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A method and device for removing organic matter in zinc sulfate solution by pressurized atomization

A zinc sulfate solution, pressurized atomization technology, applied in the direction of improving process efficiency, etc., can solve the problems of reduced electrolytic current efficiency, high production costs, and difficult recycling, and achieve reduced production costs, stable quality, and improved decomposition of organic matter The effect of removal rate

Active Publication Date: 2016-07-06
YUNNAN CHIHONG ZINC & GERMANIUM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] In the process of hydrometallurgy, too much organic matter in the solution will affect the solution purification and electrolysis production process, resulting in a decrease in electrolysis current efficiency, an increase in DC energy consumption, and an increase in overall production costs
However, the existing methods for removing organic matter in zinc sulfate solution need to add adsorbents or other additives, and the comprehensive recycling and recovery of adsorbents or additives is difficult, and the overall production cost is high.

Method used

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  • A method and device for removing organic matter in zinc sulfate solution by pressurized atomization

Examples

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Embodiment 1

[0031] A method for removing organic matter in a zinc sulfate solution by pressurized atomization, the specific steps are:

[0032] 1) Use a pressurizing device to increase the pressure to 1.0 MPa for the zinc sulfate solution in the hydrometallurgical process with an organic content of 400 mg / L and a pH value of 5.2, and at the same time, use a heating device to increase the temperature of the zinc sulfate solution to 150°C;

[0033] 2) Add the zinc sulfate solution that has been pressurized and heated to a device for removing organic matter in zinc sulfate solution by pressurized atomization. The device for removing organic matter in zinc sulfate solution by pressurized atomization mainly includes pressure Tank body 1, atomization area 2, solution distribution screen 3, stirring area 4, solution mixer 5, atomizer 6, stirring area partition 7, qualified solution outlet 8, circulating liquid outlet 9, circulating gas inlet 10, circulating gas Outlet 11, atomization zone parti...

Embodiment 2

[0041] A method for removing organic matter in a zinc sulfate solution by pressurized atomization, the specific steps are:

[0042] 1) Use a pressurizing device to increase the pressure to 1.2 MPa for the zinc sulfate solution in the hydrometallurgical process with an organic content of 650 mg / L and a pH value of 4.5, and at the same time, use a heating device to increase the temperature of the zinc sulfate solution to 150°C;

[0043] 2) Add the zinc sulfate solution that has been pressurized and heated to a device for removing organic matter in zinc sulfate solution by pressurized atomization, and the device for removing organic matter in zinc sulfate solution by pressurized atomization mainly includes pressure Tank body 1, atomization area 2, solution distribution screen 3, stirring area 4, solution mixer 5, atomizer 6, stirring area partition 7, qualified solution outlet 8, circulating liquid outlet 9, circulating gas inlet 10, circulating gas Outlet 11, atomization zone p...

Embodiment 3

[0051] A method for removing organic matter in a zinc sulfate solution by pressurized atomization, the specific steps are:

[0052] 1) Use a pressurizing device to increase the pressure to 1.5MPa for the zinc sulfate solution in the hydrometallurgical process with an organic content of COD value of 850mg / L and a pH value of 2.6. At the same time, use a heating device to increase the temperature of the zinc sulfate solution to 160°C;

[0053] 2) Add the zinc sulfate solution that has been pressurized and heated to a device for removing organic matter in zinc sulfate solution by pressurized atomization, and the device for removing organic matter in zinc sulfate solution by pressurized atomization mainly includes pressure Tank body 1, atomization area 2, solution distribution screen 3, stirring area 4, solution mixer 5, atomizer 6, stirring area partition 7, qualified solution outlet 8, circulating liquid outlet 9, circulating gas inlet 10, circulating gas Outlet 11, atomization...

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Abstract

The invention relates to a method and a device for removing organic matters in zinc sulphate solution by pressurizing and atomizing, belonging to the field of zinc hydrometallurgy of non-ferrous metallurgy. The method disclosed by the invention comprises the following steps of: adding the zinc sulphate solution into the device for removing the organic matters in the zinc sulphate solution by pressurizing and atomizing after processing by utilizing a pressurizing device and a temperature increasing device, atomizing at first, then, cutting and distributing, finally, strongly stirring, continuously supplying oxygen, ensuring gas cycle of the device, wherein oxygen and the solution in a stirring area are sufficiently reacted so as to realize gas-liquid reaction; oxygen ascends to an atomizing area and is subjected to contact reaction with the atomized solution so as to realize gas-steam reaction; and continuously carrying out circular treatment of the zinc sulphate solution so as to remove the organic matters in the zinc sulphate solution. According to the invention, by means of pressurizing, atomizing and strongly stirring, the organic matters in the zinc sulphate solution are oxidized and decomposed to generate CO2 and H2; the decomposing and removing rates of the organic matters in the zinc sulphate solution are increased; the production cost is reduced; and furthermore, the zinc sulphate solution, the organic matters in which are removed, is steady in quality.

Description

technical field [0001] The invention belongs to the field of nonferrous metallurgy hydrometallurgy zinc, in particular to a method and a device for removing organic matter in zinc sulfate solution by pressurized atomization. Background technique [0002] In the process of hydrometallurgy, too much organic matter in the solution will affect the solution purification and electrolysis production process, resulting in a decrease in electrolysis current efficiency, an increase in DC energy consumption, and an increase in overall production costs. However, the existing method for removing organic matter in zinc sulfate solution needs to add adsorbents or other additives, and the comprehensive recycling of adsorbents or additives is difficult to recover and the overall production cost is high. Contents of the invention [0003] In order to overcome the deficiencies of the prior art, the present invention provides a method for removing organic matter in zinc sulfate solution by pr...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22B3/22
CPCY02P10/20
Inventor 孙成余罗永光廖为新曲洪涛王瑞山孙斯景朱凤荣张候文邹利明邓威威
Owner YUNNAN CHIHONG ZINC & GERMANIUM
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