140results about How to "Act as a diluent" patented technology

The invention discloses a treatment method of sintering flue gas desulphurization wastewater, which completes the treatment on the sintering flue gas desulphurization wastewater through the following five steps of: 1. neutralization and coagulation: regulating the pH value of the sintering flue gas desulphurization wastewater to 8.5 to 9.5 by lye, and adding 0 to 200ppm of coagulating agents; 2. flocculation: adding 0 to 10ppm of coagulant aids for forming flocs; 3. precipitation and filter liquor separation; 4. biochemical treatment on filter liquor; and 5. deep treatment. The treatment method can be used for reducing the treatment cost of the desulphurization wastewater without generating influence on other treatment systems, thereby having good application and popularization prospects.

The invention discloses a method for hydrogenation of coal tar via a fluidized bed. The method comprises the following steps: subjecting a coal tar raw material to hydro-upgrading; carrying out separation to remove water; and then carrying out hydrorefining and fractionation so as to obtain a gasoline fraction, a diesel fraction and hydrogenation tail oil. A hydro-upgrading catalyst used in the method comprises iron oxyhydroxide, organic polybasic carboxylic acid, macroporous alumina, a molecular sieve and pseudo-boehmite; and a hydrofining catalyst used in the method comprises iron oxyhydroxide, organic polybasic carboxylic acid, macroporous alumina and a binder. The method provided by the invention adopts cheap iron oxyhydroxide as an active metal component, the hydro-upgrading catalyst and the hydro-refining catalyst are graded, so cost is low. According to the invention, moderate cracking of coal tar is carried out before refining of coal tar, so impurities in coal tar are effectively removed, product distribution and product quality are adjusted, and the running period of a device is prolonged.

The invention discloses a wax oil hydrogenated treatment and catalytic cracking combined method, which comprises the following steps of: performing hydrogenated reaction on hydrogenated treatment raw materials in the presence of hydrogen and hydrogenated treatment catalyst, performing gas-liquid separation on the hydrogenated reaction effluent, circulating the gas phase for the hydrogenated reaction, directly feeding the liquid phase into a catalytic cracking device without fractionation, and mixing dry gas and liquefied gas separated from the catalytic cracking reaction effluent, catalytic cracking heavy fraction formed by catalytically cracking gasoline and the hydrogenated treatment raw materials to perform hydrogenated reaction. Compared with the prior art, the method can produce maximum gasoline, meanwhile saves equipment investment, makes full use of reaction heat energy and reduces the production energy consumption.

The invention belongs to the technical field of in-situ preparing of polluted underground water, and particularly relates to a device and method for periodic in-situ pumping based integrated repairing of groundwater pollution. The device comprises a polluted underground water pumping system, an in-situ repairing system and a recharge system, wherein the pumping system is composed of a pumping well and a pumping pipeline; the pumping system is connected with the in-situ repairing system; the in-situ repairing system is connected with the recharge system; and the recharge system comprises a recharge pipeline and a recharge well. The pumping well and the recharge well are subjected to a pumping test and a recharge test before the periodic in-situ pumping based integrated repairing of the underground water pollution is carried out. By adopting the method, the processed underground water is recharged to the original polluted water layer to dilute the original polluted water layer, so that the concentration of pollutants in a target aquifer is reduced, convenience is provided for subsequent treatment, and the pollution manage cost is reduced. The processed polluted underground water is timely recharged; and the poor hydrogeololgy and engineering geology can be effectively avoided.

The invention discloses a waste burning smoke purification process. The process comprises a denitration step and an acid removal step. The denitration step comprises a combination step of a smoke recycling process and a selective non-catalytic reduction (SNCR) denitration process; the acid removal step comprises a primary acid removal step and a secondary acid removal step; and a spray drying method is used for removing acid in the primary acid removal step, and a suspension boiling method is used for removing acid in the secondary acid removal step. The generation of NOx is inhibited by the smoke recycling process, acidic gases in the smoke are removed by the secondary acid removal process, and the burned smoke is efficiently purified with relatively low operating cost. The deep purification effect of the smoke is achieved by organically combining several processes.

The invention discloses a hydrotreatment and catalytic cracking combined method for residuum. The hydrotreatment and catalytic cracking combined method for residuum comprises the following steps that a residuum raw material and at least part of a catalytically cracked diesel fraction undergo a hydrotreatment reaction in the presence of hydrogen and a hydrotreatment catalyst in a hydrotreatment device; a hydrotreatment reaction effluent is subjected to gas-liquid separation; a gas phase is circularly used for a hydrotreatment reaction and a liquid phase directly enters into a catalytic cracking device without passing through a fractionation device and then undergoes a catalytic cracking reaction; a catalytic cracking reaction effluent is treated by the fractionation device so that dry gas, liquefied gas, a catalytically cracked gasoline fraction, a catalytically cracked diesel fraction, catalytically cracked recycle oil and catalytically cracked slurry are separated out; a part or all of the catalytically cracked diesel fraction is fed back to the hydrotreatment device and then undergoes a hydrotreatment reaction; and the catalytically cracked recycle oil is fed back to the catalytic cracking device and then undergoes a catalytic cracking reaction. Compared with the prior art, the hydrotreatment and catalytic cracking combined method for residuum can realize maximum-yield production of gasoline, save an equipment investment, fully utilize reaction heat and reduce production energy consumption.

The invention discloses a combined process for in-depth conversion of residual oil. The combined process comprises the following steps: (1) mixing a residual oil raw material with at least part of oil slurry of a catalytic cracking unit and allowing an obtained mixture to enter into a solvent deasphalting unit so as to obtain deasphalted oil and de-oiled asphalt; (2) allowing the de-oiled asphalt obtained in step (1) to enter into a fluidized bed hydrotreatment unit and carrying out fluidized bed hydrotreatment in the presence of hydrogen and a fluidized bed hydrotreatment catalyst; and (3) mixing an effluent of fluidized bed hydrotreatment obtained in the step (2) with the deasphalted oil, adding at least a part of recycle oil of the catalytic cracking unit at the same time and allowing an obtained mixture to enter into a fixed bed hydrotreatment unit, wherein generated oil of an effluent of fixed bed hydrotreatment is used as a raw material for the catalytic cracking unit. Compared with the prior art, the combined process provided by the invention has the advantages of wide sources of the raw materials, low equipment investment, stable operation, a long operation period and a good synergistic and coordination effect.

The invention discloses an auxiliary enhancement chemical agent for oil extraction with heat. The chemical agent comprises component A, component B and component C; the component A is petroleum surfactant solution; petroleum surfactant solution is obtained by the reaction of crude oil and deacidification agent; the component B comprises at least three ingredients of ammonium acid carbonate, ammonium carbonate, sodium hydrogen carbonate, ammonium chloride and sodium nitrite; and the component C is organic metal salt or ionic liquid. The auxiliary enhancement chemical agent for the oil extraction with heat has the following beneficial effects that three components of the auxiliary enhancement chemical agent for the oil extraction with heat are cheap and easy to get, single action of the three components is supplemental with one another and coordinated to make enhancement, self-growing surfactants, gases and catalysts of an oil layer in an adjacent well area can play roles in stages of thickened oil heat injection, well stewing and oil extraction, so that the viscosity is reduced by emulsifying, gas driving and catalyzed modifying of thickened oil, self-growing surfactants and gases generated in a far well area play leading roles, and the viscosity is reduced by dissolved gas expansion of thickened oil or by promoting low-temperature emulsification of thickened oil through generated gases of the oil layer.

The invention discloses a method for treating rubbish percolates of different times for deep denitrification by using a bipolar USAB+A/O+SBR process, which belongs to the technical field of biological denitrification and is suitable for performing advanced treatment on the rubbish percolates. In the method, water output by an A/O reactor passes through a secondary sedimentation tank, then part of the water flows back into a first-stage UASB reactor to perform denitrification, so the method fully uses sufficient carbon sources of raw water, realizes an efficient denitrification efficiency, and fully uses the characteristic that the rubbish percolates contain high-concentration organic substances. Dissolved oxygen (DO), an oxidation-reduction potential (ORP) and a pH value sensor are used for monitoring the degradation and the short-range nitrification/denitrification processes of the organic substances in the reactor, and the short-range nitrification/denitrification processes can be well controlled according to monitored pH values and ORP values. The average ammonia nitrogen concentration of final yielding water is 2 mg/L, the total nitrogen concentration is lower than 40 mg/L, and the ammonia nitrogen removal rate and the total nitrogen removal rate are above 98 percent. The method completely depends on biological treatments, reduces the cost and simplifies the process. The method performs denitrification on the rubbish percolates, not only realizes complete nitrification but also realizes short-range nitrification, and realizes the deep removal of the nitrogen in the rubbish percolates.

The invention discloses a method for synthesizing in-situ formed ceramic particle reinforced iron-aluminum-based composites by laser combustion, belonging to the technical field of materials. The in-situ formed ceramic particle reinforced iron-aluminum-based composites are prepared by the following steps of: putting tungsten ore powder, iron powder, aluminum powder and carbon powder in a ball mill for milling to obtain a mixed powder material; and compressing the mixed powder material into a pressed compact, transmitting a high-energy laser beam by employing a CO2 laser processing machine to ignite the surface of the pressed compact and trigger self-propagating high temperature synthesis of the pressed compact. By the invention, two ceramic particle reinforced phases are simultaneously formed on one substrate, which shortens the preparation process of the composites, lowers material manufacture cost and facilitates large-scale production and application.

The invention discloses a hydrotreatment and catalytic cracking deeply-combined method for residuum. The hydrotreatment and catalytic cracking deeply-combined method for residuum comprises the following steps that a residuum raw material, at least part of catalytically cracked heavy recycle oil and at least part of catalytically cracked slurry undergo a hydrotreatment reaction in the presence of hydrogen and a hydrotreatment catalyst in a hydrotreatment device; a hydrotreatment reaction effluent is subjected to gas-liquid separation; a liquid phase directly enters into a catalytic cracking device without passing through a fractionation device and then undergoes a catalytic cracking reaction; a catalytic cracking reaction effluent is treated by the fractionation device so that dry gas, liquefied gas, a catalytically cracked gasoline fraction, a catalytically cracked diesel fraction, catalytically cracked heavy recycle oil and catalytically cracked slurry are separated out; and a part or all of the catalytically cracked heavy recycle oil and the catalytically cracked slurry are fed back to the hydrotreatment device and then undergo a hydrotreatment reaction. Compared with the prior art, the hydrotreatment and catalytic cracking deeply-combined method for residuum can realize maximum-yield production of gasoline, save an equipment investment, fully utilize reaction heat and reduce production energy consumption.

The invention relates to epoxy-terminated hyperbranched polyphosphate and a preparation method thereof, aiming at solving the technical problems that in the prior art, epoxy resin is lower in relativemolecular mass, poorer in corrosion resistance, higher in viscosity and troublesome in construction, the toxicity of curing agent varieties for the epoxy resin is larger, and the epoxy resin is moreaffected by the environment. The epoxy-terminated hyperbranched polyphosphate provided by the invention is prepared adding a branching agent into tri-epichloropropyl trimetaphosphate (B3), and enabling the tri-epichloropropyl trimetaphosphate (B3) and the branching agent to be subjected to an epoxide ring-opening reaction so as to obtain the epoxy-terminated hyperbranched polyphosphate. Furthermore, the invention also provides the preparation method of the epoxy-terminated hyperbranched polyphosphate. The epoxy-terminated hyperbranched polyphosphate and the preparation method thereof can be widely applied to the technical field of organic synthesis.

The invention relates to the field of anticorrosive coatings, in particular to a solvent-free epoxy heavy-duty anticorrosive coating and a preparation method thereof. The solvent-free epoxy heavy-dutyanticorrosive coating comprises a component A and a component B; the component A comprises 100 parts of a solvent-free epoxy resin, 8-16 parts of a active diluent, 70-115 parts of a pigment and filler, 1.5-2.6 parts of a coupling agent, 1.5-2.6 parts of a dispersing agent, and 0.8-1.3 parts of a thixotropic agent; and the component B is a curing agent, and the mass ratio of the component B to theliquid epoxy resin in the component A is (1.5:1)-(3.5:1). The solid content of the heavy-duty anticorrosive coating is 98% or more, and the coating is an environment-friendly coating; the coating contains only a very small amount of a volatile organic solvent, so that only a small amount of shrinkage cavities and pinholes are formed after the coating is cured, and the compactness of the coating effectively increases the barrier properties and permeability resistance of an anticorrosive coating layer.

The invention relates to silicon nitride and a preparation method thereof. The preparation method of the silicon nitride comprises the following steps: performing gas atomization treatment on siliconparticles by using nitrogen to obtain silicon powder subjected to gas atomization; continuously nitrogen under the plasma state and the silicon powder subjected to gas atomization into a reactor, maintaining the temperature of the reactor to 1300 to 1450 DEG C, performing solid and gas separation and retaining solid; and adding alpha-phase silicon nitride, ammonium fluoride and ammonium iodide into the solid, mixing uniformly, vacuumizing, introducing mixed gas of nitrogen and hydrogen until the pressure is increased to the gauge pressure of 0.005 to 0.05 MPa, heating to 1200 to 1250 DEG C, continuously introducing the mixed gas of nitrogen and hydrogen until the pressure is increased to the gauge pressure of 0.01 to 0.1 MPa, maintaining the reaction time for 5 to 10 hours, and cooling after complete reaction to obtain the silicon nitride. The preparation method of the silicon nitride is a composite synthesis method. By the preparation method of the silicon nitride, high alpha-phase silicon nitride can be obtained.

The invention discloses an EU-1 molecular sieve and a synthesis method thereof, wherein the crystal structure of the EU-1 molecular sieve is a typical EUO structure. The synthesis method comprises: mixing an inorganic alkali, an aluminum source, a silicon source, a templating agent and water, stirring to obtain a silicon-aluminum gel, and crystallizing for a certain time; and adding water, a second templating agent and alumina, uniformly stirring, and carrying out hydrothermal crystallization to obtain the EU-1 molecular sieve. According to the present invention, the EU-1 composite molecular sieve synthesized by the method is the low silica-alumina ratio zeolite, and has the high crystallinity; and with the synthesis method, the generation of the impurity crystal can be avoided, and the operation is simple and easy to perform.

The invention discloses a residual oil hydrogenation treatment and catalytic cracking combined processing method, which comprises: performing the hydrogenation reaction of a residual oil raw material in the presence of hydrogen and a hydrogenation treatment catalyst, and performing gas-liquid separation of efflux of hydrogenation reaction, wherein a gas phase is circularly used in a hydrogenation reaction, and a liquid phase is fractioned to form a light component and a heavy component; allowing a light component to enter a reactor from the bottom of a catalytic cracking riser reactor, allowing a heavy component to enter the reactor as secondary feed of the catalytic cracking riser reactor and performing a catalytic cracking reaction; and separating a dry gas, a liquefied gas and a gasoline fraction from efflux of a catalytic cracking reaction, wherein the fractions of diesel are not separated and enter a residual oil hydrogenation device after filtration. Compared with the prior art, the method can produce high-octane number gasoline and high-added-value liquefied gas to a maximum degree; meanwhile, the method can fully utilizes reaction heat and reduces production energy consumption.

The invention discloses a hydrotreatment and catalytic cracking combined method for residuum. The hydrotreatment and catalytic cracking combined method for residuum comprises the following steps that a residuum raw material and at least part of catalytically cracked heavy recycle oil undergo a hydrotreatment reaction in the presence of hydrogen and a hydrotreatment catalyst in a hydrotreatment device; a hydrotreatment reaction effluent is subjected to gas-liquid separation; a gas phase is circularly used for a hydrotreatment reaction and a liquid phase directly enters into a catalytic cracking device without passing through a fractionation device and then undergoes a catalytic cracking reaction; a catalytic cracking reaction effluent is treated by the fractionation device so that dry gas, liquefied gas, a catalytically cracked gasoline fraction, a catalytically cracked diesel fraction, catalytically cracked heavy recycle oil and catalytically cracked slurry are separated out; and a part or all of the catalytically cracked heavy recycle oil is fed back to the hydrotreatment device and then undergoes a hydrotreatment reaction. Compared with the prior art, the hydrotreatment and catalytic cracking combined method for residuum can realize maximum-yield production of gasoline, save an equipment investment, fully utilize reaction heat and reduce production energy consumption.

The invention discloses a combined process of hydrotreatment and catalytic cracking for residual oil. The combined process comprises the following steps: (1) mixing a residual oil raw material and heavy distillate oil of a catalytic cracking unit and allowing an obtained mixture to enter into a fluidized bed hydrotreatment unit for fluidized bed hydrotreatment; (2) allowing an effluent of fluidized bed hydrotreatment obtained in the step (1) to enter into a fixed bed hydrotreatment unit for fixed bed hydrotreatment, wherein generated oil of an effluent of fixed bed hydrotreatment is used as a raw material for the catalytic cracking unit; and (3) mixing the residual oil raw material with a catalytic heavy fraction obtained after dry gas, liquefied gas and catalytic gasoline are separated from an effluent of a catalytic cracking reaction and subjecting an obtained mixture to fluidized bed hydrotreatment. Compared with the prior art, the combined process provided by the invention has the advantages of wide sources of the raw materials, low equipment investment, stable operation, a long operation period and a good synergistic and coordination effect.

The invention provides a slag ball content control method for preparation of mineral wool from silicon-manganese slag and relates to improvement of a technological method for preparing mineral wool from metallurgical slag, particularly from the silicon-manganese slag. The method is characterized in that a flux is added to hot melt slag of a silicon-manganese alloy in the preparation process, wherein the flux contains calcium fluoride and magnesium oxide, adding amount of calcium fluoride is 5%-8% by weight of the hot melt slag of the silicon-manganese alloy, and the adding amount of magnesiumoxide is 3%-5% by weight of the hot melt slag of the silicon-manganese alloy. According to the method, the slag is diluted by adding the flux to the hot melt slag of the silicon-manganese alloy, flowability of the hot melt slag is enhanced, fibers can become thinner due to wool forming in a high-speed centrifugation state, content of slag balls in the mineral wool is reduced, tensile strength of the mineral wool is improved, cost is lower, and operation is facilitated; glass state of high-temperature melt of the prepared mineral wool is good, fiber forming rate is high, fiber forming quality is excellent, slag ball content is lower than 8%, heat conductivity coefficient is low, tensile strength is high, and diversified market demands can be met.

The invention discloses an environment-friendly degradable composite film for packaging and a preparation method thereof. The degradable composite film is of a composite structure comprising a first modified polyvinyl alcohol layer, an insulating layer, a titanium dioxide fireproof layer, a polyvinyl alcohol composite layer, a second modified polyvinyl alcohol layer and a PET release film layer. The modified polyvinyl alcohol layer is prepared from the following raw materials in parts by weight: 45-76 parts of modified polyvinyl alcohol, 6-12 parts of bamboo carbon fibers, 3-8 parts of a medical stone powder, 2-5 parts of a nano calcium carbonate powder, 1-4 parts of lignocellulose, 3-6 parts of polyethylene glycol 400 and 2-5 parts of acetyl tributyl citrate. The composite film formed byhot-pressing stretching has excellent tensile strength, elongation at break, water resistance and high-temperature resistance. The used raw materials are non-toxic and environment-friendly and high indegradation rate, and can be substantially degraded if being photo-oxidized for 45 days. The environment-friendly degradable composite film is suitable for serving as a composite film for packaging food, chemical products and pesticides.

The invention relates to a rake-free separation tailing thickening sand bin, and aims to solve the problems that tailing concentration equipment in the prior art is complex in structure, low in sand discharging concentration and unsmooth in discharging. The rake-free separation tailing thickening sand bin comprises a sand bin body, a flocculation feeding tube, a center feeding barrel with a middleseparation plate, a tailing feeding tube, an overflow groove, an annular sedimentation cone, a sliding frame fluidization device and a double-screw discharging device. Through design of the structure, flow field variation of a material flow in the sand bin is changed, and the flocculation agglomeration speed of fine particle tailings is accelerated; and meanwhile, a mechanical sliding frame fluidization sand-discharging technology is adopted, so that smooth sand discharging under a condition of highest underflow concentration is realized. The rake-free separation tailing thickening sand bin has the outstanding advantages of small size, simple structure, low manufacturing cost, high concentration efficiency, high underflow concentration and the like.