Flame-retardant brominated butyl rubber material and preparation method thereof

A technology of brominated butyl rubber and rubber compound, which is applied in the field of rubber materials, can solve the problems of poor wear resistance, low mechanical properties, corrosion resistance, ozone resistance and ultraviolet resistance, etc., and achieve good wear resistance and mechanical properties. The effect of excellent performance, mutual adhesion and improved co-crosslinking ability

Inactive Publication Date: 2014-12-10
ANHUI MEIXIANG IND
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Among the numerous flame retardant products, brominated flame retardants rank first among all kinds of flame retardants in terms of market size and application fields for a long time, and its excellent cost performance is unmatched by other flame retardants. The application number is CN201210007204. 9 discloses a preparation method of a halogen-free flame-retardant rubber composite material, the steps are: A, forming Al(OH)3 nanoparticles; B, placing the nano-aluminum hydroxide particles obtained in step A in a blast drying box , drying; the drying is to dry the mixture of aluminum hydroxide nanoparticles and silane coupling agent solution at 150°C for 50min; C, EPDM rubber after mastication / banburying ( In EPDM), add the aluminum hydroxide nano-particle of step B, also add rubber oil, promotor, vulcanizing agent, repeatedly knead to uniform on the roller, thin pass next sheet, obtain EPDM rubber compound rubber; D, Put the kneaded EPDM flame retardant rubber into the mold, cold press and fill the mold for the first vulcanization, and then put it in the blast drying oven on the glass cloth for secondary vulcanization to obtain the finished halogen-free flame retardant rubber composite material. This kind of flame-retardant rubber material has poor corrosion resistance, ozone resistance and ultraviolet resistance, and has relatively low mechanical properties and poor wear resistance.

Method used

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  • Flame-retardant brominated butyl rubber material and preparation method thereof
  • Flame-retardant brominated butyl rubber material and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0016] A flame-retardant brominated butyl rubber material and a preparation method thereof, wherein the chemical composition ratio of the flame-retardant brominated butyl rubber material includes 88 parts of brominated butyl rubber, 9 parts of chlorinated polyethylene, 2 parts of stearic acid 2 parts, 2 parts of zinc chloride, 2 parts of magnesium chloride, 2 parts of anti-aging agent, 3 parts of paraffin, 74 parts of flame retardant HT, 32 parts of complexed antimony, 2 parts of sulfur and 2 parts of accelerator.

[0017] A kind of preparation method of flame retardant brominated butyl rubber material, described preparation process is carried out according to the following steps,

[0018] (1) Compound mixing: Put the prepared bromobutyl rubber compound into the open mill for mixing, control the roll temperature of the open mill to 35°C, mix for 8 minutes, add chlorinated polystyrene after wrapping the roll Vinyl, and make 2 triangular bags;

[0019] (2) Mixing and tableting:...

Embodiment 2

[0022] Embodiment 2: The rest are the same as in Example 1, except that the chemical composition ratio of the flame-retardant brominated butyl rubber material includes 90 parts of brominated butyl rubber, 10 parts of chlorinated polyethylene, 2 parts of stearic acid part, 3 parts of zinc chloride, 1 part of magnesium chloride, 2 parts of antioxidant, 2 parts of paraffin, 76 parts of flame retardant HT, 30 parts of complexed antimony, 1.5 parts of sulfur and 2.5 parts of promotor; , control the roll temperature to be 38°C, knead for 9min, and make 3 triangular bags; in the step (2), add 10 parts of Qiangwei powder, and make 4 triangular bags; in the step (3), control the parking time is 24h; in the step (4), the control vulcanization temperature is 151° C., and the control vulcanization time is 30 min.

Embodiment 3

[0023] Embodiment 3: the rest are the same as in Example 1, except that the chemical composition ratio of the flame-retardant brominated butyl rubber material includes 92 parts of brominated butyl rubber, 12 parts of chlorinated polyethylene, 1 part of stearic acid part, 2 parts of zinc chloride, 2 parts of magnesium chloride, 3 parts of antioxidant, 3 parts of paraffin, 77 parts of flame retardant HT, 30 parts of complexed antimony, 2 parts of sulfur and 3 parts of accelerator; In the described step (1) , control roll temperature is 40 ℃, mixing 10min, makes 3 triangular bags; In described step (2), adds 12 parts of zinc borates, makes 4 triangular bags; In described step (3), control parking time is 25h; in the step (4), the vulcanization temperature is controlled to be 155° C., and the vulcanization time is controlled to be 35 min.

[0024] After the above process steps, the flame retardant rubber sample is taken out to be tested:

[0025]

[0026]

[0027] From the ...

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Abstract

The invention discloses a flame-retardant brominated butyl rubber material, relating to the technical field of rubber materials. The flame-retardant brominated butyl rubber material comprises the following chemical components: 85-95 parts of brominated butyl rubber, 8-12 parts of chlorinated polyethylene, 1-4 parts of stearic acid, 2-5 parts of zinc chloride, 1-2 parts of magnesium chloride, 1-3 parts of anti-aging agent, 1-3 parts of paraffin, 68-80 parts of flame retardant HT, 25-35 parts of complexed antimony, 1-3 parts of sulfur and 1-4 parts of accelerator. The invention also discloses a preparation method of the flame-retardant brominated butyl rubber material, which comprises the following steps: compounding the rubber matrix, mixing, batching off, stopping, and vulcanizing. The rubber material prepared by the method has the advantages of favorable flame retardancy, fire retardancy, high strength, excellent mechanical properties and favorable wear resistance, and can adapt to long-time friction without being damaged. By adding the environment-friendly flame retardant in the mixing process, the flame retardancy is further enhanced. The preparation technique is simple and easy to master.

Description

technical field [0001] The invention relates to the technical field of rubber materials, in particular to a flame-retardant brominated butyl rubber material, and also to a preparation method of the flame-retardant brominated butyl rubber material. Background technique [0002] Due to the light weight, water resistance, moisture resistance, excellent electrical insulation properties and excellent molding processability of polymer materials such as rubber, they are widely used in aviation, transportation, construction and household appliance industries. However, because most of the polymer materials are hydrocarbons, they are flammable, and fires are often caused by overheating and short circuits. Therefore influenced to a certain extent the further popularization of macromolecular materials such as rubber in the electrical industry. Therefore, solving the flame retardant problem of polymer materials such as rubber has become an important issue in the development of the curre...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/28C08K13/02C08K5/09C08K3/16C08K5/01C08K3/06C08K3/22C08K3/38B29C35/02
CPCC08L23/283B29C35/02C08L2201/02C08L2201/08C08L2205/03C08L23/286C08L91/06C08K13/02C08K5/09C08K2003/168C08K3/06C08K2003/387
Inventor 孙宝林
Owner ANHUI MEIXIANG IND
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