Metal/resin composite structure and metal member
By adjusting the surface roughness of metal components and using an acid-based etchant for surface roughening, the problem of insufficient joint strength and adhesion of the metal/resin composite structure was solved, and high joint strength and adhesion were achieved, which is suitable for for environmentally friendly coatings.
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Embodiment 1A
[0335] A small dumbbell metal insert mold 102 was attached to J85AD110H manufactured by Nippon Steel Works, and the aluminum plate (metal member 103 ) prepared in Preparation Example 1A was set in the mold 102 . Next, 80 parts by mass of glass fiber-reinforced polypropylene (V7100 manufactured by Primepolymer, polypropylene (MFR (230° C., 2.16 kg load): 18 g / 10 min)) as the thermoplastic resin composition (P) in the mold 102, glass 20 parts by mass of fibers) were injection molded under the conditions of cylinder temperature 250°C, mold temperature 120°C, injection speed 25mm / sec, dwell pressure 80MPa, and dwell time 10 seconds to obtain a metal / resin composite structure 106. The evaluation results of joint strength are shown in Table 3A.
Embodiment 2A
[0337] In Example 1A, the metal / resin composite structure 106 was obtained in the same manner as in Example 1A except that the aluminum plate prepared in Preparation Example 1A was changed to the aluminum plate prepared in Preparation Example 2A. The evaluation results of joint strength are shown in Table 3A.
Embodiment 3A
[0339] In Example 1A, except that the aluminum plate prepared in Preparation Example 1A was changed, and the aluminum plate prepared in Preparation Example 4A was provided, a metal / resin composite structure 106 was obtained in the same manner as in Example 1A. The evaluation results of joint strength are shown in Table 3A.
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Abstract
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