Modification method for ultrafiltration membranes, modified ultrafiltration membrane and method adopting ultrafiltration membrane for filtration
An ultrafiltration membrane, modification technology, applied to modified polymer ultrafiltration membrane, a modified polymer ultrafiltration membrane, modification method, filtration field, can solve the problem of hydrophilic polymerization The problem of limited material, affecting the formation of membrane pore structure, etc., achieves the effect of simple reaction steps, high blocking efficiency, and controllable connection amount
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no. 1 example
[0026] This embodiment provides a method for modifying an ultrafiltration membrane. The method comprises the steps of:
[0027] Step S01, performing carboxylation treatment on the polymer ultrafiltration membrane made of polyacrylonitrile; the carboxylation treatment specifically includes: soaking the polymer ultrafiltration membrane in 1.5 mol / L sodium hydroxide solution at 40°C Soak for 50 minutes.
[0028] This step is a substantive step for carboxylation of the polymer ultrafiltration membrane.
[0029] Step S02, taking out the polymer ultrafiltration membrane after soaking treatment, soaking or washing with distilled water, then soaking with 0.1mol / L hydrochloric acid solution for 45 minutes, and then soaking and washing with distilled water for 3 times, each time for 10 minutes.
[0030] The purpose of the treatment with dilute hydrochloric acid solution is to replace the sodium ions attached to the carboxyl groups of the polymer ultrafiltration membrane with hydrogen ...
no. 2 example
[0047] This embodiment provides a method for modifying an ultrafiltration membrane. The method comprises the steps of:
[0048] Step S01, performing carboxylation treatment on the polymer ultrafiltration membrane made of polyacrylonitrile; the carboxylation treatment specifically includes: soaking the polymer ultrafiltration membrane in 1mol / L sodium hydroxide solution, soaking at 35°C Process for 40 minutes.
[0049] This step is a substantive step for carboxylation of the polymer ultrafiltration membrane.
[0050] Step S02, taking out the soaked polymer ultrafiltration membrane, soaking or washing with distilled water, then soaking with 0.05 mol / L hydrochloric acid solution for 30 minutes, and then soaking and washing with distilled water for 3 times, each time for 10 minutes.
[0051] The purpose of the treatment with dilute hydrochloric acid solution is to replace the sodium ions attached to the carboxyl groups of the polymer ultrafiltration membrane with hydrogen ions. ...
no. 3 example
[0068] This embodiment provides a method for modifying an ultrafiltration membrane. The method comprises the steps of:
[0069] Step S01, performing carboxylation treatment on the polymer ultrafiltration membrane made of polyacrylonitrile; the carboxylation treatment specifically includes: soaking the polymer ultrafiltration membrane in 2mol / L sodium hydroxide solution, soaking at 45°C Process for 60 minutes.
[0070] This step is a substantive step for carboxylation of the polymer ultrafiltration membrane.
[0071] Step S02, taking out the soaked polymer ultrafiltration membrane, soaking or washing with distilled water, then soaking with 0.15 mol / L hydrochloric acid solution for 60 minutes, and then soaking and washing with distilled water for 3 times, each time for 10 minutes.
[0072] The purpose of the treatment with dilute hydrochloric acid solution is to replace the sodium ions attached to the carboxyl groups of the polymer ultrafiltration membrane with hydrogen ions. ...
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