oil for residual oil hydrogenation is Middle East mixed residue oil is Middle East mixed residue reduction: catalytic cracking heavy cycle oil=70:30 (mass%) plus All liquid phase products of hydrogen treatment (that is, oil produced by hydrogenation) directly enter the catalytic cracking unit without fractionation, and the catalytic cracking reaction effluent is fractionated to obtain dry gas, liquefied gas, catalytic cracking gasoline fraction, catalytic cracking diesel fraction, catalytic cracking cycle oil and Catalytic oil slurry, in which all the catalytic cracking heavy cycle oil obtained is recycled into the hydrotreating unit for hydroprocessing, and the catalytic cracking heavy cycle oil obtained from other catalytic cracking units is introduced. Table 2, Table 3, and Table 5 are process conditions, product distribut...

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Abstract

The invention discloses a hydrotreatment and catalytic cracking combined method for residuum. The hydrotreatment and catalytic cracking combined method for residuum comprises the following steps that a residuum raw material and at least part of catalytically cracked heavy recycle oil undergo a hydrotreatment reaction in the presence of hydrogen and a hydrotreatment catalyst in a hydrotreatment device; a hydrotreatment reaction effluent is subjected to gas-liquid separation; a gas phase is circularly used for a hydrotreatment reaction and a liquid phase directly enters into a catalytic cracking device without passing through a fractionation device and then undergoes a catalytic cracking reaction; a catalytic cracking reaction effluent is treated by the fractionation device so that dry gas, liquefied gas, a catalytically cracked gasoline fraction, a catalytically cracked diesel fraction, catalytically cracked heavy recycle oil and catalytically cracked slurry are separated out; and a part or all of the catalytically cracked heavy recycle oil is fed back to the hydrotreatment device and then undergoes a hydrotreatment reaction. Compared with the prior art, the hydrotreatment and catalytic cracking combined method for residuum can realize maximum-yield production of gasoline, save an equipment investment, fully utilize reaction heat and reduce production energy consumption.

Description

technical field [0001] The invention relates to a method for lightening residue oil, in particular to a method for lightening residue oil by organically combining residue oil hydrotreating technology and catalytic cracking technology. Background technique [0002] As crude oil becomes heavier and worse, more and more residual oil needs to be processed. Residual oil generally refers to crude oil or hydrocarbon materials from other sources. After vacuum distillation, gasoline fraction, diesel fraction, and vacuum distillate oil are removed. The remaining part after waiting for the fraction generally has the characteristics of high boiling point and high impurity content, and is the most difficult raw material to process in the oil refining industry. The processing of residual oil is not only to crack it into products with low boiling point, such as naphtha, middle distillate oil and vacuum gas oil, etc., but also to increase their hydrogen-carbon ratio, which requires decarbur...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10G69/04
Inventor 刘铁斌耿新国李洪广初人庆蒋立敬
Owner CHINA PETROLEUM & CHEM CORP
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