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Steelmaking method for vanadium-titanium-containing high-phosphorus molten iron

A high-phosphorus and molten iron technology, applied in the field of steelmaking, can solve the problems of large impact on steelmaking, difficulty in eliminating iron, and restrictions on industrial utilization, so as to improve the intensity of oxygen supply in steelmaking, ensure the ability of iron elimination in steelmaking, and reduce the The effect of material consumption

Active Publication Date: 2016-08-24
SICHUAN DESHENG GRP VANADIUM & TITANIUM CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Although the price of high-phosphorus oolitic hematite is low, due to its high phosphorus content, the molten iron obtained by using the high-phosphorus oolitic hematite has high phosphorus content, especially under the conditions of vanadium-titanium blast furnace smelting, molten iron It has high content of vanadium (0.3%), sulfur (0.05%~0.15%), phosphorus (0.2%~0.3%) and generally low temperature of molten iron (reaching the temperature of molten steel for smelting is 1250°C~1300°C) and the slag rate High (about 7%) and other characteristics, the condition of the molten iron is worse than that of ordinary high-titanium smelting molten iron, the steelmaking process needs to go through desulfurization, slag removal, vanadium extraction, steelmaking and deoxidation alloying and other processes, the process flow is more general It takes a long time to smelt hot metal, and the output of blast furnace iron continues to increase, and the iron elimination capacity of steelmaking can increase from 5,800 tons / day to 6,300-6,500 tons / day
Such a long smelting cycle, great difficulty in iron elimination, great impact on steelmaking, brings great difficulty to vanadium extraction and steelmaking production, thus restricting the industrial utilization of this mine to a certain extent

Method used

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  • Steelmaking method for vanadium-titanium-containing high-phosphorus molten iron
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  • Steelmaking method for vanadium-titanium-containing high-phosphorus molten iron

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preparation example Construction

[0105] The dephosphorizing slag agent preferably also includes sulfur, and in the present invention, the mass fraction of the sulfur is preferably ≤0.065%, more preferably ≤0.05%, and most preferably ≤0.03%. The present invention has no special limitation on the source of the desulfurization slag agent, and the preparation method of the dephosphorization slag agent preferably includes the following steps:

[0106] The dephosphorization slag agent is obtained by mixing 25%-45% of CaO, 12%-30% of MgO, 8%-25% of FeO and 8%-25% of SiO. In the present invention, 30% to 50% of lime powder, 15% to 40% of calcined magnesium powder, 14% to 35% of iron ore powder, and 15% to 35% of bentonite particles are preferably mixed to obtain the dephosphorization slag agent . The present invention has no special limitation on the mixing method, and conventional mixing technical solutions can be used.

[0107] In the present invention, the mass fraction of the lime powder is preferably 30%-50%, ...

Embodiment 1

[0148] 55wt% vanadium-titanium fine powder with an iron grade of 50% to 60%, 5wt% high-phosphorus oolitic hematite powder, 20wt% ordinary fine powder with an iron grade of 50% to 60%, 5wt% basic ordinary ore powder , 5wt% other high-grade common ore powder and 10wt% sinter waste to form ore powder, and the consumption of ore powder is 0.9 tons / ton of sintered ore;

[0149] And the raw material that described slag powder and the quicklime that consumption is 135kg / ton (sintered ore), the dolomite powder that consumption is 35kg / ton (sintered ore), the coke powder that consumption is 53kg / ton (sintered ore) is crushed , after crushing, the mass fraction of raw material particles with a particle size greater than 0 and less than or equal to 3mm is 78%.

[0150] The raw material particles obtained from the crushed materials are batched, that is, the recycled materials and some small piles and small varieties of materials are pre-batched in the primary stockyard, and then homogeniz...

Embodiment 2

[0158] 45wt% vanadium-titanium fine powder with an iron grade of 50% to 60%, 10wt% high phosphorus oolitic hematite powder, 20wt% ordinary fine powder with an iron grade of 50% to 60%, 5wt% basic ordinary ore powder , 5wt% other high-grade ordinary ore powder and 15wt% sinter waste to form ore powder, and the consumption of ore powder is 0.9 tons / ton of sintered ore;

[0159] And the raw material that described slag powder and the quicklime that consumption is 135kg / ton (sintered ore), the dolomite powder that consumption is 35kg / ton (sintered ore), the coke powder that consumption is 53kg / ton (sintered ore) is crushed , after crushing, the mass fraction of raw material particles with a particle size greater than 0 and less than or equal to 3mm is 78%.

[0160] The raw material particles obtained from the crushed materials are batched, that is, the recycled materials and some small piles and small varieties of materials are pre-batched in the primary stockyard, and then homoge...

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Abstract

The application provides a steelmaking method of high-phosphorus molten iron containing vanadium-titanium. The steelmaking method includes following steps: providing the high-phosphorus molten iron containing vanadium-titanium; performing desulfuration, drossing and vanadium-extraction successively to the high-phosphorus molten iron containing vanadium-titanium to obtain semisteel; and with oxygen gun for supplying oxygen, mixing a composite slag material with the semisteel and successively performing blowing and steel tapping to obtain molten steel and slag, wherein an oxygen-supply intensity is 3.2-3.5 m<3> / min*t and the composite slag material includes lime, light-roasted dolomite and phosphated residue removing agent. The phosphated residue removing agent includes following components, by mass, 25-45% of CaO, 12-30% of MgO, 8-25% of FeO and 8-25% of SiO2. In the application, through technology optimization, in the situation of degradation of quality of the molten iron and difficulty in desulfuration and dephosphorization is increased, a smelt period is reduced, the steel is qualified and is increased in yield and an iron-removing capacity is ensured and achieved. In addition, the steelmaking method is low in cost and is good in effect.

Description

technical field [0001] The present application relates to the technical field of steelmaking, in particular to a steelmaking method for vanadium-titanium-containing high-phosphorus molten iron. Background technique [0002] Steelmaking is to put the pig iron used for steelmaking into the steelmaking furnace and smelt it according to a certain process to obtain steel. The pig iron is a product obtained by smelting iron ore in a blast furnace. With the massive development and utilization of mineral resources, the ore is increasingly scarce. In the face of the sharp increase in demand for iron concentrate and the reality of poor, fine and miscellaneous iron ore resources in my country, comprehensive development and utilization of various iron ores has become an inevitable trend in the smelting field. . [0003] In my country's Yunnan and other places, there are abundant high-phosphorus oolitic hematite resources, the iron grade of which is generally 40% to 45%, and the reserves...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C21C5/32C21C5/28C21C7/064
CPCY02P10/20
Inventor 闵荣辉鄢刚徐瑜谢超罗清明
Owner SICHUAN DESHENG GRP VANADIUM & TITANIUM CO LTD
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