A preparation method and application technology of polyionic liquid functionalized nanofibers
A polyionic liquid and nanofiber technology, applied in the field of anti-radiation materials, can solve problems such as human hazards, difficult removal, and damage to the human body, and achieve the effects of reducing radiation hazards, good adsorption effect, and efficient adsorption
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[0017] A preparation method for polyionic liquid functionalized nanofibers, comprising the following steps:
[0018] (1) Preparation of polyionic liquid;
[0019] (2) The polyionic liquid and the base material are mixed at a mass ratio of 1: 1 and dissolved in a solvent to form a mixed solution; the polyionic liquid is 1-ethyl-3-methylimidazolium tetrafluoroborate , 1-ethyl-3-methylimidazole acetate, 1-ethyl-3-methylimidazole dinitrile amine salt, 1-butyl-3-methylimidazolium chloride salt, 1-butyl-3- Methylimidazole tetrafluoroborate, 1-(4-vinylbenzyl)-3-butylimidazole tetraborate, 1-butyl-3-methylimidazolium hexafluorophosphate, 1-butyl- 3-Methylimidazole trifluoromethanesulfonimide salt, 1-butyl-3-methylimidazole trifluoromethanesulfonate, 1-hydroxyethyl-3-methylimidazole tetrafluoroborate, 1- Aminoethyl-3-methylimidazolium tetrafluoroborate, 1-cyanopropyl-3-methylimidazolium tetrafluoroborate, 1-ethoxyethyl-3-methylimidazolium tetrafluoroborate , 1-allyl-3 methylimidazol...
Embodiment 1
[0023] Preparation of anti-radiation screens and curtains: Take 1kg of poly 1-ethyl-3-methylimidazole acetate and 1kg of polyacrylic acid, put them in a container, add 20L of N,N-dimethylformamide, and stir until dissolved. Cover the screen window cloth or curtain cloth on the receiving screen, and evenly spin the above solution on the base material fabric on the receiving screen by electrospinning to form radiation-proof screens and radiation-proof curtains, which can absorb and filter. 131 The role of to reduce indoor radiation hazards.
Embodiment 2
[0025] Prepare anti-radiation sachet: get 5g poly 1-(4-vinylbenzyl)-3-butylimidazole tetraborate, 5g poly 1-butyl-3-methylimidazolium chloride salt, 5g polyacrylonitrile and Put 5g of polystyrene in a container, add 2L of tetrahydrofuran, and stir until dissolved. The solution is prepared into polyionic liquid functionalized nanofibers by electrospinning, and then the polyionic liquid functionalized nanofibers are sewn into a sachet to form a radiation-proof sachet. Place the above-mentioned radiation-emitting sachet in the car, indoor or carry it with you, it can absorb the surrounding I 131 , thereby reducing the I entering the body 131 , play a role in reducing radiation hazards.
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