A long afterglow luminescent fire sign and its preparation method
A long afterglow luminous and fire-fighting technology, which is applied to illuminated signs, instruments, display devices, etc., can solve the problems of light storage speed, luminous brightness and luminous duration, etc., and achieve long luminous time, improved performance, and high light intensity. Effect
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Embodiment 1
[0051] 1. Preparation of oxide ultrafine particle powder raw materials
[0052] 1. Put 10g of yttrium oxide with a purity of 99.995% in an agate mortar, then add 10g of absolute ethanol, stir, and mix well, then place it in a ball mill and grind it for 10 hours until the average particle size of yttrium oxide reaches 1- 10 μm, to obtain a mixture of yttrium oxide and absolute ethanol;
[0053] 2. Add 100mL of deionized water to the container, slowly add 15mL of the above mixed solution and 20mL of concentrated ammonia water into the deionized water under stirring at room temperature (25°C), and stir until the precipitate is completely dissolved to obtain yttrium oxide. mixture;
[0054] 3. Add 20 mL of MnSO with a concentration of 10% by mass to the mixed solution in which the above precipitate is completely dissolved. 4 After mixing the solution evenly, place it in a mixer and stir for 2 hours until a colloidal solution is formed;
[0055] 4. Add 250mL polytetrafluoroethyl...
Embodiment 2
[0077] According to the following mass percentages, the raw materials of the oxide ultrafine particle powders doped with manganese elements prepared in Example 1 were weighed respectively, and the raw materials totaled 100g:
[0078] Raw material of magnesium oxide ultrafine particle powder: 15%
[0079] Titanium oxide ultrafine particle powder raw material: 15%
[0080] Raw material of yttrium oxide ultrafine particle powder: 14%
[0081] Europium oxide ultrafine particle powder raw material: 18%
[0082] Zinc oxide ultrafine particle powder raw material: 20%
[0083] Silicon oxide ultrafine particle powder raw material: 18%
[0084] According to the method described in Example 1, the above-mentioned oxide ultrafine particle powder raw materials were uniformly mixed to produce an energy storage type long-lasting luminescent material. The results of the luminous brightness and continuous luminescent time of the luminescent material are shown in Table 1;
[0085] In additio...
Embodiment 3
[0087] According to the following mass percentages, the raw materials of the oxide ultrafine particle powders doped with manganese elements prepared in Example 1 were weighed respectively, and the raw materials totaled 100g:
[0088] Raw material of magnesium oxide ultrafine particle powder: 20%
[0089] Raw material of yttrium oxide ultrafine particle powder: 20%
[0090] Aluminum oxide ultrafine particle powder raw material: 20%
[0091] Strontium oxide ultrafine particle powder raw material: 20%
[0092] Silicon oxide ultrafine particle powder raw material: 20%
[0093] According to the method described in Example 1, the above-mentioned oxide ultrafine particle powder raw materials were uniformly mixed to produce an energy storage type long-lasting luminescent material. The results of the luminous brightness and continuous luminescent time of the luminescent material are shown in Table 1;
[0094] In addition to punching a 1.5mm thick iron plate into image 3 The shape ...
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