A kind of polymer resin laminated glass glue and preparation method thereof

A technology of polymer resin and laminated glass, used in non-polymer adhesive additives, adhesives, adhesive additives, etc., can solve the problems of difficult quality control, complicated curing process, poor adhesion, etc., and reduce the number of products. Control the difficulty, simplify the process operation, easy to release the effect of air bubbles

Active Publication Date: 2016-08-17
BEIJING BOMINGTANG GLASS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] Although acrylic polymers have good transparency and excellent optical properties, acrylic polymers (such as PMMA) themselves have high hardness and are brittle. After adding plasticizers, the hardness can be reduced, but due to the migration of plasticizers, the product Poor adhesion and decreased transparency during use
The curing process requires ultraviolet light (sunlight) or heating equipment to initiate crosslinking, so the curing process is complicated, quality control is difficult, and production costs are high

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] A kind of macromolecular resin laminated glass glue described in the embodiment of the present invention 1, by the polyurethane modified polyester resin of 52kg, the m-phenylene unsaturated polyester resin of 20kg, the hydroxypropyl acrylate liquid of 6kg, the styrene liquid of 15kg, 2kg of cobalt naphthenate solution, 1kg of 2-hydroxy-4-n-octyloxybenzophenone (UV-531), 1kg of defoamer BYK-555, and 3kg of methyl ethyl ketone peroxide.

[0026] A kind of preparation method of polymer resin laminated glass glue described in embodiment 1 of the present invention comprises the following steps:

[0027] Get 52kg of polyurethane-modified polyester resin and 20kg of m-phenylene unsaturated polyester resin and put them into a container cylinder to stir and mix; then add 6kg of hydroxypropyl acrylate liquid, 15kg of styrene liquid, 2kg of cobalt naphthenate solution, and 1kg of Anti-ultraviolet agent and 1kg of defoamer BYK-555, at room temperature, start the electric stirring b...

Embodiment 2

[0030] A kind of macromolecular resin laminated glass glue described in the embodiment of the present invention 2, by the polyurethane modified polyester resin of 45kg, the m-phenylene unsaturated polyester resin of 25kg, the hydroxypropyl acrylate liquid of 6kg, the styrene liquid of 17kg, 1.5kg cobalt naphthenate solution, 1.5kg anti-ultraviolet agent 2-(2-hydroxy-5-methylphenyl) benzotriazole (UV-P), 2kg defoamer BYK-555, 2kg Made from methyl ethyl ketone peroxide.

[0031] A kind of preparation method of polymer resin laminated glass glue described in embodiment 2 of the present invention comprises the following steps:

[0032] Get 45kg of polyurethane-modified polyester resin and 25kg of m-phenylene unsaturated polyester resin and put them into a container and mix them; then add 6kg of hydroxypropyl acrylate liquid, 17kg of styrene liquid, 1.5kg of cobalt naphthenate solution, 1.5 Kg of anti-ultraviolet agent and 2kg of defoamer BYK-555, under normal temperature, start t...

Embodiment 3

[0035] A kind of macromolecular resin laminated glass glue described in the embodiment of the present invention 3, by the polyurethane modified polyester resin of 60kg, the m-phenylene unsaturated polyester resin of 18kg, the hydroxypropyl acrylate liquid of 8kg, the styrene liquid of 10kg, 2kg cobalt naphthenate solution, 1.7kg anti-ultraviolet agent 2-hydroxy-4-n-octyloxybenzophenone (UV-531), 1.3kg antifoaming agent BYK-555, 1kg methyl ethyl ketone peroxide .

[0036] A kind of preparation method of polymer resin laminated glass glue described in embodiment 3 of the present invention comprises the following steps:

[0037] Get 60kg of polyurethane-modified polyester resin and 18kg of m-phenylene unsaturated polyester resin and put them into a container and mix them; then add 8kg of hydroxypropyl acrylate liquid, 10kg of styrene liquid, 2kg of cobalt naphthenate solution, and 1.7kg of 1.3kg of anti-ultraviolet agent and 1.3kg of defoamer BYK-555, at room temperature, start ...

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Abstract

The invention relates to a polymer resin laminated glass glue, which is made of the following raw materials in weight percentage: 40-65% of polyurethane modified polyester resin, 10-30% of m-benzene unsaturated polyester resin, 5-5% of hardness regulator 10%, viscosity reducing diluent 10~30%, curing agent 0.5~4%, curing accelerator 0.1~3%, anti-ultraviolet agent 0.5~2% and defoamer 1~3%, the preparation method comprises the following steps: Polyurethane modified polyester resin and m-phenylene unsaturated polyester resin are added into the container cylinder and stirred and mixed; then hardness modifier, viscosity reducing diluent, curing accelerator, anti-ultraviolet agent and defoamer are added to the reactor, Start the stir bar at room temperature and stir for a few minutes; add curing agent and mix well. The beneficial effects of the present invention are: it can be fully cured at normal temperature and pressure, and at the same time, the viscosity of the colloid is low, it is easy to release air bubbles, and the process operation on production is simplified and convenient. glue.

Description

technical field [0001] The invention relates to the technical field of glass processing, in particular to a polymer resin laminated glass glue and a preparation method thereof. Background technique [0002] Laminated glass is a composite material in which glass and glass are separated by an intermediate layer and bonded together through treatment. It is generally used for the manufacture of safety glass, bulletproof glass, architectural decorative glass, art glass, etc. After the polymer resin laminated glass glue is cured, it can be used as the middle separation layer. Laminated glass production methods include dry production process and wet production process. The process of curing with glue is called wet process. Polymer resin laminated glass glue can also be called wet glass glue. [0003] The application technical performance of laminated glass requires optical properties (visible light transmittance, visible light reflectance, some products require ultraviolet transmi...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09J167/00C09J167/06C09J11/06
Inventor 井长水操宏智
Owner BEIJING BOMINGTANG GLASS
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