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Low-carbon deep-desulfurization refining method of LF (ladle refining) furnace

A deep desulfurization and slag technology, applied in the field of steelmaking, can solve problems such as adverse effects of molten steel quality and production efficiency, unstable sulfur content at the treatment end, increased equipment investment, etc. the effect of strength

Active Publication Date: 2015-01-07
WUHAN IRON & STEEL GRP ECHENG IRON & STEEL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Therefore, in the actual production of low-carbon and ultra-low-sulfur steel, it often occurs that the carbon content is too high due to operational factors such as improper control of argon blowing at the bottom of the LF furnace, and the RH furnace is forced to use the oxygen blowing decarburization mode to save the composition, so that Detrimental effects on molten steel quality and production efficiency
[0008] At present, there are some studies on the deep desulfurization refining process of LF furnace at home and abroad, such as: the Chinese patent application with the publication number CN102002554A and the publication date being April 6, 2011, which adopts powder spraying metallurgy to desulfurize and achieves a better Desulfurization effect, but the sulfur content at the end of the treatment is unstable, and powder spraying metallurgy increases equipment investment; the publication number is JP6145764A, and the publication date is a Japanese patent application on May 27, 1994, which mainly focuses on the research and development of refining slag systems. The reuse of refining slag is obviously different from the method of the present invention
However, there is no relevant report on how to achieve ultra-deep desulfurization while effectively controlling carbon increase in LF furnaces, which is still a technical blank

Method used

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  • Low-carbon deep-desulfurization refining method of LF (ladle refining) furnace

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] The initial carbon and sulfur content of molten steel in the LF furnace: C: 0.045%, S: 0.0086%.

[0033] 1) Entering the station to raise the temperature and slag: After the molten steel enters the LF furnace station, open the large argon gas to break the slag, and the argon flow rate is 750NL / min (visually observe the argon flower in the slag layer of the molten steel surface in the range of 300-400mm). % Is adjusted to 0.065%. Lime was added at once, the amount of lime was 15Kg / t steel, the amount of fluorite was 2.5Kg / t steel, and the large argon gas volume was stirred until the lime was molten, and then the argon gas flow rate was adjusted to 200NL / min (visual inspection of the argon in the liquid steel surface slag layer). Spend in the range of 150~200mm), the temperature is increased for 11min when the power is transmitted, the argon flow is maintained at 200NL / min during the power transmission, and aluminum shot 0.2Kg / t steel and fluorite 0.2Kg / t steel can be added ...

Embodiment 2

[0040] The initial carbon and sulfur content of molten steel in the LF furnace: C: 0.046%, S: 0.0089%.

[0041] 1) Entering the station to raise the temperature and slag: After the molten steel enters the LF furnace station, open the large argon gas to break the slag, and the argon flow rate is 770NL / min (visually observe the argon flower of the slag layer on the molten steel surface in the range of 300-400mm), and the Al line is fed to the Alt % Adjusted to 0.068%. Lime was added at one time. The amount of lime was 17Kg / t steel, and the amount of fluorite was 2.8Kg / t steel. After stirring the large argon gas volume until the lime is molten, adjust the argon gas flow rate to 220NL / min (visual inspection of the argon in the liquid steel surface slag layer). Spend in the range of 150~200mm), send power to raise the temperature for 12min, keep the argon flow at 220NL / min during power transmission (visually observe the slag layer of molten steel in the range of 150~200mm), add alumin...

Embodiment 3

[0048] The initial carbon and sulfur content of molten steel in the LF furnace: C: 0.047%, S: 0.0094%.

[0049] 1) Enter the station to raise the temperature and slag: After the molten steel enters the LF furnace station, open the large argon gas to break the slag, and the argon flow rate is 800 NL / min (visually observe the argon flower on the slag layer of the molten steel surface in the range of 300-400 mm), and the Al line is fed to the Alt % Is adjusted to 0.070%. And add lime at one time, the amount of lime is 18Kg / t steel, the amount of fluorite is 3Kg / t steel, the large argon volume is stirred until the lime is molten, and then the argon flow is adjusted to 230NL / min (visual inspection of the argon flower on the slag layer of the molten steel) In the range of 150~200mm), the temperature is raised for 13min by power transmission, and the argon flow is maintained at 230NL / min during the power transmission process (the argon flower on the slag layer of the molten steel is vis...

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Abstract

The invention discloses a low-carbon deep-desulfurization refining method of an LF (ladle refining) furnace, which comprises the following steps of: 1) heating and slagging; 2) power-off forced stirring and deep desulfurization; 3) slag regulation and component adjustment; 4) secondary power-off forced stirring and deep desulfurization; and 5) power transmission temperature regulation. According to the method disclosed by the invention, by optimizing a whole-course argon blowing gas supply model of the LF furnace and dynamically controlling the argon flow in stages, enough argon blowing stirring work is provided to guarantee the desulfurization effect, and violent rolling of steel and slag caused by excessive argon flow in a heating process and consequent contact reaction between steel, slag and graphite electrodes leading to recarburization are avoided; by adopting an intermittent heating mode of alternate power supply and power cut and reallocating the tasks in the power supply period and power-cut period, the stirring intensity is reduced by reducing the argon flow in the power supply period, and recarburization is reduced during desulfurization; and meanwhile, the stirring is enhanced by increasing the argon flow in the power-cut period to finish deep desulfurization. Thus, the deep desulfurization is finished while effectively controlling the recarburization in the whole refining process.

Description

Technical field [0001] The invention relates to the technical field of steelmaking, in particular to a low-carbon deep desulfurization refining method for an LF furnace. Background technique [0002] LF furnace (ie ladle refining furnace) is the main external refining equipment in steel production. Its main tasks are: desulfurization, temperature adjustment, precise composition fine-tuning, improvement of molten steel purity, and slagging. Among them, the LF furnace refining mainly relies on the white slag in the barrel to desulfurize the molten steel in a low-oxygen reducing atmosphere. At the same time, the argon blowing device is used to blow argon into the barrel for stirring to accelerate the gap between the white slag and the molten steel. In order to ensure sufficient refining time, the graphite electrode will heat the molten steel through the primary furnace for temperature compensation. [0003] At present, deep desulfurization technologies mainly include deep desulfuriza...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C21C7/064
CPCY02P10/20
Inventor 汪晛陈庆丰张贤忠熊玉彰黄道昌张青山陈华强
Owner WUHAN IRON & STEEL GRP ECHENG IRON & STEEL CO LTD
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