113results about How to "Guaranteed desulfurization effect" patented technology

The invention relates to a method of liquefied gas refining desulfurization that includes the following steps: putting the liquefied gas need to refining into pre-desulfurization tower to take desulfurization reaction; filtering in the sand tower after separating in separating tower; adding desulfurization agent into oxidizing regeneration tower to take oxidizing regeneration and could periodic duty after being separated. If the liquefied gas does not meet the request, it could take further oxidation sweetening mellow with sulfonation lush coblt activator, alkaline liquor and air, then separating, filtering to gain refined product. The invention has good desulfurization effect, low cost, simple device and has no secondary pollution.

The invention relates to a method for preparing selective microbial packing. A plant organic fiber or a mixture of the plant organic fiber and activated carbon is used as basic packing, and the method comprises the following steps of: screening, separating and purifying activated sludge to obtain specific desulfurization bacteria; massively propagating and culturing the bacteria in nutrient solution to prepare desulfurization bacterium mother solution; and performing nutrient solution soaking, spraying and mother solution biofilm formation on the basic packing to prepare the selective microbial packing. The biological packing is used for microbial purification in waste gas treatment, and is particularly used for removing stinky pollutants produced in petrochemical plants, sewage treatment plants, urban sewage treatment plants, animal husbandry farms and the like. By the method, class I pollutants in exhaust gases of a refinery are treated specially, the treatment load and efficiency of the pollutants are improved, and impact resistance during change of working conditions is improved.

The invention belongs to the technical field of ferrous metallurgy and particularly relates to ultra-low aluminum steel and a smelting method thereof. The smelting method provided by the invention adopts a production route with the steps of deep removal of S and P by molten iron pretreatment, decarbonization by a converter, deoxidization and alloying of silicon manganese during tapping, deslagging by argon blowing, deep removal of O, S and P by ladle refining, micro-alloying of Ti, Ni, Mo, V and other elements, RH (Ruhstahl-Hausen) vacuum circulation degassing, soft argon blowing and full-protection casting; the prepared ultra-low aluminum steel has low content of harmful elements, particularly has low content of O and Al, can prevent the inclusion of brittle aluminum oxide and realize high impact-resistant and fatigue-resistant performances of the steel, and is suitable for application fields with relatively high requirements for fatigue and impact performances, such as high-speed track traffic and the like.

The invention relates to a desulfurization system and method for flue gas of a cement kiln furnace. The desulfurization system comprises an ammonia water storing tank, conveying pumps, spraying guns, a cement decomposing furnace, a cement kiln pre-decomposing system and an automatic control system, wherein the cement kiln pre-decomposing system comprises a multi-stage pre-heater; the ammonia water storing tank communicates with the spraying guns through the conveying pumps; and spraying points of the spraying guns are located at an outlet of a cyclone barrel of a second-stage pre-heater. The desulfurization method comprises the following steps of I, preparing a 15-25% ammonia water; II, performing real-time detection on the concentration of SO2, and according to the concentration of the SO2 in flue gas, calculating and adjusting the spraying amount of the ammonia water through the automatic control system; and III, according to the spraying amount of the ammonia water, which is obtained through calculation in the step II, injecting the ammonia water which is pressurized through the conveying pumps to the spraying guns, and spraying the ammonia water into the cement kiln pre-decomposing system, wherein the spraying points of the spraying guns are located at the outlet of the cyclone barrel of the second-stage pre-heater. According to the desulfurization system and method disclosed by the invention, the desulfurization efficiency can reach 95% or above, the desulfurization efficiency is high, the ammonia-sulfur ratio is 2-2.5, and the operating cost is low.

The invention relates to a Claus tail gas condensing treatment process, which comprises the steps that Claus tail gas coming from a Claus process sulfur condenser enters a heat exchanger I, gaseous sulfur is condensed and removed; the gaseous sulfur-removed Claus tail gas is sent to a desulfurizing absorption tower and is sprayed by adopting a doctor solution coming from a gas purification device, rich liquor is returned to the gas purification device for regeneration, and regenerated acid gas is used as a raw material for a Claus process; the upper part of the desulfurizing absorption tower is provided with an alkali washing section, and alkali liquor is a replenishing solution coming from a desulfurizing unit of the gas purification device; after the removal of H2S, the Claus tail gas is sent to a coke oven gas system or is returned to a returned gas system; the heat exchanger I and a heat exchanger II work in a cyclic alternating pattern, and the continuous condensing of the gaseous sulfur in the Claus tail gas is realized. The Claus tail gas condensing treatment process has the remarkable advantages of small investment, low operating cost, energy conservation, greenness, environmental protection and the like.

The invention discloses a water curtain check-type super-purification smoke exhaust dedusting and desulfurization system, which comprises a smoke exhaust inlet tube, wherein the end part of the smoke exhaust inlet tube is connected to a flow rate control tube; the left side wall of a tube body of the flow rate control tube is provided with a guide rail; the internal thread of a lifting nut is adaptively provided with a rotating screw rod; two side walls of a conical extrusion cavity are respectively provided with one vibrating motor; the left side wall of the upper side of an inner cavity in a case body of an ultra-clean desulfuration case is provided with first diversion water curtain boards; the two first diversion water curtain boards and three second diversion water curtain boards are staggered; the bottom end of a tube body of a drainage through tube is communicated with a circulating filter box pump. The system is capable of solving the problem of weakened desulfuration effect caused by uncontrollable smoke feeding velocity in a traditional process, ensuring that sulfides in the smoke are fully absorbed and removed and the treated solvent also can be recycled, and further saving the solvent resource.

The invention discloses a concurrent high-sulfur bauxite desulfurization roasting process and device. The process comprises the steps of grinding, weighing and feeding, drying, primary suspension desulfurization roasting, secondary suspension desulfurization roasting, desulfurization roasting dust collection, cyclone cooling, cooling and dust removal and the like. According to the invention, a flue gas and material concurrent manner is adopted in the desulfurization roasting section, the contact time of the material and high-temperature flue gas in a proper reaction temperature interval rangeis prolonged, the dynamic characteristic of the high-sulfur bauxite desulfurization reaction is ensured, no return material is generated in the technological process, and the method has the characteristics of good desulfurization effect, low production cost, stable product quality and high production efficiency.

The invention aims at providing a high-capacity viscose staple fiber post-treatment production line in order to reach the annual yield of 100 thousand tons. The production line comprises a refining system and a drying system. A refiner in the refining system comprises a refining section and an oiling section. The high-capacity viscose staple fiber post-treatment production line is characterized in that the breadth of the refiner of the refining system is 4000mm, the refining section is divided into 13-18 process areas, the oiling section is divided into 2 process areas and the length of a single process area is 2500mm. The viscose staple fiber post-treatment production line comprises the refining system and the drying system, and has the advantages that the production capacity is strong, the operation stability is high, the automation level is high and the product quality is guaranteed.

The invention discloses a flue gas desulfurization method and flue gas desulfurization equipment, and aims to solve the technical problem of helping to improve the flue gas purification effect of catalytic flue gas desulfurization. The flue gas desulfurization method comprises the following steps: introducing target flue gas into a cooling system, so that the target flue gas is cooled by spraying liquid; introducing the cooled target flue gas into a desulfurization system, so that the target flue gas is desulfurized through a catalyst, and sulfur dioxide removed in the desulfurization system forms sulfuric acid on the catalyst and enters regeneration liquid for washing and regenerating the catalyst along with washing and regeneration of the catalyst, wherein the spraying liquid is from the regeneration liquid. The target flue gas is cooled through the spraying liquid, so that the dust content in the target flue gas can be reduced, and the target flue gas can reach a catalytic activity temperature interval required by the catalyst conveniently; as the spraying liquid comes from the regeneration liquid, the concentration of the spraying liquid can be increased, and subsequent utilization of the spraying liquid is facilitated.

The invention relates to method and device for improving utilization rate of alkali liquor at an alkaline cleaning section of vacuum potassium carbonate desulfurization technique. The method comprises the following steps: diluting NaOH solution by replacing industrial new water with ammonia still waste water in a chemical workshop, and storing the diluted NaOH solution in a NaOH alkali liquor tank; conveying NaOH alkali liquor in the NaOH alkali liquor tank to the NaOH alkaline cleaning section at the upper part of a desulfurizing tower for carrying out alkaline cleaning, enabling the alkaline cleaning water to flow back into a waste alkaline tank, then evenly mixing the alkaline cleaning water in the waste alkaline tank with NaOH alkali liquor in the NaOH alkali liquor tank, conveying back to the alkaline cleaning section at the upper part of the desulfurizing tower for recycling, and stopping recycling until the pH value of waste liquor in the waste alkaline tank is lower than 10; conveying the waste liquor in the waste alkaline tank into an ammonia still tower to be used as alkaline instead of NaOH. According to the method and the device, the alkaline liquor at the alkaline cleaning section can be recycled, and the usage efficiency of the alkali liquor can be improved on the premise of guaranteeing the desulfurization effect of the desulfurizing tower.

The invention discloses a method for treating ash deposition and scaling of a GGH (gas-gas heater). The method for treating ash deposition and scaling of the GGH has the advantages that the steps of blowing ash online by compressed air, flushing online by high-pressure water, flushing by low-pressure water before halting and performing high-pressure flushing by chemical cleaners after halting are adopted, so that the problems of severe ash deposition and scaling of a heated surface of the GGH due to ash deposition, acid coagulation, liquid drop adhesion and the like are solved, blockage resulting from ash deposition and scaling of the GGH is slowed down substantially, normal operation and flue gas desulfurization effect of a desulfurization system are guaranteed, halting times of the desulfurization system are decreased, and safety operation and safety economy of a unit are guaranteed under a rated condition.

The invention discloses a washing tower for ship tail gas treatment. The washing tower comprises a cylinder body, wherein an upper sealing head is arranged at the upper part of the cylinder body; a purified flue gas outlet is formed in the upper sealing head; the lower part of the cylinder body is provided with a conical lower seal head protruding downwards and a support for lifting the cylinder body to a certain height; a washing wastewater outlet is formed in the lower sealing head; a spraying pipe system is arranged in the cylinder body; the spraying pipe system comprises a spraying main pipe with the bottom sealed and a spraying liquid inlet short pipe arranged on the upper portion of the spraying main pipe and perpendicular to the spraying main pipe; a spraying slurry inlet is formedin the spraying liquid inlet short pipe; a spiral tower plate is arranged on the periphery of the spraying main pipe; and a certain distance is formed between the bottom of the spiral tower plate andthe bottom of the lower sealing head. The washing tower is compact in structure, reasonable in design and good in washing effect.

The invention discloses a method for preparing sodium pyrosulfite from coking desulfurization waste liquid and crude sulfur, which comprises a raw material pretreatment step, a sulfur burning step, afurnace gas purification step and a finished product step. The invention adopts the technology of a sulfur melting kettle to prepare sulfur, and the desulfurization waste liquid is subjected to concentrated crystallization to directly prepare mixed salt, and then the mixed salt is respectively sent to an incinerator for direct combustion, thereby not only innocuously treating the desulfurization waste liquid, but also comprehensively utilizing the sulfur resources; the low pressure saturated steam from coking plant is used to produce massive sulfur by using the technology of the sulfur meltingkettle, and the desulfurization waste liquid is also concentrated and crystallized by using the low pressure saturated steam to produce mixed salt, the method has features of low investment, low energy consumption which is only 30%-40% of that of direct hot air drying and no exhaust emission.

The invention relates to an alkali-water desulphurization dust removal technology, and relates to a wet-method environment-friendly treatment technology for sulfur-containing smoke. The alkali-water desulphurization dust removal technology comprises the following steps: performing primary desulphurization dust removal by taking a sulfur-containing solution as a first desulphurization agent, performing the secondary desulphurization dust removal by adopting the water as a second desulphurization agent, performing the primary desulphurization dust removal in a tubular reaction device, and performing the secondary desulphurization dust removal in a tower-type device; and enabling the desulphurized dust-removed sulphite-containing mixed solution to enter an independent tubular oxidation reactor, and performing the oxidation reaction to obtain a sulfate mixed solution. By adopting the alkali-water desulphurization dust removal technology, the technical defects of the traditional wet-method desulphurization technology that a spray nozzle is blocked by scales formed on the inner wall and components in the desulphurization tower can be overcome, and the long-term operation of the device can be guaranteed; the equipment investment is low, the operation expense is low, the operation flexibility is high, the absorption, neutralization and oxidation are thoroughly carried out, and the desulphurization efficiency is high.

The invention discloses a desulfurizing tower which comprises a desulfurizing tower body. The upper portion of the desulfurizing tower body includes a down-flow tower and an adverse-flow tower, a smoke inlet is formed in the down-flow tower, a smoke outlet is formed in the adverse-flow tower, and the lower portion of the desulfurizing tower body is a slurry pool. A front circulating desulfurizing zone is arranged in the down-flow tower, a rear circulating desulfurizing zone is arranged in the adverse-flow tower, vertical spiral guide vanes are arranged on the inner wall corresponding to the front circulating desulfurizing zone of the down-flow tower and on the inner wall corresponding to the rear circulating desulfurizing zone of the adverse-flow tower, an outlet of a front circulating pump is communicated to the front circulating desulfurizing zone through a front circulating pipe, an outlet of a rear circulating pump is communicated to the rear circulating desulfurizing zone through a rear circulating pipe, and spiral channels formed by a front circulating pipe and a rear circulating pipe along the corresponding vertical spiral guide vanes spirally extend into the front circulating desulfurizing zone and the rear circulating desulfurizing zone. The front circulating pipe and the rear circulating pipe extend into the spiral channels and can spray slurry in the spiral channels to enable smoke and slurry to be mixed fully, and desulfurizing effect is ensured.

The invention provides a method for removing sulfur on hydroxyl oxidize iron. By strictly controlling the water content of sulfur-containing hydroxyl oxidize iron, the desulfuration capability of hydroxyl oxidize iron and the purity of recycled sulfur are effectively ensured on the premise of efficiently separating sulfur from hydroxyl oxidize iron, which is because when the water content of hydroxyl oxidize iron is too high, the water is dispersed into fine particles in an organic solvent, which not only reduces the desulfurization capability of hydroxyl oxidize iron, but also causes the recycled sulfur to contain a large number of iron.

The invention discloses an aluminum content control method. The aluminum content control method is used for reducing the quantity of inclusions in ultra-low sulfur steel and controlling the aluminum content in the steel, and comprises the following steps that the slag amount is controlled in a primary smelting furnace and the slag adding amount is controlled in an LF; a refining reducing slag system is selected in the LF refining process so as to keep high dissolved aluminum content control in the LF refining process and at the end of the LF refining process; in the whole VD refining process,aluminum is forbidden to be supplemented into molten steel; under the LF refining and VD refining deep vacuum state, steel slag large bottom blowing flow stirring is carried out, it is guaranteed thatmolten steel, refining slag and inclusions react sufficiently, and after VD vacuum breaking, Ca line feeding treatment and soft blowing are carried out; and after the molten steel is rolled, the maximum inclusions are less than 20 microns, and the distribution density of various inclusions of 5-20 microns is 0.2-0.8/mm < 2 >.

The invention discloses a rotational flow reaction device and a flue gas desulfurization device. The rotational flow reaction device comprises a rotational flow shell and at least two rotational flow chambers, wherein each rotational flow chamber is provided with at least one swirler, a circular reaction slurry inlet is formed in the upper portion of each rotational flow chamber, and the lower side of each rotational flow chamber is communicated with a gas uniformizing chamber. Each swirler is a swirl impeller comprising an impeller shell, an impeller center shaft and at least five swirl vanes surrounding the impeller center shaft, wherein the impeller shell is fixed in the corresponding rotational flow chamber, the inner edge of each swirl vane is fixed to the impeller center shaft, and the outer edge of each swirl vane is fixed to the impeller shell. A flue gas flow regulating device is arranged on the top of each rotational flow chamber, can open and close the rotational flow chamber, and is connected with the top of the rotational flow chamber. The rotational flow reaction device is simple in structure, the number of the rotational flow chambers involved in reaction can be selected, the velocity of flue gas can be effectively controlled, flue gas desulfurization effect and degree can be guaranteed, energy can be saved, and environment pollution can be avoided.

The invention relates to a preparation method of a zinc-iron composite oxide loaded activated carbon desulfurizer, which comprises the following steps: impregnating activated carbon with the water content of 0.1-0.5 wt% in a zinc-iron mixed solution at 60-80 DEG C, and controlling the impregnation time according to the bulk density of the activated carbon; drying the impregnated activated carbon,and controlling the drying rate according to the adsorption saturation of the activated carbon during the period; and roasting the dried activated carbon at 500-700 DEG C for 2-4 hours to obtain the finished product of the zinc-iron composite oxide loaded activated carbon desulfurizer. By improving and innovating the preparation process, the loading uniformity and dispersity of the active components on the carrier are greatly improved, and the sulfur capacity and desulfurization precision of the loaded activated carbon desulfurizer are effectively improved, so that hydrogen sulfide in the chemical production process is efficiently and stably removed, equipment corrosion is prevented, and the environment is protected.

The invention belongs to the field of chemical industry, and specifically relates to a removal method for impurity ions in an organic amine desulfurized solution. The invention is to solve a technicalproblem of providing the removal method for the impurity ions in the organic amine desulfurized solution. The removal method comprises the following steps: allowing an organic amine desulfurized richliquor to pass through a cation resin exchange column of chelated resin so as to adsorb Fe3+ and Cu2+ ions, allowing the obtained organic amine desulfurized rich liquor to enter a regeneration tower,carrying out SO2 regeneration so as to obtain a poor liquor, allowing the poor liquor to pass through an anionic resin exchange column of macroporous weakly basic resin so as to remove Cl-, and allowing the obtained poor liquor to enter a freezing crystallization system so as to remove SO4<2->. The method provided by the invention can purify a used organic amine desulfurizer, reduces poisoning ofthe desulfurizer, stabilizes the effect of desulfurization, reduces the operation cost of desulfurization, and guarantees normal and stable operation of a desulfurization system.