A kind of treatment method of waste lithium iron phosphate power battery

A power battery and lithium iron phosphate technology, which is applied in the field of waste lithium iron phosphate power battery treatment, can solve the problems of high recycling rate of lithium iron phosphate power battery, complicated process steps, and high processing cost, and achieve low cost and high process steps. Simple, safe and effective

Active Publication Date: 2016-12-28
WANXIANG 123 CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The present invention aims to solve the problems that the prior art lithium iron phosphate power battery treatment method is not thorough, the process steps are complicated, the treatment cost is high, and it will affect the environment. It provides a treatment method for waste lithium iron phosphate power battery. The process steps of the treatment method are simple, low in cost, and environmentally friendly. It not only treats the lithium iron phosphate power battery thoroughly, but also has a high recycling rate for the lithium iron phosphate power battery.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] (1) Cut off and recycle the positive and negative tabs of the power battery.

[0032] (2) After drilling holes in the aluminum-plastic film of the power battery outer packaging after cutting off the positive and negative pole ears, place the power battery in the first strong alkali solution at 70°C for 12 hours at a constant temperature, take out and drain the power battery Filtrate the first strong alkali solution to obtain the first filtrate, during which air is continuously introduced, the air intake rate is 5L / min, the hole diameter formed by drilling is 2mm, and the hole density is 3 per square decimeter, the first strong alkali solution For NaOH solution, the OH in the first strong base solution — The concentration is 0.5mol / L, and the mass of the first strong alkali solution is 4 times of the total mass of the power battery.

[0033] (3) Separate the aluminum-plastic film and battery cells in the drained power battery, and recycle the aluminum-plastic film.

[...

Embodiment 2

[0038] (1) Cut off and recycle the positive and negative tabs of the power battery.

[0039] (2) After drilling holes in the aluminum-plastic film of the power battery outer packaging after cutting off the positive and negative pole ears, place the power battery in the first strong alkali solution at 80°C for 8 hours at a constant temperature, take out and drain the power battery Filtrate the first strong alkali solution to obtain the first filtrate, during which air is continuously introduced, the air intake rate is 7L / min, the hole diameter formed by drilling is 3mm, and the hole density is 2 per square decimeter, the first strong alkali solution It is a mixed solution of NaOH and KOH, the OH in the first strong alkali solution — The concentration is 1 mol / L, and the mass of the first strong alkaline solution is 3 times of the total mass of the power battery.

[0040] (3) Separate the aluminum-plastic film and battery cells in the drained power battery, and recycle the alum...

Embodiment 3

[0045] (1) Cut off and recycle the positive and negative tabs of the power battery.

[0046] (2) After drilling holes in the aluminum-plastic film of the power battery outer packaging after cutting off the positive and negative tabs, place the power battery in the first strong alkali solution at 90°C for 3 hours at a constant temperature, take out and drain the power battery Filtrate the first strong alkali solution to obtain the first filtrate, during which air is continuously introduced, the air intake rate is 10L / min, the hole diameter formed by drilling is 4mm, and the hole density is 1 per square decimeter, the first strong alkali solution For KOH solution, the OH in the first strong base solution — The concentration is 2mol / L, and the mass of the first strong alkali solution is twice the total mass of the power battery.

[0047] (3) Separate the aluminum-plastic film and battery cells in the drained power battery, and recycle the aluminum-plastic film.

[0048] (4) Soa...

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Abstract

The invention discloses a processing method of a waste lithium iron phosphate power battery, wherein the processing method comprises the following steps: (1) recycling tabs of the power battery; (2) drilling holes on an aluminum plastic film of the power battery, carrying out constant temperature soaking of the battery in a 70-90 DEG C first strong alkali solution for 3-12 h, and filtering to obtain a first filtrate; (3) separating the aluminum plastic film with an electrical core; (4) placing the electrical core in a second strong alkali solution, soaking, and filtering the second strong alkali solution to obtain a filter residue and a second filtrate; (5) adding diluted hydrochloric acid into the filter residue, regulating the pH to 7, and then filtering to obtain a filtered substance and a third filtrate; and (6) drying the filtered substance to obtain a solid waste, merging the first filtrate, the second filtrate and the third filtrate to obtain an alkali-containing solution, adding a strong alkali into the alkali-containing solution to prepare a strong alkali solution having the same OH<-> concentration as the first strong alkali solution, and then replacing the first strong alkali solution for recycling. The processing method has the advantages of simple process steps, low cost, thorough treatment on the lithium iron phosphate power battery, high recycling rate, environmental protection, and high safety.

Description

technical field [0001] The invention relates to the technical field of recycling waste lithium ion batteries, in particular to a treatment method for waste lithium iron phosphate power batteries. Background technique [0002] Lithium iron phosphate batteries are widely used as power batteries because of their safety, good cycle performance, stable voltage, and good rate performance. Correspondingly, the treatment of waste lithium iron phosphate batteries has attracted more and more attention and attention. [0003] Application publication number CN102664294A, the Chinese patent application publication date 2012.09.12 discloses a recycling method for waste lithium iron phosphate batteries, the steps are as follows: remove the residual power from waste lithium iron phosphate batteries, take out the batteries and crush them into batteries Fragments, soaked in sodium hydroxide solution and stirred, then filtered, washed, dried and vibrating sieved, the pure aluminum, pure coppe...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01M10/54
CPCY02W30/84
Inventor 石先兴葛民民谭东庆吕豪杰陈军
Owner WANXIANG 123 CO LTD
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