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Novel reusable water writing paper

A new type of technology for water writing paper, applied in the field of water writing paper, which can solve the problems of low contrast and resolution, limited application scope, etc.

Active Publication Date: 2015-06-10
JILIN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, they are all based on the fact that the sprayed white layer becomes transparent when it meets water, and the carbon black layer or the color of the dark base paper realizes the physical property change of water writing. The water writing paper prepared by this method shows mostly black color, contrast and resolution. The rate is not high, and the scope of application is limited to calligraphy and painting exercises

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0016] Using filter paper as the base, polyethylene glycol as the composite material matrix composed of performance-enhancing additives, and oxazoline hydrochromic dyes as the color-developing components, by physically doping the color-developing components into the matrix, the present invention can be obtained. Invent new products. Writing with a brush or pen dipped in clean water, or spraying water with a stencil, can clearly display the handwriting or pattern, leave it to volatilize naturally, or place it on a heating platform at a certain temperature for a certain period of time, or blow it with a hair dryer for a certain period of time, then the writing will be completed. The words or patterns disappear, and can be repeated many times. According to the different substituents on the molecules of the oxazoline hydrochromic dyes, water writing papers with different color handwriting or pattern display can be obtained.

Embodiment 2

[0018] The chromogenic component as described in Example 1 is (E)-4-(2-(9,9-dimethyl-2,3,9,9a-tetrahydrooxazoline[3,2-a ]indole-9a-)vinyl)-N,N-dimethylaniline dye, with polyethylene glycol as the color retention agent and binder in the performance enhancer, and polyethylene oxide as the performance enhancer, it It has the functions of moisture-proof, sun-proof, and leak-proof. The dye molecules are soluble in ethanol, and polyethylene glycol is soluble in water. Water writing paper can be obtained by heat treatment. The writing on the water writing paper will appear rose red after dipped in water with a pen or brush. Under natural environment, the writing will disappear in 30 minutes and can be reused many times.

Embodiment 3

[0020] The chromogenic component as described in Example 1 is (E)-4-(2-(9,9-dimethyl-2,3,9,9a-tetrahydrooxazoline[3,2-a ]indole-9a-)vinyl)-N,N-dimethylaniline dye, with polyethylene glycol as the color retention agent and binder in the performance enhancer, and polyethylene oxide as the performance enhancer, it It has the functions of moisture-proof, sun-proof, and leak-proof. The dye molecules are soluble in ethanol, and polyethylene glycol is soluble in water. Water writing paper can be obtained by heat treatment on the paper base. The water writing paper will appear rose red after being written with a pen or brush dipped in clean water, and the writing will disappear in half a minute when heated on a 70-degree heating platform, and can be reused many times.

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PUM

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Abstract

The invention relates to a new type of reusable water writing paper. The water writing paper is composed of a color-developing component and a matrix. The color component, when exposed to water, can undergo a change in molecular configuration or conformation to cause an obvious color change and develop color. After the water dries, the molecular structure will recover and the color will fade, and different colors can be displayed through the change of molecular substituents. It can be written like a handwriting Clear, not easy to spread, smooth surface, reusable, it is not only suitable for brush books, drawing exercises, but also for daily writing with pens, in addition, it can also use water spray to achieve ink-free printing, due to the special response to water, this type of Water writing paper can also be used in humidity detection cards, security and anti-counterfeiting and other fields.

Description

technical field [0001] The invention relates to a novel reusable water writing paper which develops color when exposed to water. It belongs to the field of reusable writing and printing materials. Background technique [0002] The waste of one-time writing or printing paper is serious. From the perspective of protecting the environment and reusing resources, the recycling of paper is particularly important. There are also a large number of reusable water-colored water writing papers on the market at present, but the existing water writing papers are all composed of paper base, carbon black layer and spray white layer or directly composed of dark base paper and spray white layer. For example, Chinese patent CN2628572Y discloses a reusable water writing paper. However, they are all based on the fact that the sprayed white layer becomes transparent when it meets water, and the carbon black layer or the color of the dark base paper realizes the physical property change of wate...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B43L1/00D21H27/00
Inventor 张晓安盛兰李敏杰
Owner JILIN UNIV
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