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Hydrotreatment and catalytic cracking combined method for residuum

A technology of hydrotreating and catalytic cracking, which is applied in the field of gasoline production, can solve the problems of unsatisfactory high-quality diesel products, limited yield of naphtha and diesel, and reduced total yield of gasoline products, so as to save repeated processing steps , Improve material distribution and mass transfer, reduce the effect of hydrogenation reaction difficulty

Inactive Publication Date: 2012-10-17
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In addition to the fractionation tower, the product fractionation system of the residual oil hydrogenation unit requires nearly 20 sets of other equipment such as pumps, heat exchangers, reboilers, air coolers, and various containers. The material requirements are high, and not only the construction investment is large, Moreover, the energy consumption during normal production and operation is also high
[0009] In addition, both the hydrotreating unit and the catalytic cracking unit have diesel products, and relatively speaking, the total yield of gasoline products will decrease
In addition, the residual oil cracking rate of the residual oil hydrotreating unit is low, and the yields of naphtha and diesel oil obtained by fractionating the hydrogenated oil are limited, and the diesel fraction obtained during the residual oil hydrotreating process still cannot meet the high quality requirements. Requirements for Diesel Products

Method used

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Examples

Experimental program
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Effect test

Embodiment 1

[0034] This example adopts the combined method of residual oil hydrotreating and catalytic cracking provided by the present invention, and the raw material oil for residual oil hydrogenation is Middle East mixed residue oil is Middle East mixed residue reduction: FCC diesel oil = 70:30 (mass %) hydrotreating All liquid phase products (that is, hydrogenated oil) directly enter the catalytic cracking unit without fractionation, and the catalytic cracking reaction effluent is fractionated to produce dry gas, liquefied gas, catalytic cracking gasoline fraction, catalytic cracking diesel fraction, catalytic cracking cycle oil and catalytic oil Slurry, in which part of the catalytic cracking diesel fraction is recycled into the hydrotreating unit for hydrotreating, and the catalytic cracking cycle oil is recycled back to the catalytic cracking unit for recycling treatment. Table 2, Table 3, and Table 5 are process conditions, product distribution, and main product properties, respect...

Embodiment 2

[0049] This embodiment adopts the combination method of residual oil hydrotreating and catalytic cracking provided by the present invention, and the raw material oil for residual oil hydrogenation is Middle East mixed residue oil is Middle East mixed residue reduction: straight run minus four-line wax oil: catalytic cracking diesel oil=70: 15:15 (mass%) hydrotreating all liquid phase products (that is, oil produced by hydrogenation) directly into the catalytic cracking unit without fractionation, and the catalytic cracking reaction effluent is fractionated to produce dry gas, liquefied gas, catalytic cracking gasoline fraction, catalytic cracking Diesel fraction, catalytic cracking cycle oil and catalytic oil slurry, in which part of the catalytic cracking diesel fraction is recycled into the hydrotreating unit for hydroprocessing, and the catalytic cracking cycle oil is recycled back to the catalytic cracking unit for recycling treatment. Table 7, Table 8, and Table 9 are proc...

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Abstract

The invention discloses a hydrotreatment and catalytic cracking combined method for residuum. The hydrotreatment and catalytic cracking combined method for residuum comprises the following steps that a residuum raw material and at least part of a catalytically cracked diesel fraction undergo a hydrotreatment reaction in the presence of hydrogen and a hydrotreatment catalyst in a hydrotreatment device; a hydrotreatment reaction effluent is subjected to gas-liquid separation; a gas phase is circularly used for a hydrotreatment reaction and a liquid phase directly enters into a catalytic cracking device without passing through a fractionation device and then undergoes a catalytic cracking reaction; a catalytic cracking reaction effluent is treated by the fractionation device so that dry gas, liquefied gas, a catalytically cracked gasoline fraction, a catalytically cracked diesel fraction, catalytically cracked recycle oil and catalytically cracked slurry are separated out; a part or all of the catalytically cracked diesel fraction is fed back to the hydrotreatment device and then undergoes a hydrotreatment reaction; and the catalytically cracked recycle oil is fed back to the catalytic cracking device and then undergoes a catalytic cracking reaction. Compared with the prior art, the hydrotreatment and catalytic cracking combined method for residuum can realize maximum-yield production of gasoline, save an equipment investment, fully utilize reaction heat and reduce production energy consumption.

Description

technical field [0001] The invention relates to a method for lightening residual oil, in particular to a process for mainly producing gasoline products by organically combining residual oil hydrotreating and catalytic cracking and using residual oil as a raw material. Background technique [0002] As crude oil becomes heavier and worse, more and more residual oil needs to be processed. Residual oil generally refers to crude oil or hydrocarbon materials from other sources. After vacuum distillation, gasoline fraction, diesel fraction, and vacuum distillate oil are removed. The remaining part after waiting for the fraction generally has the characteristics of high boiling point and high impurity content, and is the most difficult raw material to process in the oil refining industry. The processing of residual oil is not only to crack it into products with low boiling point, such as naphtha, middle distillate oil and vacuum gas oil, etc., but also to increase their hydrogen-car...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10G69/04
Inventor 刘铁斌李洪广翁延博耿新国张庆军韩照明蒋立敬
Owner CHINA PETROLEUM & CHEM CORP
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