Blue light conversion agent s-triazine derivatives for agricultural film and their preparation method and use method
An application method, the technology of s-triazine, which is applied in chemical instruments and methods, luminescent materials, organic chemistry, etc., can solve the problems of decreased mechanical properties of the film, poor deliquescence resistance and dispersion, affecting the light transmittance of the film, etc., and achieves the reduction of additives Quantity, easy to disperse, and the effect of improving the utilization rate of photosynthesis
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[0027] The present invention will be further described through the embodiments below in conjunction with the accompanying drawings.
[0028] In the embodiment, the synthesis of 2,4,6-three (1-naphthylethyl)-s-triazine
[0029] Weigh 6 moles of 1-naphthaldehyde and 1.8 moles of potassium hydroxide, then add 20 L of methanol to dissolve. 5 L of 1,3,5-trimethyl-s-triazine solution dissolved in 1 molar amount was dropped into the flask drop by drop. After the drop was completed, it was refluxed for another 24 hours, and the solvent was removed by a rotary evaporator, and the residue was washed with V( Benzene): V (ethanol) = 10:1 toluene-ethanol mixture as eluent, separated by silica gel column chromatography to obtain a white powder product, yield 36.7%, and by FTIR, MALDI-TOP, 1 HNMR and other methods confirmed the structure of the compound. IR(KBr) ν: 3063, 3029, 2026, 1453-1641cm -1 , 635-750 cm -1 ; Mass Spectrum MALDI-TOF m / z: 538(M+H) + ; 1 HNMR (CDCl 3 , 400 MHz) δ...
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