Polypropylene-use matting agent masterbatch, and preparation method and application thereof

A technology of matting agent and polypropylene, which is applied in the field of plastic modification, can solve the problems of reducing the surface gloss of polypropylene blended modified materials, and the matting effect is not ideal, and achieves the effect of simple and reliable use method and reducing surface gloss

Active Publication Date: 2013-05-01
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

Publication No. CN101121799A patent discloses a method of crosslinking polyethylene molecules by adding a peroxide crosslinking agent to form microgels distributed in the polypropylene matrix. The microgels produce fine protrusions on the surface of the product to cause diffuse reflection of light To reduce the glossiness of the surface of the polypropylene blend modified material, but the matting effect is not ideal

Method used

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  • Polypropylene-use matting agent masterbatch, and preparation method and application thereof
  • Polypropylene-use matting agent masterbatch, and preparation method and application thereof
  • Polypropylene-use matting agent masterbatch, and preparation method and application thereof

Examples

Experimental program
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Effect test

Embodiment 1～8

[0036] Polypropylene (K9020, Sinopec Yanshan Branch), matting agent masterbatch (A-D) and antioxidant (Irganox 1010 and Irgafos 168 compounded at a weight ratio of 1:1, Swiss Ciba Specialty Chemical Co., Ltd.) were put into In a high-speed mixer, stir at a speed of 300 rpm for 3 minutes to fully mix the components. Subsequently, the above-mentioned mixed material is extruded and granulated through a twin-screw extruder within the range of 190°C to 220°C to obtain a low-gloss polypropylene modified material. Its specific formula is shown in Table 2, wherein the content of each component is calculated in parts by weight.

[0037] The extruded pellets were dried in a constant temperature oven at 95°C for 6 hours, and then injected into standard specimens at a temperature of 210°C to 225°C to test the matting properties and notched Izod impact strength. The test of Izod notched impact strength is tested according to the international standard test method ISO180. Gloss test using...

Embodiment 9～16

[0039] Polypropylene (K9020, Sinopec Yanshan Branch), matting agent masterbatch (A-D), ultrafine talc powder (average particle size 6.5 μm, Liaoning Haicheng Powder Material Co., Ltd.) and antioxidants (Irganox 1010 and Irgafos 168 is compounded at a weight ratio of 1:1 (Swiss Ciba Specialty Chemical Co., Ltd.) into a high-speed mixer, and stirred at a speed of 300 rpm for 3 minutes to fully mix the components evenly. Subsequently, the above-mentioned mixed material is extruded and granulated through a twin-screw extruder within the range of 190°C to 220°C to obtain a low-gloss polypropylene modified material. Its specific formula is shown in Table 3, wherein the content of each component is calculated in parts by weight.

[0040] The extruded pellets were dried in a constant temperature oven at 95°C for 6 hours, and then injected into standard specimens at a temperature of 210°C to 225°C to test the matting performance. Gloss test using JFL-BZ 20 ° 60 ° 85 ° intelligent glos...

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Abstract

The invention provides a polypropylene-use matting agent masterbatch, and a preparation method and an application thereof. The invention relates to the field of plastic modification. The masterbatch comprises the blended materials of, by weight: 100 parts of polypropylene, 20-70 parts of functionalized SBS copolymer, 10-50 parts of fully vulcanized powder silicone rubber, and 5-20 parts of silica. The fully vulcanized powder silicone rubber has an average particle size of 0.05-1mum and a gel content of 60wt% or higher. The average particle size of silica is 1-10mum. With the matting agent masterbatch provided in the invention, polypropylene modified material surface gloss can be substantially reduced. During an application process, matting agent masterbatch dose can be flexibly controlled according to different requirements on gloss. The application method is simple and reliable. The masterbatch can be widely applied in fields such as high-end automotive interior parts.

Description

technical field [0001] The invention relates to the field of plastic modification, in particular to a matting agent masterbatch for reducing the glossiness of polypropylene, a preparation method and application thereof. Background technique [0002] Polypropylene has the advantages of high heat resistance, fatigue resistance, electrical insulation, chemical corrosion resistance, good processability, low price, light weight, and easy recycling, so it is widely used in the automotive industry and other fields. However, most ordinary modified polypropylene materials have the characteristics of gloss or reflection. This defect not only reduces the overall decoration grade of the car interior, but also makes the car driver easy to fatigue, and even affects the driving safety of the car driver, increasing the risk of traffic accidents. probability, and cannot meet the needs of the development of new automotive plastics that can be decorated and integrated. Therefore, low-gloss po...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/12C08L23/14C08L53/02C08L83/04C08K3/36C08K13/02C08J3/22
Inventor 蔡涛金滟康鹏王学峰丁树岩刘善元石胜鹏
Owner CHINA PETROLEUM & CHEM CORP
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