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Metal/resin composite structure and metal member

By adjusting the surface roughness of metal components and using an acid-based etchant for surface roughening, the problem of insufficient joint strength and adhesion of the metal/resin composite structure was solved, and high joint strength and adhesion were achieved, which is suitable for for environmentally friendly coatings.

Active Publication Date: 2015-04-29
MITSUI CHEMICALS INC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, in the lamination method, the press method, etc., there are disadvantages in that the degree of freedom of the applicable shape is low, and the acid-modified polyolefin resin is attached to the place other than the place where the joint is desired, so that there is a problem that the parts are not flexible. The shape of the metal component cannot make effective use of the performance and appearance of the metal component
[0010] However, even if a water-based paint containing the above-mentioned resin composition is used, the adhesion of the paint film to the metal surface cannot be sufficiently satisfied.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1A

[0335] A small dumbbell metal insert mold 102 was attached to J85AD110H manufactured by Nippon Steel Works, and the aluminum plate (metal member 103 ) prepared in Preparation Example 1A was set in the mold 102 . Next, 80 parts by mass of glass fiber-reinforced polypropylene (V7100 manufactured by Primepolymer, polypropylene (MFR (230° C., 2.16 kg load): 18 g / 10 min)) as the thermoplastic resin composition (P) in the mold 102, glass 20 parts by mass of fibers) were injection molded under the conditions of cylinder temperature 250°C, mold temperature 120°C, injection speed 25mm / sec, dwell pressure 80MPa, and dwell time 10 seconds to obtain a metal / resin composite structure 106. The evaluation results of joint strength are shown in Table 3A.

Embodiment 2A

[0337] In Example 1A, the metal / resin composite structure 106 was obtained in the same manner as in Example 1A except that the aluminum plate prepared in Preparation Example 1A was changed to the aluminum plate prepared in Preparation Example 2A. The evaluation results of joint strength are shown in Table 3A.

Embodiment 3A

[0339] In Example 1A, except that the aluminum plate prepared in Preparation Example 1A was changed, and the aluminum plate prepared in Preparation Example 4A was provided, a metal / resin composite structure 106 was obtained in the same manner as in Example 1A. The evaluation results of joint strength are shown in Table 3A.

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Abstract

A metal / resin composite structure (106) is obtained by joining a metal member (103) and a resin member (105) made of a thermoplastic resin composition (P). When three arbitrary straight-line parts which are present on the surface (110) of the metal member (103) in parallel with each other and three arbitrary straight-line parts which are perpendicular to said straight-line parts, namely six straight-line parts in total, are subjected to surface roughness measurement according to JIS B0601 (corresponding international standard: ISO4287), the surface roughness values measured satisfy the requirements (1) and (2) simultaneously: (1) at least one of the straight-line parts exhibits a material ratio of the roughness profile (Rmr) of 30% or less as determined at a section level of 20% and an evaluation length of 4mm; and (2) the ten-point average roughness values (Rz) of all the straight-line parts as determined at an evaluation length of 4mm exceed 2μm.

Description

technical field [0001] The present invention relates to a metal / resin composite structure and a metal member. Background technique [0002] From the viewpoint of reducing the weight of various parts, resin is used as a substitute for metal. However, it is often difficult to replace all metal parts with resin. In such a case, it is conceivable to manufacture a new composite part by joining and integrating the metal molded body and the resin molded body. However, a metal molded body and a resin molded body can be joined and integrated with high joint strength by an industrially advantageous method and have not been put into practical use. [0003] In recent years, as a technique for joining and integrating a metal molded body and a resin molded body, it has been studied to form fine unevenness on the surface of a metal member, and to bond an engineering plastic having a polar group having an affinity with the metal member ( For example, Patent Documents 1 to 5, etc.). [0...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C23F1/00B29C45/14B32B15/08
CPCB29C45/14311C23F1/20B29K2705/00Y10T428/12993Y10T428/31507Y10T428/31678Y10T428/31681Y10T428/31692C09D109/02C09D123/12C09D125/06C09D125/12C09D167/00C09D179/08C09D181/06B32B15/20B32B15/18B32B15/08B32B3/263B32B7/04B32B15/085B32B15/09B32B2262/101B32B2307/538C09D133/12C09D133/20C09D169/00C09D171/00C09D177/00
Owner MITSUI CHEMICALS INC
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