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A method for measuring optical constant and thickness of metal absorbing film layer

A technology for absorbing film layers and optical constants, which is applied in the direction of color/spectral characteristic measurement, measuring devices, optical devices, etc. Disconnection and other problems, to achieve the effect of simplifying the design and development and production control process, reducing equipment investment costs, and improving accuracy

Active Publication Date: 2017-10-27
CHINA BUILDING MATERIALS ACAD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

When using a step meter to measure the thickness of the film layer, steps need to be prepared, the sample preparation cycle is long, and the thickness of the metal absorbing film layer is generally less than 20nm. Because the surface of the metal film layer is relatively soft, when using the step method to measure the thickness, due to the physical contact of the probe It will cause scratches on the film layer, and the measurement error will be large under the condition that the height of the step is less than 20nm
[0004] In view of the above-mentioned deficiencies in the existing professional testing instruments, these testing instruments cannot obtain the actual optical constants and thickness of the film in a timely and accurate manner, making it difficult for the factory to obtain the actual optical constants of the metal absorbing film in a timely and accurate manner. and thickness, resulting in a disconnection between the input parameters and the actual when using the film system design software

Method used

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  • A method for measuring optical constant and thickness of metal absorbing film layer
  • A method for measuring optical constant and thickness of metal absorbing film layer
  • A method for measuring optical constant and thickness of metal absorbing film layer

Examples

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Embodiment 1

[0046] The embodiment provides a method for measuring the optical constant and thickness of a metal absorbing film layer, the flow of the measurement method is as follows figure 1 As shown, it specifically includes the following steps:

[0047] 1. Sample preparation

[0048] The coating sample in this step can be coated with a metal absorbing film layer on the substrate by magnetron sputtering or other coating methods. The plated metal absorbing film layer can be black metal (such as iron, chromium, manganese and their alloys) or heavy metal (such as titanium, nickel, niobium, tin, zinc, cobalt and their alloys).

[0049] Magnetron sputtering: Ar gas is used for magnetron sputtering. Under the same gas flow rate, the thickness of the metal absorbing film layer is proportional to the sputtering power (plating power described later), and proportional to the light transmittance. inverse relationship.

[0050] In order to improve the accuracy of the analysis, under the conditio...

Embodiment 2

[0073] Nickel-chromium alloy NiCr film is commonly used in off-line Low-E coated glass and solar control coated glass film system. The NiCr thin film plays a crucial role in adjusting the optical properties and environmental resistance of the product. The optical constant and thickness of the NiCr thin film are tested and analyzed in detail below using the optical constant and thickness measurement method of the metal absorbing film layer provided in Example 1 of the present invention.

[0074] 1, the present embodiment adopts off-line coating production line to carry out NiCr thin film coating sample production, according to the magnetron sputtering power source power range, selects the stable and reliable power value to test, the present invention is in same power 3kW, argon Ar gas flow rate 1400sccm (sccm: gas Flow rate unit, milliliter per minute under standard conditions), the glass substrate passes through the NiCr target at the speed of 1m / min and 0.5m / min respectively, ...

Embodiment 3

[0090] Analyze the optical constants of other ferrous metals, heavy metals and their alloys according to the same method and flow process as in Example 2, such as iron Fe, chromium Cr, manganese Mn, titanium Ti, nickel Ni, niobium Nb, tin Sn, zinc Zn, cobalt Co , stainless steel, etc., such as Image 6 is the optical constant of chromium Cr film in the wavelength range of 380-780nm, Figure 7 is the optical constant of the niobium Nb thin film in the visible light wavelength range of 380-780nm, Figure 8 is the optical constant of the stainless steel film in the visible light wavelength range of 380-780nm, and Table 3 is the polynomial model parameters of the optical constants of the chromium Cr, niobium Nb, and stainless steel film layers in the visible light wavelength range of 380-780nm.

[0091] Table 3 is the polynomial model parameters of optical constants in the visible light wavelength range of chromium Cr, niobium Nb, and stainless steel coatings

[0092]

[0093...

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Abstract

The invention discloses a method for measuring the optical constant and the thickness of metallic absorbing film layers, relates to the field of coated glass, and solves the problem that the optical constant and the thickness of the metallic absorbing film layer cannot be accurately and timely measured in the prior art. According to the technical scheme, the method includes: producing N film-coated samples, wherein each film-coated sample comprises a substrate and one metallic absorbing film layer coating the substrate; measuring the transmittance spectrum, in a preset wavelength range, of each film-coated sample; initially setting the parameters of an optical constant polynomial model and the film layer thickness of each film-coated sample to form initial values; using a genetic algorithm, using the initial values as searching starting points and using the transmittance spectrums as searching basis to obtain the refractive index, extinction coefficient and thickness of the metallic absorbing film layers. The method is mainly used for timely and accurately measuring the optical constant and the thickness of the metallic absorbing film layers so as to simplify a product design, development and production control process and reduce enterprise equipment investment cost.

Description

technical field [0001] The invention relates to the field of coated glass, in particular to a method for measuring the optical constant and thickness of a metal absorption film layer. Background technique [0002] Coated glass (such as offline LOW-E coated glass, solar control coated glass, etc.) is coated with one or more layers of thin film on the surface of the glass to change the optical properties of the glass to meet certain specific requirements. The metal absorbing film layer plays the role of sunshade, improving film adhesion and environmental resistance in the film system. For example, the metal absorbing film layer is used as a sacrificial layer in the off-line low-emissivity (LOW-E) film system, which can prevent the low-emissivity functional layer (such as noble metal Ag film) from being oxidized or corroded in subsequent processing and storage, and can improve low-emission The adhesion of the radiation functional layer (eg, Ag thin film); in the solar control ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): G01N21/41G01N21/25G01B11/06
Inventor 余刚汪洪
Owner CHINA BUILDING MATERIALS ACAD