Method for synthesizing in-situ formed ceramic particle reinforced iron-aluminum-based composites by laser combustion

An in-situ self-generated, ceramic particle technology, applied in the field of materials, can solve the problems of reinforcement pollution, poor wettability, high temperature rise rate, etc., and achieve the effects of improving comprehensive performance, shortening the preparation process, and advanced preparation methods

Inactive Publication Date: 2010-12-08
LIAONING TECHNICAL UNIVERSITY
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  • Abstract
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  • Claims
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Problems solved by technology

According to the source of the reinforcement, it can be divided into two types: externally introduced reinforcement and in-situ self-generated reinforcement; there are many preparation methods for metal matrix composites reinforced by externally introduced reinforcement, and the research is also very mature, mainly including squeeze casting, stirring Casting, etc.; the disadvantage of these methods is that there are problems such as poor wettability between reinforcement and matrix, reinforcement contamination, poor bonding or interface embrittlement
However, the disadvantage of SHS technology is that it is extremely difficult to study its mechanism. This is because the temperature of the combustion reaction is extremely high and the speed is extremely fast. The combustion temperature is generally above 1500°C. The expansion rate of the combustion wave is in the range of 1 to 150 mm / s, and the temperature rise rate of the reactants is as high as 10 4 ~10 5 K / s, it is extremely difficult to capture the information of the phase transformation and microstructure transformation process under such high temperature and such fast conditions

Method used

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  • Method for synthesizing in-situ formed ceramic particle reinforced iron-aluminum-based composites by laser combustion

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] Mix tungsten ore powder, iron powder, aluminum powder and carbon powder with a particle size below 200 mesh, and the mixing ratio is iron powder: tungsten ore powder: aluminum powder: carbon powder=80: 0.3: 18: 1.2 by weight, and then place Mix in a ball mill for 4 hours at a ball milling speed of 200 rpm to obtain a mixed powder.

[0028] The mixed powder is pressed into a compact under the pressure condition of 400MPa, and the thickness of the compact is 25mm.

[0029] Using CO 2 The laser processing machine emits a high-energy laser beam to ignite the surface of the green compact, triggering the self-propagating sintering of the green compact. The reaction speed is 3mm / s, and the in-situ self-generated ceramic particle-reinforced iron-aluminum matrix composite material is generated. The laser output power is 550W, and the laser ignition time is 25s. .

[0030] SEM image of microstructure of Fe-Al matrix composites reinforced by self-generated ceramic particles fig...

Embodiment 2

[0034] Mix tungsten ore powder, iron powder, aluminum powder and carbon powder with a particle size below 200 mesh, and the mixing ratio is iron powder: tungsten ore powder: aluminum powder: carbon powder = 80: 0.6: 18.5: 0.9, and then place Mix in a ball mill for 6 hours at a ball milling speed of 150 rpm to obtain a mixed powder.

[0035] The mixed powder is pressed into a compact under the pressure condition of 500MPa, and the thickness of the compact is 20mm.

[0036] Using CO 2 The laser processing machine emits a high-energy laser beam to ignite the surface of the green compact, triggering self-propagating sintering of the green compact, with a reaction speed of 4mm / s to generate in-situ self-generated ceramic particle-reinforced iron-aluminum matrix composites. The laser output power is 600W, and the laser ignition time is 20s .

[0037] The average hardness of the obtained composite material is 160HB, compared with the metallurgical sintered FeAl alloy, the relative we...

Embodiment 3

[0040] Mix tungsten ore powder, iron powder, aluminum powder and carbon powder with a particle size below 200 mesh, and the mixing ratio is iron powder: tungsten ore powder: aluminum powder: carbon powder=80: 1.0: 19: 1.2 by weight, and then place Mix in a ball mill for 8 hours at a ball milling speed of 100 rpm to obtain a mixed powder.

[0041] The mixed powder is pressed into a compact under the pressure condition of 600MPa, and the thickness of the compact is 15mm.

[0042] Using CO 2 The laser processing machine emits a high-energy laser beam to ignite the surface of the green compact, triggering self-propagating sintering of the green compact, with a reaction speed of 3mm / s, and generates in-situ self-generated ceramic particle-reinforced iron-aluminum matrix composite materials. The laser output power is 650W, and the laser ignition time is 10s .

[0043] The average hardness of the obtained composite material is 110HB, compared with the metallurgical sintered FeAl al...

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Abstract

The invention discloses a method for synthesizing in-situ formed ceramic particle reinforced iron-aluminum-based composites by laser combustion, belonging to the technical field of materials. The in-situ formed ceramic particle reinforced iron-aluminum-based composites are prepared by the following steps of: putting tungsten ore powder, iron powder, aluminum powder and carbon powder in a ball mill for milling to obtain a mixed powder material; and compressing the mixed powder material into a pressed compact, transmitting a high-energy laser beam by employing a CO2 laser processing machine to ignite the surface of the pressed compact and trigger self-propagating high temperature synthesis of the pressed compact. By the invention, two ceramic particle reinforced phases are simultaneously formed on one substrate, which shortens the preparation process of the composites, lowers material manufacture cost and facilitates large-scale production and application.

Description

technical field [0001] The invention belongs to the technical field of materials, and in particular relates to a method for synthesizing in-situ self-generated ceramic particle-reinforced iron-aluminum matrix composite materials by laser combustion. Background technique [0002] In recent years, metal matrix composites (MMCs) have attracted great attention from all over the world because of their special properties such as high specific strength, specific modulus, high temperature resistance, and wear resistance; among them, particle-reinforced metal matrix composites are It has many advantages such as low reinforcement cost, isotropic material properties, low manufacturing cost, large-scale production, and can be processed by traditional metal processing technology, and has become one of the main directions for the development of MMCs. According to the source of the reinforcement, it can be divided into two types: externally introduced reinforcement and in-situ self-generat...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C38/06C22C33/02
Inventor 李刚陈永君
Owner LIAONING TECHNICAL UNIVERSITY
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