Comprehensive recovery method of rare metals in waste circuit boards
A technology for waste circuit boards and rare and precious metals, applied in the direction of improving process efficiency, etc., can solve the problems of strong corrosion of toxic aqua regia, etc., and achieve the effects of low environmental pollution, high metal recovery rate, and large profits
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Embodiment 1
[0034] A comprehensive recovery method for rare and precious metals in waste circuit boards, comprising the following steps:
[0035] Step (1): Roasting
[0036] The waste circuit boards are roughly broken and finely broken, and then electrostatically sorted to separate the metal components and non-metal components. The composition and content of the metals are as follows:
[0037] metal name
Cu
Ni
Pb
Zn
Fe
Al
PD
Sb
Content (%)
86.7
3.31
1.73
0.35
0.14
0.11
0.076
0.04
metal name
co
mn
Cr
Ca
Cd
Ag
Au
Content (%)
0.0001
0.01
0.0011
0.0001
0.0001
0.0001
0.0001
[0038] The metal was calcined at 200°C for 2h at low temperature.
[0039] Step (2): Ammonia immersion
[0040] The roasted metal components are leached in ammonia water at atmospheric pressure, and the two-stage countercur...
Embodiment 2
[0051] A comprehensive recovery method for rare and precious metals in waste circuit boards, comprising the following steps:
[0052] Step (1): Roasting
[0053] The waste circuit boards are roughly broken and then electrostatically sorted, and the metal components and non-metal components are sorted out. The composition and content of the metals are as follows:
[0054] metal name
Cu
Ni
Pb
Zn
Fe
Al
PD
Sb
Content (%)
86.7
3.31
1.73
0.35
0.14
0.11
0.076
0.04
metal name
co
mn
Cr
Ca
Cd
Ag
Au
Content (%)
0.0001
0.01
0.0011
0.0001
0.0001
0.0001
0.0001
[0055] The metal is fired at a low temperature of 250°C for 3 hours.
[0056] Step (2): Ammonia immersion
[0057] The roasted metal components are leached in ammonia water at atmospheric pressure, and the two-stage countercurrent lea...
Embodiment 3
[0070] A comprehensive recovery method for rare and precious metals in waste circuit boards, comprising the following steps:
[0071] Step (1): Roasting
[0072] The waste circuit boards are roughly broken and then electrostatically sorted, and the metal components and non-metal components are sorted out. The composition and content of the metals are as follows:
[0073] metal name
Cu
Ni
Pb
Zn
Fe
Al
PD
Sb
Content (%)
86.7
3.31
1.73
0.35
0.14
0.11
0.076
0.04
metal name
co
mn
Cr
Ca
Cd
Ag
Au
Content (%)
0.0001
0.01
0.0011
0.0001
0.0001
0.0001
0.0001
[0074] The metal is fired at a low temperature of 300°C for 5 hours.
[0075] Step (2): Ammonia immersion
[0076] The roasted metal components are leached in ammonia water at atmospheric pressure, and the two-stage countercurrent lea...
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