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Blue light conversion agent s-triazine derivatives for agricultural film and their preparation method and use method

An application method, the technology of s-triazine, which is applied in chemical instruments and methods, luminescent materials, organic chemistry, etc., can solve the problems of decreased mechanical properties of the film, poor deliquescence resistance and dispersion, affecting the light transmittance of the film, etc., and achieves the reduction of additives Quantity, easy to disperse, and the effect of improving the utilization rate of photosynthesis

Inactive Publication Date: 2013-06-19
TANGSHAN NORMAL UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
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AI Technical Summary

Problems solved by technology

Among them, inorganic rare earth fluorescent compounds have high fluorescence intensity, but there are problems of sharp peak emission and poor anti-attenuation performance. The world stock of rare earth metal elements is small and the cost is high; although metal-organic complexes have high luminous intensity and good photostability properties, but metal-organic complexes are not conducive to uniform dispersion into polymer resins, resulting in a decrease in the physical and mechanical properties of the film and affecting the light transmittance of the film; organic fluorescent pigments, such as the sulfide-type light-converting agent that has been reported more at present , although the spectral matching is good, but there are defects of deliquescence resistance and poor dispersion in agricultural film

Method used

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  • Blue light conversion agent s-triazine derivatives for agricultural film and their preparation method and use method
  • Blue light conversion agent s-triazine derivatives for agricultural film and their preparation method and use method
  • Blue light conversion agent s-triazine derivatives for agricultural film and their preparation method and use method

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Embodiment Construction

[0027] The present invention will be further described through the embodiments below in conjunction with the accompanying drawings.

[0028] In the embodiment, the synthesis of 2,4,6-three (1-naphthylethyl)-s-triazine

[0029] Weigh 6 moles of 1-naphthaldehyde and 1.8 moles of potassium hydroxide, then add 20 L of methanol to dissolve. 5 L of 1,3,5-trimethyl-s-triazine solution dissolved in 1 molar amount was dropped into the flask drop by drop. After the drop was completed, it was refluxed for another 24 hours, and the solvent was removed by a rotary evaporator, and the residue was washed with V( Benzene): V (ethanol) = 10:1 toluene-ethanol mixture as eluent, separated by silica gel column chromatography to obtain a white powder product, yield 36.7%, and by FTIR, MALDI-TOP, 1 HNMR and other methods confirmed the structure of the compound. IR(KBr) ν: 3063, 3029, 2026, 1453-1641cm -1 , 635-750 cm -1 ; Mass Spectrum MALDI-TOF m / z: 538(M+H) + ; 1 HNMR (CDCl 3 , 400 MHz) δ...

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Abstract

The invention relates to blue light conversion agent s-triazine derivatives for an agricultural film and their preparation method and use method, and belongs to the technical field of fluorescent materials, organic electroluminescence materials and agricultural film light-conversion materials. The blue light conversion agent s-triazine derivatives comprise 2,4,6-tri(1-naphthylethyl)s-triazine (TNNA-1) having a molecular formula of C39H27N3 and a three-branch structure, and 2,4,6-tri(2-naphthylethyl)s-triazine (TNNB-1) having a molecular formula of C39H27N3 and a three-branch structure. The preparation method has simple processes and adopts traditional easily-acquired chemical materials. The blue light conversion agent s-triazine derivatives as organic light-emitting materials having s-triazine derivative structures have high thermostability, high glass-transition temperatures and high launching light intensity. In agricultural film preparation, the blue light conversion agent s-triazine derivatives are uniformly distributed in the agricultural film so that the agricultural film has the bright and flat surface and controllable thickness. The blue light conversion agent s-triazine derivatives have a wide application range, can convert ultraviolet light into visible blue light, adopt easily acquired raw materials, have low prices, can be prepared by the simple preparation method and are suitable for large-scale industrial production.

Description

technical field [0001] The invention relates to a blue light conversion agent s-triazine derivative for agricultural film, a preparation method and an application method thereof, belonging to fluorescent materials or fluorescent marking materials, organic electroluminescent materials, organic thin film bipolar tube materials, and agricultural film light conversion materials technology field. Background technique [0002] Agricultural film is an important agricultural production material after seeds, fertilizers, and pesticides. It has the effect of warming up and preserving moisture in the soil. my country is the country with the largest production and use of agricultural film in the world, which is 1.6 times the sum of all other countries. Agricultural film has made an important contribution to increasing agricultural efficiency and increasing farmers' income. With the improvement of crop cultivation technology, agricultural films with various special functions have appear...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C07D251/24C09K11/06C08L27/06C08K5/3492
Inventor 王光荣张永飞李莉莉
Owner TANGSHAN NORMAL UNIV
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