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A lithium-ion battery core aluminum-plastic film made by hot-melt adhesive coating process

A lithium-ion battery and coating technology, which is applied to battery components, circuits, electrical components, etc., can solve the problems affecting the material's deep-drawing performance, appearance and anti-short circuit performance, inner polypropylene film aging, and electrolyte resistance Poor performance and other problems, to achieve the effect of excellent electrolyte corrosion resistance, high electrolyte corrosion resistance, and good cold stamping formability

Active Publication Date: 2016-11-23
江苏锦尚新材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The representative manufacturer of the all-dry process is Showa Denko Corporation of Japan. It is characterized in that the three layers of nylon, aluminum foil, and polypropylene film are bonded with two-component glue. The advantages lie in excellent cold stamping, anti-short circuit, and waterproof properties. Its disadvantage lies in its poor resistance to electrolyte; the representative manufacturer of thermal process is Japan Dainippon Printing Co., Ltd., which is characterized in that the outer nylon layer and the aluminum foil layer are bonded with glue, while the inner layer of polypropylene film and the inner layer of aluminum foil are glued together. MPP is then thermally synthesized under the conditions of increasing temperature and pressure. The advantage is that it has excellent electrolyte resistance and heat sealing performance. The disadvantage is that the production process is long, and the aluminum foil is embrittled and the inner layer of polypropylene is caused by long-term high-temperature baking. Aging of the film, which affects the drawing properties, appearance and short-circuit resistance of the material

Method used

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  • A lithium-ion battery core aluminum-plastic film made by hot-melt adhesive coating process

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] Embodiment 1, configure the treatment solution according to the following formula: the chromium salt is potassium dichromate, and the mass percentage concentration in the mixed solution is 0.3%; the acid is hydrochloric acid, and the mass percentage concentration in the mixed solution is 4%; the fluoride is fluoride Potassium, the mass percent concentration in the mixed solution is 0.2%; the rest is pure water. Use this treatment liquid to process 40μm thick grade 8021 soft aluminum foil on the aluminum foil processing machine; the treated aluminum foil is coated with a layer of 4μm thick PP hot melt adhesive on the aluminum foil coating machine, and compounded with two-component polyurethane glue to 25μm in the dry process machine After the polyamide film and the aluminum foil coated with hot melt adhesive, the surface of the aluminum foil that is not coated with hot melt adhesive is the composite surface, and the thickness of the adhesive layer is 5 μm; the above-menti...

Embodiment 2

[0026] Embodiment 2, configure the treatment solution according to the following formula: the chromium salt is chromium oxide, and the mass percentage concentration in the mixed solution is 0.4%; the acid is boric acid, and the mass percentage concentration in the mixed solution is 8%; the fluoride is sodium fluoride in The mass percentage concentration in the mixed solution is 00.4%; the remaining components are pure water. Use this treatment liquid to process 40μm thick grade 8021 soft aluminum foil on the aluminum foil processing machine; the treated aluminum foil is coated with a layer of 4μm thick PP hot melt adhesive on the aluminum foil coating machine, and compounded with two-component polyurethane glue to 25μm in the dry process machine Polyamide film and aluminum foil coated with hot-melt adhesive, the surface of the aluminum foil not coated with hot-melt adhesive is the composite surface, and the thickness of the adhesive layer is 5 μm; the above-mentioned semi-finis...

Embodiment 3

[0027] Embodiment three, according to the following formula configuration treatment liquid: chromium salt is potassium chromate, and the mass percent concentration in the mixed solution is 0.5%; The acid is phosphoric acid, and the mass percent concentration in the mixed solution is 7%; Fluoride is potassium fluoride The mass percent concentration in the mixed solution is 0.5%; the rest is pure water. Use this treatment solution to process 40 μm thick grade 8021 soft aluminum foil on the aluminum foil processing machine; use two-component polyurethane glue to compound 15 μm thick polyamide film and treated aluminum foil in the dry process machine, and the thickness of the glue layer is 5 μm; the surface of the above-mentioned semi-finished aluminum foil is The AC gluing part of the extruder is directly coated with PP hot melt adhesive, the thickness of the coating is 3μm, and the finished product can be obtained by pouring a heat-sealing layer on the glue surface after coating....

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Abstract

An aluminum-plastic film for lithium-ion battery cores produced by a hot-melt adhesive coating process, which is characterized in that it includes a protective layer, an adhesive layer, a chemical treatment layer I, an aluminum foil layer, a chemical treatment layer II, and a hot-melt adhesive. layer and a heat-sealing layer; the chemical treatment layer is a dense metal oxide film layer formed on the surface of the aluminum foil by chemically treating the surface of the aluminum foil; the dense metal oxide film layer is made of chromium salt, acid, fluoride and water The mixed solution is formed by chemically treating the surface of the aluminum foil; the aluminum-plastic film of the present invention can be used for the packaging of lithium-ion battery cores, and has excellent electrolyte corrosion resistance, good cold stamping performance, heat-sealing performance, and the thickness of the heat-sealing layer can be It can be adjusted online in the range of 20-100 microns, so that battery films of different thicknesses can be produced, and it has the advantages of dry compounding and thermal compounding to make aluminum-plastic films for lithium batteries.

Description

technical field [0001] The invention relates to a lithium-ion battery flexible packaging technology, in particular to an aluminum-plastic film for a lithium-ion battery core produced by a hot-melt adhesive coating process. Background technique [0002] At present, the aluminum-plastic film packaging materials used in flexible packaging lithium-ion batteries are mainly provided by Japan, and the production process is generally divided into dry lamination or thermal lamination. The representative manufacturer of the all-dry process is Showa Denko Corporation of Japan. It is characterized in that the three layers of nylon, aluminum foil, and polypropylene film are bonded with two-component glue. The advantages lie in excellent cold stamping, anti-short circuit, and waterproof properties. Its disadvantage lies in its poor resistance to electrolyte; the representative manufacturer of thermal process is Japan Dainippon Printing Co., Ltd., which is characterized in that the outer n...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B32B9/04B32B15/20B32B27/32B32B27/34B32B27/36B32B7/12B32B33/00H01M2/02H01M50/128H01M50/129H01M50/145
CPCY02E60/10
Inventor 张兴洋单宁于广省梁裕波江灿灿何建中徐根华张军伏阳陈强吴新上
Owner 江苏锦尚新材料有限公司
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