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Surface-treated metal material having excellent scale adhesion-suppressing properties, method for producing same, heat exchanger, and seawater evaporator

A surface treatment and metal material technology, applied in metal material coating process, seawater treatment, heat exchange equipment, etc., can solve the problems of reduced maintenance frequency, reduced thermal conductivity of metal materials, unable to inhibit scale adhesion, etc., to reduce maintenance. Frequency, the effect of scale adhesion suppression

Inactive Publication Date: 2015-07-15
KOBE STEEL LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] However, the above-mentioned technology cannot suppress the adhesion of scale, nor is it a technology to reduce the frequency of maintenance, nor does it solve the problem that the scale mainly composed of calcium carbonate adheres to the metal material and causes the thermal conductivity of the metal material itself to decrease.

Method used

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  • Surface-treated metal material having excellent scale adhesion-suppressing properties, method for producing same, heat exchanger, and seawater evaporator
  • Surface-treated metal material having excellent scale adhesion-suppressing properties, method for producing same, heat exchanger, and seawater evaporator
  • Surface-treated metal material having excellent scale adhesion-suppressing properties, method for producing same, heat exchanger, and seawater evaporator

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] (for the production of experimental pieces)

[0036] As the titanium base material, a plate (thickness: 0.5 mm) composed of industrial pure titanium class 2 (JIS H4600) was used, and the plate was cut into 10 mm×50 mm, washed with acetone, and air-dried at room temperature. The titanium plate was immersed in a mixed acid aqueous solution (2%HF-10%HNO3) composed of hydrofluoric acid and nitric acid at room temperature 3 ) after 15 seconds, wash with ion-exchanged water, and polyphosphate (sodium polyphosphate: Na n+2 P n o 3n+1 ) and metal salt (chloride) in a mixed aqueous solution (surface treatment solution) for 3 minutes or 3 to 12 hours, then rinsed with ion-exchanged water, and air-dried at room temperature.

[0037] (Determination of surface element concentration)

[0038] The concentration of each element in the modified layer was measured by glow discharge spectroscopy (GD-OES method). The test pieces were cut into about 10 mm squares and embedded in indium...

Embodiment 2

[0054] (for the production of experimental pieces)

[0055] A plate (thickness: 0.5 mm) made of SUS304 (JIS G4304) was used as the stainless steel base material, which was cut into 10 mm×50 mm, washed with acetone, and air-dried at room temperature. The stainless steel plate was washed with ion-exchanged water, and polyphosphate (sodium polyphosphate: Na n +2 P n o 3n+1 ) and metal salt (chloride) in a mixed aqueous solution (surface treatment solution) for 3 minutes or 3 to 12 hours, then rinsed with ion-exchanged water, and air-dried at room temperature.

[0056] The surface-treated stainless steel material was subjected to measurement of surface element concentration and scale adhesion evaluation in the same manner as in Example 1.

[0057] The results after these implementations are shown in Table 2 (Experiment Nos. 12 to 22) below together with the types of surface treatment liquids.

[0058] 【Table 2】

[0059]

[0060] From this result, the following can be cons...

Embodiment 3

[0068] (for the production of experimental pieces)

[0069] As the titanium base material, a plate (thickness: 0.5 mm) composed of industrial pure titanium Class 2 (JIS H4600) was used, which was cut into 10 mm×50 mm, washed with acetone, and air-dried at room temperature. The titanium plate was immersed in a mixed acid aqueous solution (2% HF-10% HNO 3 ) at room temperature for 15 seconds, washed with ion-exchanged water, polyphosphate (sodium polyphosphate: Na n+2 P n o 3n+1 ) and metal salts (chlorides) with water or hydrofluoric acid and nitric acid (0.1% HF-0.5% HNO 3 ) is immersed in the surface treatment solution of the solvent for 12 hours, then rinsed with ion-exchanged water, and air-dried at room temperature.

[0070] For the surface-treated titanium material, the measurement of the surface element concentration and the scale adhesion evaluation were carried out by the following methods.

[0071] (Determination of surface element concentration)

[0072] The su...

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Abstract

This surface-treated metal material has a base material that is formed of titanium, a titanium alloy or stainless steel, and the surface of the base material is modified. From the outermost surface to a depth of 10 nm of the surface-treated metal material, the P concentration is not less than 1.0 % by atom and the total concentration of one or more metal elements selected from the group consisting of Sn, Co, Ni, Fe, Zn and Mg is not less than 1.0% by atom. The surface-treated metal material excellently suppresses adhesion of scales that are mainly composed of calcium carbonate.

Description

technical field [0001] The present invention relates to surface-treated metal materials used in heat exchangers, seawater evaporators, etc., and their manufacturing methods, as well as heat exchangers or seawater evaporators formed by arranging the surface-treated metal materials. Surface-treated metal materials with excellent scale adhesion inhibition. Background technique [0002] In heat exchangers (for example, plate heat exchangers), seawater evaporators (seawater desalination devices), titanium, titanium alloys, or stainless steels with corrosion resistance and high thermal conductivity are often used (sometimes collectively referred to as "metals"). Material"). Groundwater, tap water and other water in contact with metal materials contain a small amount of calcium ions (Ca 2+ ), bicarbonate ion (HCO 3 - ). Therefore, it is known that when water is heated in heat exchangers and seawater evaporators, calcium carbonate (CaCO 3 ), and the scale mainly composed of th...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C23C22/07C23C22/23F28F19/06
CPCC23C22/36B01D1/00C23C22/362C02F2103/08C02F1/042C23C22/23F28F19/06C23C22/78C23C22/368F28F21/083F28F21/086Y02A20/124C23C22/07
Inventor 柳泽佳寿美
Owner KOBE STEEL LTD